Chlorinated dioxins and furans as trace products of combustion: Some theoretical aspects

Recent advances in combustion theories are reviewed, especially the detailed mechanisms of hydrocarbon oxidation, formation of polynuclear aromatic hydrocarbon from aliphatic fuels, and the behavior of halogens in flames. Experimental observations of polychlorinated dibenzo‐p‐dioxins and dibenzofurans (PCDD/F) formation in combustion of aliphatic fuels such as acetylene, ethylene and methane in the presence of hydrogen chloride are summarized. Then, from combustion chemistry considerations a reaction mechanism for T₄CDD/F formation in the CH₄/ HCl/O₂ system is developed. This mechanism consists of elementary reactions describing the main oxidation steps, formation of chlorinated C₁‐ to C₄‐species, formation of the first aromatic ring, and T₄CDD/F formation. The mechanism may be extended to other hydrocarbon fuels and higher PCDD/F homologues. Possible relevance of the mechanism to the “trace chemistries of fire hypothesis”; is discussed.     

The effects of testosterone on antibody production and plumage coloration in male house sparrows (Passer domesticus)

Many bird species have patches of colour in their plumage, contrasting with their basic coloration, which are used to display and signal status to conspecifics. These are called ’badges of status’, because they are believed to be low-cost signals of social status. For a signalling system to be evolutionarily stable, cheating must be controlled. The conventional view is that there is frequent testing, which uncovers cheats. Recently, the immunocompetence handicap hypothesis (ICHH) suggested that signals may be dependent on testosterone for their development, with a cost being imposed through immune suppression. We report experiments on house sparrows (Passer domesticus) which show that testosterone significantly influences the size of the bib (a ’badge of status’). The ultimate effect of the testosterone manipulation was to impair antibody production, as predicted by the ICHH. However, testosterone manipulations also changed the levels of the ’stress hormone’ corticosterone. The level of corticosterone was also related to the degree of immunosuppression. After controlling for the effect of corticosterone, testosterone enhanced the birds’ ability to produce antibodies, counter to the ICHH. The hypothesis therefore must be modified. We suggest that testosterone has a dual effect: it leads to immunosuppression through a mechanism involving corticosterone but, conversely, leads to increased immunocompetence probably via dominance influencing access to resources. Received: 5 March 1999 / Received in revised form: 1 October 1999 / Accepted: 16 October 1999     

Can environmental regulation promote industrial innovation and productivity?Based on the strong and weak Porter hypothesis

This paper constructed extended CDM model to study the effects of environmental regulation on industrial innovation and productivity based on the perspective of strong and weak “Porter hypothesis”, by using 28 manufacturing industry panel data of 2003–2014. The findings reveal that: (1) the impact of environmental regulation on R&D intensity lags behind. In the long run, environmental regulation intensity has a significant role in promoting R&D investment in manufacturing industry. (2) The R&D has a significant role in promoting the substantial innovation of manufacturing industry, and has a strong lag and continuity. However, the R&D intensity has no obvious effect on strategic innovation of manufacturing industry. (3) The substantial innovation doesn’t significantly promote the economic performance of manufacturing industry, but it has a significant role in promoting the energy performance of manufacturing industry, and the substantial innovation plays a significant role in promoting environmental performance in the long term. The strategic innovation significantly promotes the economic performance of manufacturing industry, and it inhibits the energy performance and has no significant effect on environmental performance in the short term. It can promote the energy performance of manufacturing industry, but significantly inhibit environmental performance in the long term. (4) Environmental regulation has significantly suppressed the substantive innovation and strategic innovation of manufacturing industry, and the weak Porter hypothesis has not yet been supported. In the short term, environmental regulation inhibits manufacturing economic performance, but it can promote energy and environmental performance. In the long run, environmental regulation promotes the economic and energy performance of manufacturing industry, but it inhibits environmental performance. The establishment of strong Porter hypothesis has a certain scenario.     

