Effective incineration technology with a new-type rotary waste incinerator

The technology of steady combustion in a new type of rotary incinerator is firstly discussed. The formation and control of HCI,NOx and S02 during the incineration of sampled municipal organic solid waste are studied with the incinerator. Results showed that the new model of rotary incinerator can effectively control and reduce the pollutant formations by post combustion.     

Effect of TiO2 surface properties on the SCR activity of NOx emission abatement catalyst

NOx emission abatement catalysts V2O5 supported on various TiO2 including anatase, rutile and mixture of both were investigated with various physico-chemical measurements such as BET, NH3-TPD, NARP, XRD and so on, and the effect of TiO2 surface properties on the SCR (selective catalytic reduction) activity of V20s/TiO2 catalysts was studied. It was found that the TiO2 surface properties had strong affect on the SCR activity of V2Os/TiO2 catalysts. The stronger acidic property resulted in the higher exposure of active sites as well as the higher SCR activity.     

新型铈钨钛复合氧化物催化还原脱硝机理

利用水热共沉淀法制备了铈钨钛复合氧化物催化剂,考察了H₂O₂络合修饰对其催化脱硝转化频率（TOF）的影响;并借助傅里叶原位红外光谱仪研究了H₂O₂络合修饰后铈钨钛复合氧化物的催化脱硝机理.结果表明：H₂O₂络合修饰可增强铈钨钛复合氧化物表面Brønsted酸位强度,提高其表面NH₃低温吸附和中低温NH₃-SCR脱硝性能,400℃时其NO_x催化脱除频率TOF高达0.658s^-1;NH₃和NO_x在H₂O₂络合修饰后铈钨钛复合氧化物表面存在竞争吸附,其表面催化脱硝反应主要为吸附态NH₃、NH₂和NH₄⁺与气态NO+O₂的反应,其低温NH₃-SCR反应机理遵循Eley-Rideal（E-R）机理.     

中国平板玻璃行业大气污染物排放特征研究

基于中国2013~2015年27个省（区、市）平板玻璃企业的逐生产线基础信息、活动水平及污染物控制技术等数据,建立了平板玻璃主要大气污染物SO₂、NO_x排放量计算方法和排放清单,使用蒙特卡洛法进行了不确定性分析.统计了平板玻璃产量、燃料使用量、燃料结构以及污染物控制技术,分析了排放特征与空间差异.结果表明：中国平板玻璃行业以天然气/煤气为主要燃料,平均单位产品能源消耗量为13.2kg标煤/重量箱,山西、内蒙古等省份较高;37%和42%的生产线分别安装了脱硫、脱硝设施,技术以烟气循环流化床、双碱法、SCR为主;SO₂排放量先升后降,2014年达到16.84万t,2015年下降至13.67万t,湖北、浙江、河北、广东排放量较大;NO_x排放量持续下降,从2013年的37.47万t下降至2015年的28.38万t,河北、湖北、山东、广东排放量较大;SO₂排放强度西南部地区高于其他地区,且有上升趋势,其他地区SO₂排放强度整体下降;NO_x排放强度中西部地区较高.应加强高能耗、高排放以及高强度地区的污染控制力度.     

减推力起飞对NOx排放影响计算方法研究

伴随着航空公司对未来几年氮氧化物(NOx)排放量增长的预测,量化机场NOx排放量日益重要。根据国际民航组织认证的发动机排放数据,在研究推力对NOx排放的影响时,通常模拟4个推力级别:100%(起飞阶段)、85%(爬坡阶段)、30%(进近阶段)、7%(慢车阶段)。美国联邦航空局设计了模型——排放和扩散模拟系统,利用该模型对4个阶段分别进行模拟。结果表明,飞机在最大推力时产生的NOx量最多。分析了起飞阶段减推力下起飞对机场年NOx排放量的影响,通过排放和扩散模拟系统,研究了一系列算法,用于预测推力与NOx排放量的关系。     

稻壳混煤燃烧对NOx排放的影响

本文利用循环流化床实验平台分析稻壳混煤燃烧对NOx排放的影响。结果表明,贫煤混合稻壳后燃烧,当燃烧温度恒定时,NOx的排放量随着燃料中稻壳所占比重增加而降低;当燃料中稻壳所占比重恒定时,NOx的排放量随着燃烧温度的升高而增加。     

Influence of NOx on the activity of Pd/θ-Al2O3 catalyst for methane oxidation: Alleviation of transient deactivation

Alumina supported Pd catalyst（Pd/Al₂O₃） is active for complete oxidation of methane, while often suffers transient deactivation during the cold down process. Herein, heating and cooling cycle tests between 200 and 900 °C and isothermal experiments at 650 °C were conducted to investigate the influence of NO_x on transient deactivation of Pd/θ-Al₂O₃ catalyst during the methane oxidation. It was found that the co-fed of NO alleviated transient d...     

Fabric-filter-supported catalyst for removal of harmful solid and gaseous compounds in municipal waste incinerator exhaust gas: characteristics of NO x reduction

We have investigated a fabric-filter-supported catalyst for removing harmful solid and gaseous compounds simultaneously from municipal incinerator exhaust gas. We studied the ways in which the efficiency of NO _x removal is influenced by filter temperature, gas flow rate, and catalyst content. The reduction of the catalyst content by mechanical reverse washing was investigated, and the state of the catalyst supported in the fabric filter was also observed using a scanning electron microscope. The catalyst supported by the fabric filter showed a removal efficiency above 75% when the filter temperature was 200°C, the gas flow rate was 1 m/min, and the catalyst content of the fabric filter was above 300 g/m². The catalyst was supported uniformly on the fibers of the fabric filter, and fine catalyst particles remained on the fibers after mechanical reverse washing. Received: October 15, 1997 / Accepted: March 19, 1999     

催化剂在工业废气脱氮技术中的应用

查阅了国内外有关工业废气脱氮技术中催化剂应用方面的大量资料,对催化剂在锅炉烟气脱氮、烟气联合脱硫脱氮、汽车尾气脱氮等氮氧化物控制技术中的应用原理、现状、发展趋势和主要优缺点进行了详尽的论述.通过对各种催化剂的性能、最佳应用条件、价格等方面的分析、综合和比较,提出了未来催化剂研究工作的重点;基于我国的实际情况提出了工业废气脱氮的可行方案,从而为工业废气脱氮催化剂的进一步开发和研究工作提供参考.     

Competitive diesel engine emissions of sulphur and nitrogen species

NO_x, nitrate and sulphate emissions from a typical European passenger car diesel engine have been measured testing eight different fuels under five steady operating conditions (reproducing modes of the European transient urban/extraurban certification cycle). It is confirmed that nitrogen species compete with sulphur compounds to be adsorbed by diesel particulate matter (DPM) before being emitted into the atmosphere. This competition is found to increase with engine load, and is explained on the basis of the different specific surface and adsorption capacity of soot particles under different operating modes. When a high specific surface is available, as occurs in low load modes, both nitrates and sulphates are adsorbed by soot particles. On the contrary when a small surface is accessible, like in high load modes, sulphates are selectively adsorbed. This is specially important since sulphates are responsible for hydrocarbon retention in DPM due to the scrubbing effect.