Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors

Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L⁻¹, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L⁻¹, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L⁻¹, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.     

Does salt marsh fertilization enhance shellfish production? An application of flow analysis

The method of flow analysis, which is similar to economic input-output analysis, is presented as a means of making flow models of ecological systems more useful to environmental managers. This paper considers as an illustration the extent to which nitrogen fertilizer added toSpartina salt marsh sediments can enhance shellfish growth. Nitrogen flow models of both the Barataria Bay salt marsh complex of coastal Louisiana and the Sippewissett Marsh of western Cape Cod are analyzed. The analysis shows the transfer of added nitrogen to shellfish growth viaSpartina growth, decomposition, and detrital feeding to be considerably less efficient than its transfer toSpartina growth itself. These results are similar for both marsh systems, despite their great physical differences and despite the inclusion of considerably more microbial processing of nitrogen in the Barataria Bay model than in the Sippewissett models. The results suggest that the most efficient mechanism by which added nitrogen could enhance shellfish growth in salt marshes may have to bypass the route through theSpartina life cycle.     

PRECIPITATION RETENTION AND SOIL EROSION UNDER VARYING CLIMATE,LAND USE,AND TILLAGE AND CROPPING SYSTEMS1

ABSTRACT: Nonirrigated crop yields and forage production are limited by low and variable precipitation in the southern Great Plains. Precipitation variation involves production risks, which can be reduced by considering probability of precipitation, precipitation retention, and soil erosion under various production systems. The objective of this study was to probabilistically quantify the impact of precipitation variations, land use, cropping, and tillage systems on precipitation retention and soil erosion. Five 1.6 ha watersheds that had 3 to 4 percent slopes, and similar silt loam soils were selected. One was kept in native grass, and the others were planted into winter wheat (Triticum aestivum L.) under different cropping and tillage systems. Daily runoff and soil erosion were measured at the outlet of each watershed. Precipitation distributions exhibited great seasonal and interannual variations, and precipitation retention distributions resembled those of precipitation. Cropping and tillage systems affected precipitation retention but much less than did precipitation variations. Available soil water storage, which was largely controlled by ET, played an important role in retaining precipitation. This indicates that cropping systems should be adjusted to precipitation patterns, if predictable, for better soil water use. Land use and cropping and tillage systems had a much greater impact on soil erosion than on precipitation retention. Soil erosion risks, which were proportional to the levels of tillage disturbance, were mainly caused by a few large storms in summer, when surface cover was low. This study explored a novel approach for evaluating production risks associated with insufficient precipitation retention and excessive soil erosion for certain crops or cropping systems under assumed precipitation conditions.     

CALIBRATION OF STORM LOADS IN THE SOUTH PRONG WATERSHED,FLORIDA, USING BASINS/HSPF1

ABSTRACT: The South Prong watershed is a major tributary system of the Sebastian River and adjacent Indian River Lagoon. Continued urbanization of the Sebastian River drainage basin and other watersheds of the Indian River Lagoon is expected to increase runoff and nonpoint source pollutant loads. The St. Johns River Water Management District developed watershed simulation models to estimate potential impacts on the ecological systems of receiving waters and to assist planners in devising strategies to prevent further degradation of water resources. In the South Prong system, a storm water sampling program was carried out to calibrate the water quality components of the watershed model for total suspended solids (TSS), total phosphorous (TP), and total nitrogen (TN). During the period of May to November 1999, water quality and flow data were collected at three locations within the watershed. Two of the sampling stations were located at the downstream end of major watercourses. The third station was located at the watershed outlet. Five storm events were sampled and measured at each station. Sampling was conducted at appropriate intervals to represent the rising limb, peak, and recession limb of each storm event. The simulations were handled by HSPF (Hydrologic Simulation Program‐Fortran). Results include calibration of the hydrology and calibration of the individual storm loads. The hydrologic calibration was continuous over the period 1994 through 1999. Simulated storm runoff, storm loads, and event mean concentrations were compared with their corresponding observed values. The hydrologic calibration showed good results. The outcome of the individual storm calibrations was mixed. Overall, however, the simulated storm loads agreed reasonably well with measured loads for a majority of the storms.     

