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151.
Fate of pharmaceuticals and personal care products in wastewater treatment plants - Conception of a database and first results 总被引:1,自引:0,他引:1
C. Miège J.M. Choubert L. Ribeiro M. Eusèbe M. Coquery 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1721-1726
We created a database in order to quantitatively assess the occurrence and removal efficiency of pharmaceuticals and personal care products (PPCPs) in wastewater treatment plants (WWTPs). From 117 scientific publications, we compiled 6641 data covering 184 PPCPs. Data included the concentrations of PPCPs in WWTP influents and effluents, their removal efficiency and their loads to the aquatic environment. The first outputs of our database allowed to identify the most investigated PPCPs in WWTPs and the most persistent ones, and to obtain reliable and quantitative values on their concentrations, frequency of detection and removal efficiency in WWTPs. We were also able to compare various processes and pointed out activated sludge with nitrogen treatment and membrane bioreactor as the most efficient ones. 相似文献
152.
Existing and projected water shortages and related factors have helped focus attention on the need for water reuse. With recent technological advances in wastewater treatment, it is now possible to produce reclaimed water of any quality. Thus, the use of reclaimed water will depend on the reuse opportunities and the cost of the required infrastructure. Historically, centralized wastewater treatment facilities have served the needs of organized societies since the mid 1800s. However, as there are limited options for expansion of most existing centralized facilities, the use of satellite and decentralized wastewater management systems offers significant advantages including being close both to the source of wastewater generation and to potential water reuse applications. The comparative advantages of satellite and decentralized wastewater management systems for a number of water reuse applications are presented and discussed in this paper. Selected case studies are presented to demonstrate the utility of satellite and decentralized wastewater management. Specific issues associated with the application of such systems in existing and in new developments are examined and discussed. 相似文献
153.
Allen CD 《Environmental management》2009,43(2):346-356
Characterized by expensive housing, high socioeconomic status, and topographic relief, Upper Sonoran Lifestyle communities
are found primarily along the Wildland-Urban Interface (WUI) in the Phoenix, Arizona metro area. Communities like these sprawl
into the wildlands in the United States Southwest, creating a distinct urban fringe. This article, through locational comparison,
introduces and evaluates a new field assessment tool for monitoring anthropogenic impact on soil–vegetation interactions along
the well-maintained multi-use recreational trails in Upper Sonoran Lifestyle region. Comparing data from randomly selected
transects along other multi-use trails with data from a control site revealed three key indicators of anthropogenic disturbances
on soil–vegetation interactions: soil disturbance, vegetation disturbance, and vegetation density. Soil and vegetation disturbance
displayed an average distance decay exponent factor of −0.60, while vegetation density displayed a reverse decay average of
0.60. Other important indicators of disturbance included vegetation type, biological soil crusts, and soil bulk density. The
predictive ability of this new field tool enhances its applicability, offering a powerful rapid ecological assessment method
for monitoring long-term anthropogenic impact in the Upper Sonoran Lifestyle, and other sprawling cities along the WUI. 相似文献
154.
Sorption of alkylphenols on Ebro River sediments: comparing isotherms with field observations in river water and sediments 总被引:1,自引:0,他引:1
Navarro A Endo S Gocht T Barth JA Lacorte S Barceló D Grathwohl P 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):698-703
This study reports sorption isotherms of the endocrine disruptors nonylphenol (NP) and octylphenol (OP) in three sediment samples from the Ebro River basin (NE Spain), with organic carbon fractions (fOC) ranging from 0.0035 to 0.082 gOC g−1. All isotherms were fitted to the Freundlich model with slightly nonlinear exponents ranging from 0.80 to 0.94. The solubility of the compounds as well as the organic carbon (OC) content had the strongest influences on the sorption behavior of these compounds. Comparison of the laboratory-spiked samples with the native contamination of NP of 45 water and concurrent sediment samples resulted in reasonable matches between both data sets, even though the lowest concentrations in the field were not completely reached in laboratory tests. This good agreement indicates that sorption laboratory data can be extrapolated to environmental levels and therefore the distribution of nonylphenol between sediments and water can be predicted with a precision of one order of magnitude. Furthermore, laboratory experiments with simultaneous loading of NP and OP revealed negligible competition for sorption sites at low concentrations. 相似文献
155.
