油气田含油污泥处理相关标准解析

通过对目前已出台油气田含油污泥处理相关标准的解析,针对标准之间存在着适用范围不一致、检测项目名称及限值不一致、检测方法不统一以及计算基础不统一等,造成油气田环保工作者和管理者认识上的混乱,对含油污泥处理技术的选用和治理市场的管理带来诸多问题。为加快促进油气田含油污泥处理减量化、资源化、无害化技术的发展,建议尽快出台有针对性、普适性强、统一的油气田含油污泥污染控制标准,确保含油污泥处理既科学合理,又经济可行;同时制定针对性强的含油污泥污染物检测方法,检测方法统一、计算公式一致,保证结果真实可靠,具有可比性。     

Numerical study on premixing characteristics and explosion process of starch in a vertical pipe under turbulent flow

Fire and explosion accidents are frequently caused by combustible dust, which has led to increased interest in this area of research. Although scholars have performed some research in this field, they often ignored interesting phenomena in their experiments. In this paper, we established a 2D numerical method to thoroughly investigate the particle motion and distribution before ignition. The optimal time for the corn starch dust cloud to ignite was determined in a semi-closed tube, and the characteristics of the flame propagation and temperature field were investigated after ignition inside and outside the tube. From the simulation, certain unexpected phenomena that occurred in the experiment were explained, and some suggestions were proposed for future experiments. The results from the simulation showed that 60–70 ms was the best time for the dust cloud to ignite. The local high-temperature flame clusters were caused by the agglomeration of high-temperature particles, and there were no flames near the wall of the tube due to particles gathering and attaching to the wall. Vortices formed around the nozzle, where the particle concentration was low and the flame spread slowly. During the explosion venting, particles flew out of the tube before the flame. The venting flame exhibited a “mushroom cloud” shape due to interactions with the vortex, and the flame maintained this shape as it was driven upward by the vortex.     

区块链技术在环保领域的应用

近年来,区块链技术快速发展,被广泛应用于多个领域,发挥了不错的成效,比如推动公共服务质量的提升。环保领域中,区块链技术的应用处于探索阶段,还面临着诸多挑战和困难需要加以克服。环保领域对区块链技术的需求很大,若能够切实发挥技术的优势,可有效推动环保事业的发展。现结合具体研究,作如下论述。     

强磁场影响下菌株B1对染料的脱色作用

从校园土壤中筛选出一株对人工合成染料酸性红B有一定脱色能力的菌株B1(芽孢杆菌属),经过6.0、8.0、8.0T的强磁场分别作用30、15、30 min后进行了脱色试验;根据实验数据,得到染料脱色模型.结果表明,强磁场对B1具有诱变作用,能使其脱色能力得到强化.     

街道峡谷内汽车排放污染物浓度分布的观测与数值模拟

在上海某典型街道峡谷内按一定的空间布点,在一定时段内同时对各布点进行采样并做一氧化碳浓度分析,同时记录车辆种类、车流量、气象条件等,分析街道峡谷内污染物浓度的分布.运用风向频率加权(WDFW)方法,结合大气流动和污染物扩散的CFD模型进行数值模拟计算.结果表明,数值模拟结果和现场观测结果较吻合,建筑物低的一侧污染物浓度远高于建筑物高的一侧污染物浓度,两侧的污染物浓度随着高度的增加而降低.     

河南双河油泥在生物降解过程中饱和烃污染物的组成与分布

分析了河南双河油泥在微生物降解过程中烷烃的组成与分布特征,结果表明,XT-4、F-2、C-2、A-1和AB-1菌的混合菌对饱和烃组分有好的降解效果:当饱和烃含量在60~70g/kg范围时,经过120d的降解,饱和烃降解率达到66.4%,随着降解的进行,正构烷烃分布由单峰形变成了双峰形;萜烷类抗微生物降解能力强,在本实验条件下,其组成与分布没有发生显著变化。微生物对烷烃类化合物易降解顺序为:正构烷烃>类异戊二烯烃>藿烷类,C21以前的正构烷烃>C22以后的正构烷烃,姥鲛烷>植烷,Tm>Ts,藿烷>莫烷。     

