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311.
312.
Kotaro Minomo Nobutoshi Ohtsuka Kiyoshi Nojiri Yasundo Kurata Masafumi Karaushi Yugo Isobe 《Journal of Material Cycles and Waste Management》2009,11(1):73-81
In this study, we propose an analytical method to determine the fourteen of azaarenes present in flue gas samples collected
according to Japanese Industrial Standard K 0311, which designates the method for the determination of dioxins in flue gas.
Azaarenes can be analyzed using the acidic water phase after shaking extraction with dichloromethane, which is unnecessary
for dioxin analysis. Flue gas samples were obtained from 24 waste incinerators in Japan, and azaarenes were detected in all
the flue gas samples (0.21–3800 μg/m3
N). The most abundant of the detected compounds were quinoline and isoquinoline. The concentration of azaarenes had a tendency
to increase with that of polychlorinated dibenzo-p-dioxins and dibenzofurans. The isomer distribution of heptachloro-dibenzofurans (HpCDFs) was calculated using the computed
Gibbs energy of formation (ΔG
f
) obtained by the semiempirical molecular orbital method at various temperatures. The calculated isomer distribution was fitted
to the measured value of HpCDFs. It seems that the temperature obtained from the fitting calculations is an indicator of the
cooling capacity of the combustion gas in an incinerator. The computed ΔG
f
also explained the measured isomer distributions of azaarenes. It is suggested that the isomer distribution of azaarenes
in the combustion process is thermodynamically controlled.
This work was presented in part at the International Conference on Combustion, Incineration/Pyrolysis, and Emission Control,
2006, Kyoto 相似文献
313.
K. Walha R. Ben Amar P. Bourseau P. Jaouen 《Process Safety and Environmental Protection》2009,87(5):331-335
Tuna cooking juice from a Tunisian tuna-processing unit has a high level of polluting load: chemical oxygen demand (COD) is comprised between 4 and 20 g L−1, nitrogen kjedahl (NK) between 0.6 and 3 g L−1 and dry matter between 120 and 160 g L−1. The juice has thus to be treated before being rejected into the environment. This paper considers the nanofiltration (NF) of these concentrated organic/inorganic mixtures using an AFC 30 (NF) membrane. The work focusses on the effect of organic and inorganic matters on the permeate flux and rejections of these matters. For this purpose, mixtures of salt and organic pollution (COD), used as model solutions, were prepared by the dilution of a typical industrial tuna cooking juice. The permeate flux was found to decrease when salt and organic matter concentrations increase. The recovery rate in organic matter decreases with increasing salt or organic matter content and the recovery rate of salt decreases when the COD concentration increases. 相似文献
314.
315.
基于化工园区整体风险量分析的安全规划研究 总被引:3,自引:2,他引:1
通过对园区安全容量和危险量的分析,得到园区整体的风险评估值;提出并定义园区危安比最大临界点,用其反映园区的最大可接受风险量;运用"二八法则",确定危安比上限;当危安比在3种不同值域区间下,对应的园区安全规划的重点不同;从园区整个生命周期考虑,提出包含各个阶段的园区安全规划主要内容。 相似文献
316.
用Ames试验检测水源水和自来水中的遗传毒性 总被引:3,自引:0,他引:3
用微伤寒沙门氏菌/哺乳动物微粒体酶系的Amaes试验,研究了不同季节物水源水及管网自来水中的遗传毒性,以XAD2树脂为吸附剂,以丙酮-甲醇的混合液为洗脱液,浓率水样中的有机物,并对部分阳性水样进行有机成分的定性分析。结果发现:13个水样中有7个样品在淡需要代谢活化系统S9的情况下,可诱导鼠伤寒沙门氏菌碱基移码型菌株的回复突变;不同水样在不同季节不同的诱导作用;同时通过GC/MS方法分析,发现阳性水 相似文献
317.
This paper discusses why estimates of the benefits of reduced air pollution differ in accordance with the approach used. Estimates based on bottom-up studies of the damage costs related to air pollution usually turn out much lower than estimates based on assessments of the utility of reduced air pollution, obtained for instance by willingness to pay assessments. This is usually explained by the fact that the willingness to pay approach includes the utility aspect of non-market values, and for this reason, it is often preferred to the damage cost approach. This is, however, not the whole story. The paper shows why alternative approaches should not be considered as being in conflict, but rather as means to get supplementary information necessary to put a value on environmental quality. Information from bottom-up assessments of damage costs and from studies of the willingness to pay is used in a macroeconomic model to carry out an evaluation of the social costs of energy saving measures in Hungary. 相似文献
318.
合成麝香是一类近十多年才引起人们关注的有机污染物.合成麝香广泛分布于环境中.难降解,易生物富集,对水生生物和人体均呈现一定的生物毒性.文章对某一化妆品厂生产车闯内、外及工厂外的上、下风向大气中多环麝香进行了定性定量分析,结果表明,除ATⅡ之外,大气中检测出了五种多环麝香,其中作为对照点的上风向多环麝香总浓度为5.43ng/m3,而工厂室内、外及下风向的多环麝香浓度范围为17.25~5543.4ng/m3;气固分配实验研究发现,超过68.43%的多环麝香分布于气相中. 相似文献
319.
320.