Jussi Kosonen Leif Kronberg 《Environmental science and pollution research international》2009,16(5):555-564
Background, aim and scope Each year, large quantities of pharmaceuticals are consumed worldwide for the treatment and prevention of human and animal
diseases. Although the drugs and the metabolites observed in the wastewaters and in the environment are present at concentrations
several orders of magnitude lower than the concentrations required to exert their effects in humans or animals, their long-term
impact on the environment is commonly not known. In this study, the occurrence of six antihistamines, which are used for the
relief of allergic reactions such as hay fever, was determined in sewage treatment plants wastewaters and in recipient river
waters.
Materials and methods The occurrence of the antihistamines cetirizine, acrivastine, fexofenadine, loratadine, desloratadine and ebastine in sewage
treatment plants wastewaters and in recipient river waters was studied. The analytical procedure consisted of solid-phase
extraction of the water samples followed by liquid chromatography separation and detection by a triple-quadrupole mass spectrometer
in the multiple reaction mode.
Results Cetirizine, acrivastine and fexofenadine were detected in both influent and effluent wastewater samples at concentration levels
ranging from about 80 to 220 ng/L, while loratadine, desloratadine and ebastine could not be detected in any samples. During
sewage treatment, the concentration of the antihistamines dropped by an average of 16–36%. Furthermore, elevated concentrations
of antihistamines were observed in samples collected during the season of most intensive plant pollen production, i.e. in
May. In the river water samples, the relative pattern of occurrence of cetirizine, acrivastine and fexofenadine was similar
to that in the wastewater samples; although the concentration of the compounds was substantially lower (4–11 ng/L). The highest
concentrations of the studied drugs were observed near the discharging point of the sewage treatment plant.
Discussion The highest concentrations of antihistamines in STP wastewaters correlate with the outbreak of allergic reaction caused by
high amounts of plant pollens in the air. The analysis results of the river water samples show that the antihistamines are
carried far away from the effluent discharge points. They may account for a part of the mix of pharmaceuticals and of pharmaceutical
metabolites that occur downstream of STPs.
Conclusions Antihistamines are poorly degraded/eliminated under the biological treatment processes applied in the wastewater treatment
plants and, consequently, they are continuously being discharged along with other drugs to the aquatic environment.
Recommendations and perspectives As a huge quantity and variety of drugs and their metabolites are continuously discharged to rivers and the sea, the compounds
should be considered as contaminants that may possess risks to the aquatic ecosystem. Further studies are urgently needed
on the environmental fate of the antihistamines and other pharmaceuticals in the aquatic environment. These studies should
be concerned with the stability of the compounds, their transformation reactions and the identity of the transformation products,
the distribution of drugs and their uptake and effects in organisms. On the basis of these studies, the possible environmental
hazards of pharmaceuticals may be assessed. 相似文献
156.
A.A.L. Oiffer J.F. Barker F.M. Gervais K.U. Mayer C.J. Ptacek D.L. Rudolph 《Journal of contaminant hydrology》2009,108(3-4):89-106
An anaerobic plume of process-affected groundwater was characterized in a shallow sand aquifer adjacent to an oil sands tailings impoundment. Based on biological oxygen demand measurements, the reductive capacity of the plume is considered minimal. Major dissolved components associated with the plume include HCO3, Na, Cl, SO4, and naphthenic acids (NAs). Quantitative and qualitative NA analyses were performed on groundwater samples to investigate NA fate and transport in the subsurface. Despite subsurface residence times exceeding 20 years, significant attenuation of NAs by biodegradation was not observed based on screening techniques developed at the time of the investigation. Relative to conservative tracers (i.e., Cl), overall NA attenuation in the subsurface is limited, which is consistent with batch sorption and microcosm studies performed by other authors. Insignificant biological oxygen demand and low concentrations of dissolved As (< 10 µg L− 1) in the plume suggest that the potential for secondary trace metal release, specifically As, via reductive dissolution reactions driven by ingress of process-affected water is minimal. It is also possible that readily leachable As is not present in significant quantities within the sediments of the study area. Thus, for similar plumes of process-affected groundwater in shallow sand aquifers which may occur as oil sands mining expands, a reasonable expectation is for NA persistence, but minimal trace metal mobilization. 相似文献
157.