经济发展与环境污染脱钩理论及EKC假说的关系——兼论中国地级城市的脱钩划分

脱钩理论与EKC假说,两者都描述了经济发展与环境污染之间的动态关系,其中,脱钩理论揭示了经济发展与环境压力是否同步变化的关联,而EKC假说先于脱钩理论出现,并阐述了环境污染随着经济发展水平呈现出的非线性关系。本研究基于脱钩理论与EKC假说的理论内涵,首先通过数理模型的推导,得到了二者的内在联系,并运用一阶差分GMM方法对此进行实证检验。基于数理分析和一阶差分GMM估计的实证结果显示,脱钩理论与EKC假说均呈现出先上升后下降的倒"U"型曲线特征,且相对脱钩与绝对脱钩的临界点正好对应于EKC的拐点。其次,结合二者的关联,本研究将人均GDP水平加入脱钩类型的判定标准,在传统脱钩状态分类的基础上,以EKC拐点处所对应的人均GDP水平,以及数值为0.8的脱钩弹性系数为两条分界线,进一步将城市的经济发展与环境污染脱钩关系类型划分为6种形态,分别为"高收入未脱钩"、"低收入未脱钩"、"低收入相对脱钩"、"高收入相对脱钩"、"低收入绝对脱钩"和"高收入绝对脱钩"。最后,本研究将理论部分所做的推导以及脱钩的象限划分应用于实际的城市脱钩案例研究中,并依据一阶差分GMM的回归结果,将中国271个地级城市的经济发展与污染排放的脱钩状态进行了归类。对2004—2013年中国271个地级城市的经验分析表明,近50%的城市尚处于"低收入未脱钩"和"低收入相对脱钩"状态,意味着中国地级城市发展不平衡,且城市内部的脱钩发展与经济发展不匹配问题突出,这些城市在未来的绿色脱钩建设过程中将长期面临着"保增长"和"促脱钩"的双重任务。     

Another outlook into energy-growth nexus in Mexico for sustainable development: Accounting for the combined impact of urbanization and trade openness

This study corroborates the importance of United Nations Sustainable Development Goal 7 (SDG-7), intended to ensure access to affordable, reliable, sustainable energy for all, and SDG-8, designed to promote decent work and sustainable economic growth. This article is motivated by the highlighted SDGs and empirically explores the long-run and causality relationship between energy consumption, urbanization, trade openness, and economic growth for annual frequency data from 1965 to 2021 for the case of Mexico. To this end, we leverage the use of fully modified ordinary least squares, dynamic ordinary least squares, and canonical regression estimation methods, while for the direction of causality, the gradual shift and wavelet coherence methods are used. According to the Autoregressive distributed lag (ARDL), the bounds test traces a long-run relationship between the outlined variables over the sampled period. Empirical evidence validates the energy-induced growth hypothesis. This result resonates with the causality analysis, where energy consumption drives economic growth one way in Mexico. This suggests that Mexico cannot embark on energy-conservative policies, as such actions will hurt economic progress. In addition, unidirectional causality is seen between urbanization, trade openness, and economic growth. These findings have far-reaching implications for economic growth and macroeconomic indicators in Mexico. More insights are highlighted in the concluding section.     

Greening the Brazil,Russia, India,China and South Africa (BRICS) economies: Assessing the impact of electricity consumption,natural resources,and renewable energy on environmental footprint

Electricity consumption is a crucial factor in the environmental pollution process, and therefore, its impact needs to be carefully considered by policymakers. This study investigates the relationship between energy consumption, electricity generation, natural resource utilization, and environmental pollution in BRICS nations, which have a substantial share in global resource consumption. To this end, we employed a novel methodology, namely the Method of Moment Quantile Regression (MMQR), for the time period between 1990 and 2018, within the framework of the Environmental Kuznets Curve (EKC) theory. The study's outcome shows that natural resources and renewable energy are efficacious and significant in curbing environmental degradation among the sample countries. The investigation reveals a positive correlation between electricity consumption and environmental degradation, thereby highlighting this vital resource's role in exacerbating the BRICS nations’ ecological footprint. The findings from this research can provide crucial insights for policymakers to achieve sustainable development and carbon neutrality in these countries.     

