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21.
利用第一次全国污染源普查“火力发电行业产排污系数核算”工作中现场监测得到的数据,首次采用偏相关分析的方法,对固态排渣煤粉炉中机组规模、空气过剩系数、煤中挥发分和发电负荷率等因素对NOx产生浓度的影响进行定性分析,结论:NOx产生浓度与前三种因素存在显著的相关。而与发电负荷率的关系受锅炉是否采用低氮燃烧技术的影响。空气过剩系数越大,煤的挥发分越高,NOx产生浓度越低;采用低氮燃烧装置的锅炉中,机组规模越大,产生的NOx越少,且对于同一锅炉来说,NOx产生浓度随着发电负荷率的升高而增大;未采用燃烧控制的锅炉中,机组规模越大,NOx产生浓度越高,且与发电负荷率不相关。根据分析结果,提出了控制燃煤电厂固态排渣煤粉炉NOx排放的优化措施和建议。 相似文献
22.
烟气脱硝技术及在我国的应用 总被引:3,自引:0,他引:3
氮氧化物气体是危害最大、最难处理的大气污染物之一。随着经济的发展,有效控制燃煤造成的大气污染已经刻不容缓,特别是控制燃煤过程中的氮氧化物,烟气脱硝技术显得相当重要。本文分析了几种常用的烟气脱硝技术(选择性催化还原脱硝技术、选择性非催化还原脱硝技术、碱性溶液吸收法和等离子体活化法等)的原理、技术特点以及在我国的应用情况。 相似文献
23.
Hang Seok Choi Seock Joon Kim Kwan Tae Kim 《Journal of Material Cycles and Waste Management》2008,10(1):1-6
The mixing characteristics of a passive scalar in the turbulent flow of a selective catalytic reduction process were numerically
and experimentally investigated, focusing especially on an injection nozzle with multiple holes for the reducing agent. The
multihole injection nozzle studied has six holes that are perpendicular to the ambient flue gas flow and are located near
the tip of the nozzle. Large eddy simulation was applied to the turbulent flow and mixing fields to elucidate the mixing mechanism
of the proposed nozzle compared with the single-hole nozzle that is commonly used in the conventional selective catalytic
reduction process. From the results, there exist broader regions of higher turbulent intensities for the multihole nozzle
than for the conventional single-hole nozzle. These regions are well matched with the positions of high vorticity in the near
upstream region of the jet flow issuing from the multiple holes of the nozzle. Consequently, the high turbulent intensities
and vorticity magnitudes lead to intensified mixing between the flue gas and the reducing agent. Hence, the most suitable
molar ratio between NOx and the reducing agent for the catalytic reaction can be easily obtained within a shorter physical
mixing length as a result of the enhanced scalar mixing. Finally, the numerical results were applied to a trial design version
of a multihole nozzle, and this nozzle was experimentally tested to confirm its mixing performance. 相似文献
24.
大气光化学烟雾反应机理比较(Ⅰ)O3和NOx的比较 总被引:8,自引:0,他引:8
在相同初始和排放条件下,对四种应用较广的光化学烟雾反应机理(CB4-99,RADM2,RACM,SAPRC99)进行了比较.研究发现对于O3,在低VOCs/NOx时,四种机理模拟结果相关较小,平均相对标准偏差为7%,在高VOCs/NOx时,平均相对标准偏差为26%,差距较大;对于NOx,多数情况下RACM和RADM2的模拟结果较高,CB4-99和SAPRC99的模拟值偏低,其原因主要来源于不同机理中O3的生成对NOx及VOCs的敏感性不同而造成的.在用模式模拟O3和NOx时,应特别注意机理不同而带来的模拟结果差异. 相似文献
25.
26.
Chung-Ming Liu 《Chemistry and Ecology》1996,12(1):147-161
In this paper, three sensitivity studies are designed to analyze the effect of the NMHC (Non-Methane HydroCarbon) composition, the aerosol back-scattering and the high chimney NOx emission to the photochemical prodution of ozone by using a one-dimensional photochemistry-diffusion model under a favourable meteorological condition. Measurements of the NMHC composition in Taipei indicated that the percentage of iso-butene, cis-2-butene, trans-2-butene and benzene in a unit volume was much higher than of those observed in other major cities. the high ratio of benzene was directly linked to its high percentage in gasoline. As to the unusually high amount of iso-butene, cis-2-butene and trans-2-butene, more researches are needed to identify their source. Concerns are raised as to how productive is NMHC composition is to the photochemical production of the surface ozone. A rough estimate shows that the total reactivity of the Taipei NMHC composition is about 1.21 × 10-9 cm3 s-1 which is 1.6 times that of the Los Angeles (LA) NMHC composition, while the simulated noon peak will be different by 28 ppbv, i.e. 18% more than that simulated with a LA composition.
Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.
In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NOx from high chimneys cannot be ignored. in this study, NOx is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NOx emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated. 相似文献
Meanwhile, high aerosol loading is a serious problem in Taipei. the attenuation of the UV radiation by aerosols cannot be ignored. A numerical simulation shows that the noon ozone level will decrease from 178 to 141ppbv, i. e. about 21% reduction, with deterioration of the visual range from 85 to 5 km.
In the southern Taiwan, industry parks are mixed with the populated Kaohsiung city, hence the large emission of NOx from high chimneys cannot be ignored. in this study, NOx is assumed to be emitted in the layer between 235-460 m high with an emission rate of 0.05 or 0.145 ppbv/sec. the results show that the NOx emitted from the elevated stack lead to a considerable reduction of surface ozone. Such conclusion is obtained due to the fact that a one-dimensional model is used in this paper. Whereas, if a three-dimensional regional model was used, then a higher productivity of ozone downstream would be simulated. 相似文献
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Dian Ding Jia Xing Shuxiao Wang Xing Chang Jiming Hao 《Frontiers of Environmental Science & Engineering》2019,13(5):76