Kinetic mechanism and effects of molecular structure on thermal hazards of azo compounds

In this paper, the kinetic mechanism of AIBN, AMBN, and ABVN was proposed, and the effect of molecular structure on their thermal hazards based on the kinetic mechanism was investigated. Calculated by non-isothermal DSC datum, the kinetic mechanism of AIBN, AMBN, and ABVN is revealed by the linear relationship between the integrated form of mechanical function and reaction time. The results indicate that the thermal decomposition process is controlled by the Johnson-Mehl-Avrami equation. Based on the determination of kinetic mechanism function, the reaction rate constants at various heating rates are directly calculated, and the intercept of the best fitting straight line of reaction rate constants with heating rate is approximately equal to the reaction rate constant under isothermal conditions. Besides, theoretical values obtained by multiplying kinetic mechanism function by reaction rate are well consistent with the experimental values, suggesting that the kinetic mechanism obtained is credible. Bond Dissociation Energies (BDE) calculated by quantum chemical equations are employed to evaluate the thermodynamics stability of AIBN, AMBN, and ABVN. Depending on similar molecular structures, the influence of differentiated group structure on the thermodynamic stability represented by BDE and heat release and the kinetic stability characterized by reaction rate constant were revealed. Finally, the results demonstrate that the thermal hazard increases as the volume of substituent group and molecular weight.     

空气污染视角下北京市产业结构调整的政策模拟研究

空气污染问题是制约经济社会健康发展的重要因素,产业结构调整是缓解该问题的重要途径,探究产业结构调整对于空气污染问题的改善效应具有重要的意义。本文以环境保护和经济增长为双重目标,以投入产出理论为基础,构建了一个一般的具有政策权重的产业结构双目标优化模型。模型目标中的权重体现了政策对两个目标的倾向性需求。给定了某种政策权重,就能根据优化模型计算出最优的产业结构。进一步,我们以SO 2的排放量作为环保指标,以GDP作为经济指标,利用上述模型,依据实际数据,在不同政策权重下,对北京市2017年的产业结构进行了模拟测算,从而给出了与之对应的北京市最优化的产业结构调整方案。特别地,选择了其中三种政策倾向力度,即经济增长偏向性政策、中性政策、环境保护偏向性政策方案,分别给出了最优产业结构方案的数量结果和两个目标的值。我们注意到,2017年的实际值与2016年的实际值相比,2017年的污染物SO 2的排放量大幅减少,且GDP也有所增加,这表明了政府部门的政策相对有效。但是,我们计算出的三种最优化的产业结构对应的两个目标值均优于2017年实际值。事实上,对于经济偏向性政策,最优化的产业结构使得GDP的数量上升更多,而SO 2的排放量也减少了不少;即使是采用环保偏向性政策,不仅使污染物SO 2的排放量更少,而且使GDP的数量仍然高于2017年的实际值。这说明本文提出的通过优化产业结构实现环境保护是一个可行的、合理的途径。     

凹型建筑外立面火灾烟气蔓延特性研究

为了研究凹型建筑外立面火灾烟气蔓延特性，对高层建筑凹槽内火灾烟气“三场”数值模拟。研究表明:结构因子α（进深与槽宽之比）的变化导致凹型建筑结构内呈现不同的火灾烟气蔓延规律；当α为0~0.4时，建筑凹槽内的火灾烟气无烟囱效应；当α为0.6~1.2时，建筑凹槽内的火灾烟气呈现一定的烟囱效应，其火灾烟气温度场、CO浓度场、扩散速度场变化显著；当α>1.2的，建筑凹槽内的火灾烟气烟囱效应显著。     

从环境-社会系统的角度看"建设和谐社会"

环境-社会系统的三元结构是指人、社会和自然三元。可持续发展取决于对这三元运动机制的协调。从环境-社会系统的视角看。可持续发展是指通过三种生产的和谐运行与环境—社会系统的稳定演进．获得“经济-社会-环境”整体的高效益。人类社会发展的两大基本矛盾是资源生产的矛盾和资源配置的矛盾．因此。建设和谐社会的关键在于：在争取“人-社会-自然”和谐演进的前提下。处理好人与社会、人与自然、自然与社会以及自然的、社会的方方面面的“关系”。     

