Characteristics of N2O emission from Medicago sativa stands and its response to nitrogen fertilizers in the Longdong dryland Plateau北大核心CSCD

Nitrous oxide (N2O) is one of the potent greenhouse gases (GHG) that depletes the stratospheric ozone. Nitrogen fertilizers are considered to be a major source of nitrous oxide (N2O) emissions from arable soils. To investigate the characteristics of N2O emission, its influencing factors, and its response to nitrogen application in dry grassland in the Loess Plateau, one of the most intensively used agricultural regions in China, we conducted a field trial with two treatments including N0 (0 kg hm-2) and N150 (150 kg hm-2) at the Qingyang Loess Plateau grassland agricultural research station of Lanzhou University. An LGR-N2O/CO gas analyzer was used to monitor the emissions. The results showed that the N2O fluxes of the N0 and N150 treatments during the monitoring period were -0.0036 and 0.0118 mg m-2 h-1, respectively; the flux in case of the N150 treatment was significantly higher than that for the N0 treatment. The N2O emission flux has a distinct diurnal variation characteristic, which first showed the trend of decreasing and then increasing. Regression analysis indicated a significant positive correlation between the N2O flux and the surface soil water content at a depth of 10 cm. The N2O emission flux increased by 131.3%, compared with that during the non-precipitation days. At the same time, the N2O emission flux showed a trend of decreasing with the increase of the surface soil temperature at a depth of 10 cm. The daily emission characteristics indicated that there may be a significant underestimation of the N2O flux at the daily or longer time-scale, based on the N2O flux value measured at 9:00-11:00. In summary, the N2O emissions from the sown alfalfa grassland of the eastern Gansu are strongly affected by precipitation and nitrogen application and have obvious daily dynamic characteristics. It is recommended that the accuracy and representativeness of N2O emission flux data be enhanced by continuous dynamic measurement using the instrument. © 2018 Science Press. All rights reserved.     

Enzymatic nitrous oxide emissions from wastewater treatment

Nitrous oxide (N₂O), a potent greenhouse gas, is emitted during nitrogen removal in wastewater treatment, significantly contributing to greenhouse effect. Nitrogen removal generally involves nitrification and denitrification catalyzed by specific enzymes. N₂O production and consumption vary considerably in response to specific enzyme-catalyzed nitrogen imbalances, but the mechanisms are not yet completely understood. Studying the regulation of related enzymes’ activity is essential to minimize N₂O emissions during wastewater treatment. This paper aims to review the poorly understood related enzymes that most commonly involved in producing and consuming N₂O in terms of their nature, structure and catalytic mechanisms. The pathways of N₂O emission during wastewater treatment are briefly introduced. The key environmental factors influencing N₂O emission through regulatory enzymes are summarized and the enzyme-based mechanisms are revealed. Several enzymebased techniques for mitigating N₂O emissions directly or indirectly are proposed. Finally, areas for further research on N₂O release during wastewater treatment are discussed.

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安徽淮北矿区地表水氮的富营养化特征及来源解析

为探索淮北临涣矿区地表水体中氮的分布和来源,采集研究区河流和沉陷积水区样品,测试分析其水化学指标和氮、氧同位素特征值,并采用IsoSource模型计算不同端源氮的污染贡献率。结果表明:研究区地表水处于中度富营养化状态,矿区地表水中氮的输入源受含氮肥料、土壤有机氮和粪肥污水共同影响,所发生的硝化及反硝化作用微弱;矿区河水中氮的主要输入源为粪肥污水,贡献率达66.6%,沉陷积水区氮主要受含氮肥料输入的影响,贡献率达52.0%。     

基于社会嵌入视角的农户减施化肥意愿影响因素分析

化肥是中国农业生产中最基础的物质投入要素,而化肥的过施滥施则是造成和加重农业面源污染的重要原因。农户作为化肥施用行为的主体,引导其科学施肥对农业可持续发展具有重要意义。本文基于洞庭湖区农业面源污染综合治理试点项目区353份农户问卷调查数据,依托社会嵌入理论,运用二元Logistic模型分析农业面源污染治理中农户减施化肥意愿及其影响因素。结果表明:研究区域农户减施化肥意愿不强;农户减施化肥意愿不仅受到经济利益因素的驱动,还受到社会背景特征、农户自身特征等因素的影响;政府支持、农户认知及社会关系等社会嵌入因素对农户减施化肥意愿存在显著正向影响。基于此,政府应加强对科学施肥行为的支持力度,因地制宜构建科学施肥的社会嵌入环境,提高农户关于减施化肥方面的认知水平,充分发挥社会关系在科学施肥中的引导和示范作用。     