煤中砷及燃煤固砷技术研究

对煤中砷的含量、分布、赋存状态等地球化学特征进行了综述,分析了煤炭燃烧过程中砷的迁移转化行为与释放特性,指出煤中砷的燃烧释放不仅与砷的物理化学性质有关,更取决于煤中的浓度、赋存状态及燃烧工况等因素。进一步讨论了天然钙基材料燃煤固砷技术及燃煤砷污染控制的研究现状。     

WATERSHED MANAGEMENT WITHOUT SURFACE RUNOFF1

ABSTRACT: Legal, economic, and social constraints prevented the development of a surface outlet from an 878 acre watershed in the eastern Great Plains. However, frequent flooding of potentially excellent cropland within the watershed had to be controlled. The process of considering various alternatives within given constraints and utilizing natural features of the watershed to attain a water management system without surface runoff is presented. The coordinated system includes surface drainage, waterholding structures, and pumping plants. The excellent water control provided permits effective utilization of more than 115 acres of land which was previously of very low productivity.     

Modelling nitrogen cycles of farming systems as basis of site- and farm-specific nitrogen management

The paper describes a model designed for analysing interrelated nitrogen (N) fluxes in farming systems. It combines the partial N balance, farm gate balance, barn balance and soil surface balance, in order to analyse all relevant N fluxes between the subsystems soil–plant–animal–environment and to reflect conclusive and consistent management systems. Such a system approach allows identifying the causes of varying N surplus and N utilisation.The REPRO model has been applied in the experimental farm Scheyern in southern Germany, which had been subdivided into an organic (org) and a conventional (con) farming system in 1992. Detailed series of long-term measuring data are available for the experimental farm, which have been used for evaluating the software for its efficiency and applicability under very different management, yet nearly equal site conditions.The organic farm is multi-structured with a legume-based crop rotation (N₂ fixation: 83 kg ha⁻¹ yr⁻¹). The livestock density is 1.4 LSU ha⁻¹. The farm is oriented on closed mass cycles.The conventional farm is a simple-structured cash crop system based on mineral N (N input 145 kg ha⁻¹ yr⁻¹). Averaging the years 1999–2002, the organic crop rotation reached, with regard to the harvested products, about 81% (6.9 Mg ha⁻¹ yr⁻¹) of the DM yield and about 93% (140 kg ha⁻¹ yr⁻¹) of the N removal of the conventional rotation. Related to the cropped area, the N surplus calculated for the organic rotation was 38 kg ha⁻¹ yr⁻¹ versus 44 kg ha⁻¹ yr⁻¹ for the conventional rotation. The N utilisation reached 0.77 (org) and 0.79 (con), respectively. The different structure of the farms favoured an enhancement of the soil organic nitrogen stock (35 kg ha⁻¹ yr⁻¹) in the organic crop rotation and caused a decline in the conventional system (−24 kg ha⁻¹ yr⁻¹). Taking account of these changes, which were substantiated by measurements, N surplus in the organic rotation decreased to 3 kg ha⁻¹ yr⁻¹, while it increased to 68 kg ha⁻¹ yr⁻¹ in the conventional system. The adjusted N utilisation value amounted to 0.98 (org) and 0.69 (con), respectively.     

Classification of di erent sustainable flood retention basin types

Using a revised version of a previously published expert classification system, a database of potential Sustainable Flood Retention Basins has been developed for Scotland. The research shows that the majority of small and former (often old) drinking water reservoirs are kept full and their spillways are continuously in operation. Utilising some of the available capacity to contribute to flood control could significantly reduce the costs of complying with the European Union Flood Directive. Furthermore, the application of a previously developed classification model for Baden in Germany for the Scottish data set showed a lower diversity for basins in Scotland due to less developed infrastructure. The classification system appears to be robust and has the potential, with minor modifications, to be applied across Europe. The principle value of this approach is a clear and unambiguous categorisation, based on standard variables, which can help to promote communication and understanding between stakeholders.     

N-羧甲基壳聚糖的制备表征及性能研究

通过乙醛酸与壳聚糖形成西佛碱,用硼氢化钠还原制备N位取代的羧甲基壳聚糖,采用FT-IR、X-ray、NMR分析手段对分子结构进行表征。吸湿保湿性能研究发现取代度较低的N-羧甲基壳聚糖吸湿性能较好,保湿性能随着羧甲基取代度的增加而增强。通过羟基磷灰石、骨胶原与N-羧甲基壳聚糖制备了新型的复合生物材料,与没有添加N-羧甲基壳聚糖的复合材料相比较,发现具有良好的机械性能和溶涨性能。     

湖泊水体中营养盐控制技术研究进展

营养盐物质是造成湖泊水体富营养化的关键因素,在对湖泊水体营养盐控制技术探讨过程中,分析了营养盐的来源形式,从物理、化学、生物生态学角度分别对营养盐的控制技术进行了论述和思考,并指出了今后湖泊水体中营养盐控制技术发展方向。