热解吸/GC/MS联用测定石化工业区大气环境中挥发性有机物

采用二次热解吸／气相色谱／质谱联用测定石化工业区大气环境中挥发性有机物,质谱检测器同时进行全扫描和选择离子扫描,全扫描定性,选择离子扫描和内标法定量。方法线性良好,50种目标化合物的检出限为0.14ng-2.45ng,在3个浓度水平的加标回收试验中,1,1-二氯乙烯和二氯甲烷回收率较低,氯仿和苯低浓度回收率较差,其余46种目标化合物的回收率为83.4％-116％,RSD为0.5％-8.9％。     

Conjunctive Vadose and Saturated Zone Monitoring for Subsurface Contamination

A comprehensive subsurface monitoring program should include contaminant detectors in both the vadose and saturated zones. Vadose zone detectors can provide an early warning of an impending groundwater contamination problem, and also yield information relevant to placing groundwater monitoring wells. Moisture probes, gas monitoring wells, and pore-liquid samplers deployed in the vadose zone complement groundwater detection wells. The objective(s) of a monitoring program, spatial-scales, and hydrogeology are important considerations for designing subsurface monitoring networks. Often, these networks are used to detect potential releases or characterize existing contamination beneath land-based waste storage facilities. A case study in Santa Barbara, California, U.S.A., illustrates the utility of vadose zone monitoring in characterizing a gasoline contamination problem and guiding the placement of groundwater monitoring wells.     

城市辖区生态示范区建设规划中若干问题探讨

以国家生态示范区建设试点区——乌鲁木齐市沙依巴克区生态示范区为例,针对城市行政辖区作为复合生态系统相对独立性太弱的特点,对在规划中需特别注意的政府职责层次、示范区区域界定及建设区模式选择等问题进行了探讨,并根据该区生态示范区规划编制工作中的实际情况,提出了解决这些问题的基本思路。     

油气田瓦斯隧道开挖掌子面围岩安全厚度研究

为降低油气田区隧道施工风险，以龙泉山隧道为依托，采用数值模拟方法对隧道开挖掌子面前方围岩安全厚度进行分析，并结合现场监测数据对所得结论进行验证。研究结果表明:隧道施工使隧址区围岩应力重分布，且应力变化与围岩距掌子面距离L有关，当L≤0.75D（D为隧道净高）时，围岩处于应力释放区；当0.75D相似文献   

Effects of environment, vehicle and driver characteristics on risky driving behavior at work zones

This study aims to analyze the effects of environment, vehicle and driver characteristics on the risky driving behavior at work zones. A decision tree is developed using the classification and regression tree (CART) algorithm to graphically display the relationship between the risky driving behavior and its influencing factors. This approach could avoid the inherent problems occurred in the conventional logistic regression models and further improve the model prediction accuracy. Based on the Michigan M-94/I-94/I-94BL/I-94BR highway work zone driving behavior data, the decision tree comprising 33 leaf nodes is built. Bad weather, poor road and light conditions, partial/no access control, no traffic control devices, turning left/right and driving in an old vehicle are found to be associated with the risky driving behavior at work zones. The middle-aged drivers, who are going straight ahead in their vehicles with medium service time and equipped with an airbag system, are more likely to take risky behavior at lower work zone speed limits. Further, the middle-aged male drivers engage in risky driving behavior more frequently than the middle-aged female drivers. The number of lanes exhibits opposing effects on risky behavior under different traveling conditions. More specifically, the risky driving behavior is associated with the single-lane road under bad light or weather conditions while drivers are more likely to engage in risky behavior on the multi-lane road under good light conditions.     

极限平衡区顶煤自燃三维非均质动态数值模拟

为探究极限平衡区内顶煤自燃规律,利用Fluent软件对顶煤自燃进行数值模拟研究。通过对顶煤移动变形及自燃特点的分析,确定顶煤自燃过程的模拟为三维非均质动态模拟,并建立数学模型,给出相关参数及边界条件的确定方法。以恒大矿某工作面为例,对其顶煤的自燃过程进行数值模拟,并分析工作面风量及煤体耗氧速度与自然发火期之间的关系。结果表明:对计算区域进行模拟所得到的速度场、氧浓度场及温度场与现场观测结果及理论结果比较吻合;工作面风量对煤体自然发火期影响较小,而对高温区域中心点位置影响较大;煤体耗氧速率与自然发火期近似成负指数函数关系。     

Low energy buildings in Taiwan mountain areas: A weather data analysis

The energy consumption of buildings is influenced by the climates tremendously. Taiwan is an island covered with high mountains. Crossed by the tropic of cancer, the basic climates zones include tropical and subtropical climates. In this research, the degree day and degree hour methods were used to analyze 37 weather stations data in mid and high elevation regions of Taiwan collected over 10 years. The WRF model were used to predict summer cooling hours using 26, 28, 30°C as the base temperatures. The research showed that Taiwan has complicated climate zones due to the variations of the elevation. The low air-conditioning load areas in the mid and high elevation regions will be the most suitable areas to design low energy consumption buildings in Taiwan.     

关于有序填海的思路与方法

填海造陆在扩展土地和发展经济的同时也对海岸带环境造成了不利影响。将有序人类活动贯穿于整个填海造陆过程,通过科学合理的规划、组织和实施而进行有序填海,从而增加填海造陆的积极效应,限制其破坏性影响,是实现海岸带可持续发展的必由之路。整体性、矛盾论、动态平衡和因地制宜是有序填海的基本观点。要实现有序填海,首先必须在对填海造陆的效益和损失进行科学评价的基础上进行可行性论证,然后制定不同尺度的填海规划并确定填海造陆的适宜规模,最后利用一系列有效方法加以实施,包括：维护海岸带自然系统功能、完善监督管理制度、实行生态补偿与生态系统重建、加速改良填海区环境等。     

基于性能化防火设计的建筑“准安全区”判定方法

为判定人员疏散过程中"准安全区"的安全性,采用基于性能化防火设计的方法对建筑"准安全区"的安全性进行判定。"准安全区"内烟气热辐射、烟气能见度及有毒气体等有害因素的指标必须达到"准安全区"规定的指标要求。发生火灾时,"准安全区"内距离地面2 m以下烟气层温度不应超过60℃,烟气层能见度不应小于10 m,烟气层CO浓度不应大于5×10-4mol/mol。工程应用中可根据"准安全区"各性能判定标准,通过火灾模拟软件模拟分析火灾场景下"准安全区"内各有害因素的性能参数分布,对"准安全区"的安全性进行定性、定量评估。     

大型水体下顶水安全开采的可行性研究

在大型水体下顶水采煤,一方面要确保煤矿井下安全生产,同时要保护地表水资源不被破坏。基于峰峰矿区小屯矿的地质采矿条件,在分析与评价上覆岩层结构的基础上,选取水体下11个计算特征点,探讨上覆岩层破坏高度、防水安全煤岩柱及安全煤岩柱最小富余尺寸,绘制各类等值线图。采用概率积分法,从下沉、倾斜、水平变形和裂缝深度等方面,研究分析顶水开采后水体底部所受的采动影响。结果表明,在特定的地质采矿条件下,各工作面开采以后,上覆岩层中导水裂隙带发育的最大标高与基岩顶部之间具有较厚的岩柱,导水裂隙带不会波及到地表水体,水体底部的地表移动变形较小,不会影响到矿井安全生产,在大型水体下顶水采煤是安全可行的。