有机无机肥料对农业环境影响述评

论述了有机肥在中国的使用情况和对农业生产的作用、化肥对农产品质量的影响、化肥对土壤肥力的贡献、有机肥和化肥对大气环境和水体的影响。目前人们在对化肥使用的认识上普遍存在误区,认为施用化肥一定会对环境产生污染,只有使用有机肥才能解决问题。中国是一个人口大国,今后在一个相当长的时间内,农业产品的生产在养分的投入上仍然需要以化肥为主,充分、合理、平衡的化肥投入不仅能满足人们对农产品数量上的需要,而且一定能满足人们对农产品品质的要求。化肥的合理施用可以改善和提高农产品品质,提高土壤有机质含量,改善土壤理化性质,减少温室气体的排放和水体污染。化肥本身是无害的,有害的是对化肥的不合理施用。在肥料问题上,今后需要关注 的应该是生产和使用更优质、更高效的化肥,推广科学合理的施肥技术,提高化肥的利用效率。     

国外家畜粪便肥料成分含量快速预测方法的研究

研究家畜粪便的物理指标与其肥料成分含量的关系,用来预测家畜粪便肥料成分含量.目前国外主要研究的预测家畜粪便肥料成分含量的物理指标主要有:干物质含量、比重、电导率、流变学特性、pH值及几个指标的组合.研究表明,预测牛、奶牛和猪粪便中氮和磷的含量可用比重和干物质含量,并且用比重代替干物质含量更易于实现畜禽粪便营养成分含量的快速和在线检测;电导率可预测牛、猪粪便中铵态氮和钾的含量;此外家畜粪便的流变学特性ln(k)和pH值也可用来预测某些成分,但效果较差.同时采用某2个物理指标来预测的效果优于单个指标的预测效果.     

Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors

Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L⁻¹, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L⁻¹, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L⁻¹, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.     

Does salt marsh fertilization enhance shellfish production? An application of flow analysis

The method of flow analysis, which is similar to economic input-output analysis, is presented as a means of making flow models of ecological systems more useful to environmental managers. This paper considers as an illustration the extent to which nitrogen fertilizer added toSpartina salt marsh sediments can enhance shellfish growth. Nitrogen flow models of both the Barataria Bay salt marsh complex of coastal Louisiana and the Sippewissett Marsh of western Cape Cod are analyzed. The analysis shows the transfer of added nitrogen to shellfish growth viaSpartina growth, decomposition, and detrital feeding to be considerably less efficient than its transfer toSpartina growth itself. These results are similar for both marsh systems, despite their great physical differences and despite the inclusion of considerably more microbial processing of nitrogen in the Barataria Bay model than in the Sippewissett models. The results suggest that the most efficient mechanism by which added nitrogen could enhance shellfish growth in salt marshes may have to bypass the route through theSpartina life cycle.     

脲硫酸复肥新工艺减少氟逸出的研究

用脲硫酸代替硫酸分解磷矿生产复合肥，研究了反应温度、磷矿粉细度、搅拌强度、酸解剂配比(尿素与硫酸、水的摩尔比)对磷矿转化率和气相氟逸出率的影响。结果表明，酸解剂配比是影响氟逸出率的最主要因素，由于尿素的加入使氟逸出率较传统酸解磷矿减少75％以上。在酸解剂配比3．6：1：1、反应温度85℃、搅拌强度400r／min、磷矿粉细度120～150目条件下，磷矿初期分解率可达90％以上，气相氟逸出率可降至3％左右，固相氟含量未增加。     

CALIBRATION OF STORM LOADS IN THE SOUTH PRONG WATERSHED,FLORIDA, USING BASINS/HSPF1

ABSTRACT: The South Prong watershed is a major tributary system of the Sebastian River and adjacent Indian River Lagoon. Continued urbanization of the Sebastian River drainage basin and other watersheds of the Indian River Lagoon is expected to increase runoff and nonpoint source pollutant loads. The St. Johns River Water Management District developed watershed simulation models to estimate potential impacts on the ecological systems of receiving waters and to assist planners in devising strategies to prevent further degradation of water resources. In the South Prong system, a storm water sampling program was carried out to calibrate the water quality components of the watershed model for total suspended solids (TSS), total phosphorous (TP), and total nitrogen (TN). During the period of May to November 1999, water quality and flow data were collected at three locations within the watershed. Two of the sampling stations were located at the downstream end of major watercourses. The third station was located at the watershed outlet. Five storm events were sampled and measured at each station. Sampling was conducted at appropriate intervals to represent the rising limb, peak, and recession limb of each storm event. The simulations were handled by HSPF (Hydrologic Simulation Program‐Fortran). Results include calibration of the hydrology and calibration of the individual storm loads. The hydrologic calibration was continuous over the period 1994 through 1999. Simulated storm runoff, storm loads, and event mean concentrations were compared with their corresponding observed values. The hydrologic calibration showed good results. The outcome of the individual storm calibrations was mixed. Overall, however, the simulated storm loads agreed reasonably well with measured loads for a majority of the storms.