Rhetorical Recommendations Built on Ecological Experience: A Reassessment of the Challenge of Environmental Communication

This article reconsiders the challenge of environmental communication by inquiring into the fundamental rhetorical difficulty of thinking in terms of ecology. We discuss two essential yet bewildering aspects of ecology: its focus on interconnection and its use of multiple scales. On this basis, we distil six rhetorical recommendations: a shift from appealing to pre-existing values to avenues for transforming values; a shift from arguments from authority to addressing legitimate resistances; a shift from a focus on mutual agreement to a mutual bewilderment; a shift from intellectual comprehension to personal experience; a shift from negative effects to positive connections; and, finally, a shift from a focus on political results to local transformations. We experiment with this rhetorical approach through two applications: for critical reassessments of past articulations we consider the Gaia Hypothesis and Deep Ecology, and for current refinements to environmental problems we consider controversies around Marcellus Shale gas development     

Proximate control of siblicide in cattle egrets: a test of the food-amount hypothesis

Avian sibling aggression plays an important role in controlling food distribution among nest mates. The food-amount hypothesis predicts that the amount of food obtained by siblings acts as a proximate cue controlling their level of aggression. The importance of this cue to cattle egrets (Bubulcus ibis) in Oklahoma was evaluated by studying parental feeding rates, food distribution among nestlings, and nestling aggression in three-chick broods [A-(oldest), B-, and C-chicks]. We compared nests in which siblicide occurred to nests where all three chicks survived (nonsiblicide nests). Relative to nonsiblicide nests, siblicide nests received decreasing amounts of food as the day of siblicide approached. Similarly, aggression levels of all three chicks in siblicide nests increased significantly compared with nonsiblicide nests, with most of the aggressive behavior involving B- and C-chicks. As a result, on a per-day basis, food amount and aggression exhibited a strong, negative correlation, thus providing support for the food-amount hypothesis. Though the total amount of food delivered to siblicide nests declined on the days prior to siblicide, the amount of food received by A-chicks in these nests did not. Relative to nonsiblicide nests, A-chicks in siblicide nests received an increased share (percent of volume) of the food delivered at the expense of C-chicks, with the percent remaining the same for B-chicks. The percentage of food B-chicks received the day after siblicide increased significantly from that received the day before siblicide, with no change occurring in either the amount or percentage of food received by A-chicks; clearly, B-chicks were the beneficiary of their aggressive actions that resulted in the death of C-chicks. We provide evidence supporting the hypothesis that aggression is proximately linked to food amount, possibly by a relatively simple cue such as hunger. Received: 25 November 1994/Accepted after revision: 10 February 1996     

Ecological correlates of duckling adoption among white-winged scoters Melanitta fusca: strategy, epiphenomenon, or combination?

Young waterfowl can frequently join foster females shortly after hatch, resulting in post-hatch brood amalgamation. Much uncertainty remains about physiological or ecological factors that motivate adoption including potential costs and benefits to fostered offspring as well as to females that either lose or accept young. Several hypotheses have been put forth to explain adoption. In this paper, we examine the salvage strategy (SSH) and accidental-mixing (AMH) hypotheses. According to the SSH, females abandon or lose their young due to substantial energetic constraints from incubation and brood rearing. The AMH posits that adoption results from local ecological conditions on breeding areas (i.e., adverse weather conditions, high brood densities) which act to separate offspring and mothers. We used multistate modeling to estimate relationships between probabilities of adoption by white-winged scoter (Melanitta fusca) ducklings from natal to foster females and a set of hypothesized ecological covariates. Results showed that most adoption occurred within 6 days of hatch; additionally, likelihood of adoption was positively related to inclement weather and negatively related to hatch date, size, and condition of natal females, and duckling condition. We conclude that adoption in this population is consistent with both the salvage strategy and accidental-mixing hypotheses. Ultimately, we suggest that adoption in our study population was foremost an outcome of intense gull predation but also of local environmental conditions.     

铬污染场地调查数据评估与暴露浓度估计

针对某铬污染场地调查采样得到的1 269个土壤w(TCr)和w〔Cr(Ⅵ)〕,分别采用检出限替代法和Walsh's Test方法分析了未检出值和潜在的异常值.结果表明,异常值的取舍对数据的统计分析结果影响较大,结合该铬污染场地的实际情况和采样记录,最终保留了潜在异常值. 分别采用Q-Q图示法和假设检验方法探讨了该铬污染场地土壤w(TCr)和w〔Cr(Ⅵ)〕的数据分布形态发现,二者均不符合3种常见的分布形态(即正态分布、对数正态分布和Gamma分布),因此,采用基于切比雪夫不等式的非参数方法计算该铬污染场地调查数据的95%UCL(置信区间上限值),确定w(TCr)和w〔Cr(Ⅵ)〕的暴露值分别为0.285 6%和0.022 7%.