Field reconnaissance and estimation of petroleum hydrocarbon and heavy metal contents of soils affected by the Ebocha-8 oil spillage in Niger Delta, Nigeria

Field reconnaissance of the Ebocha-8 oil spill-affected site at Obiobi/Obrikom in the Niger Delta region of Nigeria was carried out to assess the extent of damage to the terrestrial ecosystem and delimit the epicenter of oil spillage. Following three successive reconnaissance surveys, the area to be sampled was delimited (200 x 200 m2), and soil samples were collected using the grid method from three replicate quadrats at two depths, surface (0-15 cm) and subsurface (15-30 cm). A geographically similar area located 50 m adjacent to the oil-polluted area was used as a reference (control) site. Total hydrocarbon content (THC) and heavy metal concentrations were later determined in the laboratory by extraction and spetrophotemetric techniques. Generally, the THC of soils at surface and subsurface depths of the oil-polluted plots was 2.06 x 10(4) +/- 4.97 x 10(3) mg/kg and 1.67 x 10(3) +/- 3.61 x 10(2) mg/kg soil, respectively, (no overlap in standard errors at 95% confidence limit) while concentrations of heavy metals(Pb, Cd, V, Cu and Ni) were enhanced, especially at the surface. The high levels of THC and heavy metals may predispose the site, which hitherto served as arable agricultural land, to impaired fertility and possible conflagration. When concentrations of heavy metals reach the levels obtained in this study, they may become toxic to plants or possibly bio-accumulate, thus leading to toxic reactions along the food chain. While the spilled-oil may have contributed to the enhanced levels of the metals in the affected soils, physico-chemical properties of the soils, mobility of metals, and the intense rainfall and flooding that preceded the period of study may have also contributed in part to their enhanced concentrations. The presence of high hydrocarbon content may cause oxygen deprivation, which may result in the death of soil fauna by asphyxiation. There is, therefore, an urgent need to clear the affected site of these excess hydrocarbon deposits so as to enhance the rehabilitation process of the affected mat layer of soils. Other appropriate mitigating measures, such as subsequent monitoring of hydrocarbon levels at suitable intervals after the clean up activities, are also recommended, with reference to the findings of this study, for effective management of the affected area.     

用膨润土处理油田污水的研究进展

介绍了膨润土的基本特性及其存油田污水处理中的研究情况。天然膨润土经改性后,可吸附去除油田污水中的油、烃类衍生物、注聚残留聚合物及表面活性剂;负载金属氧化物的改性膨润土可对光催化氧化产生协同效应,提高光催化氧化油田污水中有机物的能力;在高压下将膨润土制成薄膜,对油田污水中的无机离了有一定的截留去除作用。     

磁场对酪氨酸酶活性及其催化降解酚类有机物影响的研究

研究了恒磁场对酪氨酸酶(TYR)活性及其催化降解酚类有机物的影响.结果显示,不同磁场强度(10～350 mT)处理下TYR酶活性均有提高,最佳磁场强度150mT下酶活力提高了27.1%.不同磁化时间下TYR酶活都有上升,但磁化60min后酶活上升幅度有所下降.酶经磁场处理后对温度、pH值稳定性增强,在温度为20～35 ℃、pH为5.0～10.0时均能保持较高活性,最佳温度为25℃,最佳pH为7.0;磁化后TYR酶的Michaelis常数Km为3.83 mmol·L-1,未磁化的Michaelis常数Km为2.65 mmol·L-1.磁场作用可促进TYR对酚类有机物邻苯二酚、苯酚、2,4-二氯酚的转化,反应速度依次递减,磁化处理对邻苯二酚反应的促进作用尤其明显;磁化处理后的酶对不同浓度苯酚和2,4-二氯酚的去除率均明显高于未磁化处理的酶,且随着酶用量增加,酚去除率提高.荧光发射光谱分析表明,磁化酪氨酸酶的荧光强度增强,构像发生了变化.