Specific features of the allozyme structure of dandelion populations under conditions of radionuclide and chemical contamination

A study of allozyme spectra has been performed in dandelion cenopopulations growing for a long time under conditions of chemical pollution (the zone of the Nizhnii Tagil Metallurgical Plant, NTMP) or radioactive contamination (the zone of the Eastern Ural Radioactive Trace, EURT). Cenopopulations from the NTMP and EURT zones and from the background area differ significantly in the qualitative and quantitative composition of allozyme phenes. An analysis of clonal diversity has shown that all cenopopulations are phenogenetically unique. The genesis of each cenopopulation proceeded in a specific way: they had different sets of progenitor plants, whose descendants varied genetically in the course of their reproduction and more or less successful colonization of habitats, undergoing selection under the impact of natural environmental factors and technogenic stress. An increased variability of enzyme systems, compared to the sample from the background area, and, as a consequence, reduced clonal diversity may be regarded as a trait common to populations exposed to chemical or radiation stress.     

Spatiotemporal population structure of the bank vole in a gradient of technogenic environmental pollution

Between 1998 and 2005, specific features of spatiotemporal distribution of small mammals in transformed habitats were studied using the example of the bank vole living in a gradient of chemical environmental pollution (the Middle Urals). Technogenic degradation of spruce-fir forests proved to entail significant changes in the spatial structure and abundance of vole populations. Differences in colonization of disturbed and intact territories by bank voles at different stages of population dynamics were revealed.     

Biodiversity of plants and soils in landscapes adjacent to the Buzuluk Pine Forest

The influence of the Buzuluk Pine Forest on biodiversity of plants and soil properties in adjacent territories has been studied. The results show that in the immediate vicinity of the pine forest, under the influence of the relatively mild and humid mesoclimate, natural phytocenoses are dominated by mesophytic species. Biodiversity reaches a peak at a distance of 17–18 km from the forest, which is explained by the presence of both mesophytes and xerophytes in the same phytocenosis. The same zone is also characterized by the maximum diversity of soil properties and structural complexity of the soil cover. Grass communities on ordinary chernozems with a homogeneous soil cover, typical of the steppe zone, are formed at greater distances from the forest.     

城市空间结构生态化基本原理研究

本文在论述生态化研究在全球经济、社会与城市等领域的普遍性和城市空间结构生态化的涵义及其研究的重要性的基础上，从空间结构状态原理、空间结构效率原理、空间结构关系原理、空间结构发展原理四个方面阐述了城市空间结构生态化的基本原理。     

湖北省1981年以来不同时间尺度气温的变化

详细分析全省７１站１９８１￣１９９４年与前２０年不同时间尺度平均气温差值的时空分布特征后发现，８０年代以来我省各地年均气温变化小，但相对地降温范围广，幅度大，且四季及逐月、甸格局发生重大调整，区域差异明显，其特点是冬久暖，夏久凉，春季前冷后暖，秋季反之、其中以夏凉春热最显著；鄂西山区四季均为负变温。     

江南丘陵县域农业资源利用与农业结构优化

针对南方红壤丘陵区农业资源利用的现状，以湖南省桃江县为例，应用灰色关联度模型定量分析了农业各部门产值对农业总产值的影响程度。结果发现，近50年来桃江县农业各部门的关联序列为：种植业（0.887 5）>牧业（0.760 2）>渔业（0.675 6）>林业（0.543 3）。种植业和牧业产值的变化对桃江农业总产值的波动起着主导作用。基于历史统计数据，利用灰色预测模型预测了2001~2005年5年内桃江县农业各部门产值的变化趋势。预测结果表明，各部门发展对农业总产值的关联度分别为：种植业（0.611 3）>渔业（0.358 7）>林业（0.347 6）>牧业（0.334 7）。比较两组关联序列可以清楚发现农业产业各部门的发展潜力。结合桃江农业资源和各部门的发展趋势，提出了桃江县农业结构优化调整的方向。