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Explosive gas mixtures and explosive dust clouds, once existing, exhibit similar ignition and combustion features. However, there are two basic differences between dusts and gases which are of substantially greater significance in design of safety standards than these similarities. Firstly, the physics of generation and up-keeping of dust clouds and premixed gas/vapour clouds are substantially different. This means that in most situations where accidental explosive gas clouds may be produced quite readily, generation of explosive dust clouds would be highly unlikely. Secondly, contrary to premixed gas flame propagation, the propagation of flames in dust/air mixtures is not limited only to the flammable dust concentration range of dynamic clouds. The state of stagnant layers/deposits offers an additional discrete possibility of flame propagation.
The two European Directives 94/9/EC (1994) and 1999/92/EC (1999) primarily address gases/vapours, whereas the particular properties of dusts are not addressed adequately. Some recent IEC and European dust standards resulting from this deficiency are discussed, and the need for revising the two directives accordingly is emphasized. 相似文献
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T. D. Blackall M. R. Theobald C. Milford K. J. Hargreaves E. Nemitz L. J. Wilson J. Bull P. J. Bacon K. C. Hamer S. Wanless M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):279-285
Ammonia emissions from two contrasting seabird colonies in Scotland were measured, based on the determination of atmospheric concentrations downwind of the colonies. Atmospheric concentrations of ammonia (NH3) across the downwind plume were compared with the inverse application of a Gaussian dispersion model (ID) to calculate the modelled NH3 emission that would generate the measured cross-wind-integrated plume concentration. In parallel, a tracer gas (sulphur hexafluoride, SF6) was released from the colonies with air samples taken to allow determination of SF6 concentrations. On the basis of the known emission rate of SF6, the magnitude of ammonia emissions was estimated by the cross-wind-integrated tracer ratio (TR) of NH3/SF6 concentrations. Coupled with data on annual bird attendance, the measurements indicate annual emissions from the Isle of May and the Bass Rock of 18 and 132 tonnes NH3-N year–1, respectively. The measured NH3 emissions were compared with estimates of seabird nitrogen excretion to estimate the proportion of excreted N that is volatilised as NH3 (FNr). The emission estimates of the two methods compared favourably, giving 4 and 6 kg NH3-N h–1 (FNr = 15%) for the Isle of May for the ID and TR methods, respectively, and 21 and 25 kg NH3-N h–1 (FNr = 50%) for the Bass Rock for the ID and TR methods, respectively. The results provide the first measurement-based estimates to allow regional up scaling of ammonia emissions from seabirds. 相似文献
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大型城市重大危险源监管与应急救援体系的研究 总被引:7,自引:12,他引:7
分析大型城市重大危险源的现状,指出重大危险源监管存在的主要问题,提出大型城市重大危险源监管与应急救援体系包括的子系统,即:重大危险源的普查与辨识系统、重大危险源的安全评估系统、重大危险源的管理与控制系统、重大危险源事故的应急救援系统,并对其子系统的概念、构成和内容进行分析和阐述,提出了大型城市重大危险源监管与应急救援的思路、模式和对策。 相似文献
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阐述了安全预警技术和重大危险源安全预警系统的建立.重大危险源安全预警系统的建立,将对实现重大危险源安全监察工作信息化、科学化、现代化起到积极的推动作用. 相似文献
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Jerry R. Miller Mark Lord Steven Yurkovich Gail Mackin Lawrence Kolenbrander 《Journal of the American Water Resources Association》2005,41(5):1053-1075
Sedimentation rates and sediment provenance were examined for lacustrine sediments deposited in Fairfield Lake, western North Carolina, during the past 111 years. Stratigraphic, radionuclide, and cartographic data indicate that sedimentation rates have increased several fold during the past three decades in response to localized development. The magnitude of increased sedimentation was surprising given limited development within the basin: 0.12 to 0.68 buildings/ha in 2000 in those parts directly delivering sediment to the dated cores. Thus, the analysis illustrates the potential sensitivity of watersheds in the southern Appalachians to changes in land cover. An approach that combined geochemical fingerprinting with sediment mixing models was subsequently evaluated to determine its ability to accurately estimate the contribution of sediment from (1) major bedrock formations that underlie the watershed and (2) potential sources associated with four land cover categories. Sediment sources in both analyses proved difficult to geochemically fingerprint to greater than 90 percent accuracy using data on acid‐soluble metals and selected isotopes of lead (Pb). The relative contributions of sediment from delineated sources, estimated by the mixing models, generally corresponded with known temporal and spatial patterns of land cover. However, the models were plagued by two significant problems — the chemical alteration of sediments as they were transported through upland streams to depositional sites within the lake and the loss of elemental mass. Thus, future investigations using the fingerprinting approach in this area of intense weathering, and presumably others, will need to modify the existing methods to more accurately elucidate changes in sediment provenance related to development. 相似文献
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A model of multiple domino scenarios and the risk of the domino effect, which is a sequential chain escalating from the primary unit to the last unit, is presented in this paper. The trajectories of fragments from all units, the ground distribution of projectiles, and the risk of the sequential chain of the domino effect were calculated using Monte Carlo simulations. The results showed that the range affected by the fragments from each tank included the other tanks, meaning that fragments from one tank could hit the other tanks and cause multiple accidents, and that the sequential chain of the domino effect could indeed happen. The distributions of ground impacts showed that tank fragments were projected over long distances, up to 1200 m from the source. The spatial distribution of the kinetic energy at ground impact for tank fragments was also obtained. Moreover, the magnitudes of the probabilities of the primary, secondary, third, and fourth accidents in the domino chain were respectively about 10−7, 10−11, 10−15, and 10−19. These results showed that for neighboring domino effect units in the same accident chain, the risk of the most recent domino effect was 104 times that of the following domino effect. 相似文献
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华北地区乡村站点(曲周)夏季PM2.5中二次无机组分的生成机制与来源解析 总被引:2,自引:1,他引:1
利用大气PM2.5水溶性组分及其气态前体物在线测量系统(GAC-IC)于2014年6月9日~7月11日对华北地区乡村站点曲周大气PM2.5中水溶性组分及其气态前体物进行了在线测量,分析了PM2.5中水溶性组分与气态前体物日变化规律及其相互作用,探讨了当地细颗粒物的气粒转化机制并分析了其来源.结果表明夏季曲周大气PM2.5中水溶性无机离子与相关气态前体物的浓度呈现明显的日变化规律.观测期间,PM2.5中SO2-4、NH+4和NO-3的平均浓度分别是26.28、18.08和16.36μg·m-3,是PM2.5中最主要的水溶性无机离子,约占PM2.5质量浓度的76.23%;气态前体物中,NH3浓度明显偏高、平均值为44.85μg·m-3,主要来源于当地的农业活动排放;硫氧化率(SOR)和氮氧化率(NOR)平均值分别是0.60和0.30,表现出明显的二次污染特征.经相关性分析发现:曲周大气PM2.5中NH+4与NO-3、SO2-4有良好的相关性,且表现为富氨状态,NH+4以(NH4)2SO4形式存在,NO-3的生成主要受HNO3的限制.对NH4NO3平衡进行研究发现:与夜间相反,白天曲周大气环境不利于NH4NO3生成和保持.结果也表明,二次转化是曲周夏季细颗粒物的主要来源,堆肥与农田释放的NH3是导致高浓度二次无机颗粒物(SNA)的重要因素. 相似文献