A.O. Babatunde Y.Q. Zhao M.A. Morris 《Environmental pollution (Barking, Essex : 1987)》2009,157(10):2830-2836
Aluminium-based water treatment residual (Al-WTR) is the most widely generated residual from water treatment facilities worldwide. It is regarded as a by-product of no reuse potential and landfilled. This study assessed Al-WTR as potential phosphate-removing substrate in engineered wetlands. Results indicate specific surface area ranged from 28.0 m2 g−1 to 41.4 m2 g−1. X-ray Diffraction, Fourier transform infrared and energy-dispersive X-ray spectroscopes all indicate Al-WTR is mainly composed of amorphous aluminium which influences its phosphorus (P) adsorption capacity. The pH and electrical conductivity ranged from 5.9 to 6.0 and 0.104 dS m−1 to 0.140 dS m−1 respectively, showing that it should support plant growth. Batch tests showed adsorption maxima of 31.9 mg P g−1 and significant P removal was achieved in column tests. Overall, results showed that Al-WTR can be used for P removal in engineered wetlands and it carries the benefits of reuse of a by-product that promotes sustainability. 相似文献
158.
J. Medellín-Azuara L.G. Mendoza-Espinosa J.R. Lund J.J. Harou R.E. Howitt 《Journal of environmental management》2009,90(11):3470-3478
This paper uses simple hydro-economic optimization to investigate a wide range of regional water system management options for northern Baja California, Mexico. Hydro-economic optimization models, even with parsimonious model formulations, enable investigation of promising water management portfolios for supplying water to agricultural, environmental and urban users. CALVIN, a generalized hydro-economic model, is used in a case study of Baja California. This drought-prone region faces significant challenges to supply water to agriculture and its fast growing border cities. Water management portfolios include water markets, wastewater reuse, seawater desalination and infrastructure expansions. Water markets provide the flexibility to meet future urban demands; however conveyance capacity limits their use. Wastewater reuse and conveyance expansions are economically promising. At current costs desalination is currently uneconomical for Baja California compared to other alternatives. Even simple hydro-economic models suggest ways to increase efficiency of water management in water scarce areas, and provide an economic basis for evaluating long-term water management solutions. 相似文献
159.
Adsorption of phenol and its derivatives from water using synthetic resins and low-cost natural adsorbents: a review 总被引:1,自引:0,他引:1
In this article, the technical feasibility of the use of activated carbon, synthetic resins, and various low-cost natural adsorbents for the removal of phenol and its derivatives from contaminated water has been reviewed. Instead of using commercial activated carbon and synthetic resins, researchers have worked on inexpensive materials such as coal fly ash, sludge, biomass, zeolites, and other adsorbents, which have high adsorption capacity and are locally available. The comparison of their removal performance with that of activated carbon and synthetic resins is presented in this study. From our survey of about 100 papers, low-cost adsorbents have demonstrated outstanding removal capabilities for phenol and its derivatives compared to activated carbons. Adsorbents that stand out for high adsorption capacities are coal-reject, residual coal treated with H3PO4, dried activated sludge, red mud, and cetyltrimethylammonium bromide-modified montmorillonite. Of these synthetic resins, HiSiv 1000 and IRA-420 display high adsorption capacity of phenol and XAD-4 has good adsorption capability for 2-nitrophenol. These polymeric adsorbents are suitable for industrial effluents containing phenol and its derivatives as mentioned previously. It should be noted that the adsorption capacities of the adsorbents presented here vary significantly depending on the characteristics of the individual adsorbent, the extent of chemical modifications, and the concentrations of solutes. 相似文献
160.