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91.
WU Yu-qiong WANG Chong-gang WANG Yun ZHAO Yang CHEN Yi-xin ZUO Zheng-hong 《环境科学学报(英文版)》2007,19(9):1129-1135
It has been reported that there is an interaction between Benzo[a]pyrene (BaP), a widespread carcinogenic polycyclic aromatic hydrocarbon, and tributyltin (TBT), an organometal used as an antifouling biocide. This study was therefore designed to examine the potential in vivo influence of BaP, TBT and their mixture on splenic antioxidant defense systems of Sebastiscus marmoratus. The fish were exposed to water containing environmentally relevant concentrations of BaP, TBT and their mixture. Spleens were collected for biochemical analysis after exposure for 7, 25, 50 d and after recovery for 7, 20 d. Cotreatment with BaP and TBT for 7 d potentiated the induction of glutathione peroxidase (GPx) activity by BaP or TBT alone. The cotreatment for 25 and 50 d resulted in inhibition of GPx activity, which was similar to the effect of TBT. Splenic glutathione S-transferase (GST) activities were significantly elevated in S. marmoratus exposed to BaP starting from 7 d and remained high up to 25 d. However, no further activity change was found with prolonged exposure. Cotreatment of BaP and TBT primarily inhibited the GST activity, which was similar to the effect of TBT. Cotreatment with BaP and TBT for 25 or 50 d potentiated the depletion of GSH (glutathione) by BaP or TBT alone. MDA (malondialdehyde) contents in spleen of S. marmoratus were not significantly altered compared with the control during the test period. Spleen, as an immune organ, is sensitive to exposure of BaP or TBT. It should have an effective mechanism to counteract oxidative damage. Antioxidative defense systems in spleen of S. marmoratus should be considered as potential biomarkers. Short-term exposure of BaP or TBT could result in induction of antioxidant defense system. A significant decrease of these indices, such as GSH, GST, GPx might indicate more severe contamination. 相似文献
92.
93.
An organic Rankine cycle (ORC) is generally used for converting low-grade heat into electricity. In this study, an extensive literature survey was conducted to identify current research gaps on experimental ORC systems. Specifically, there is limited experimental data and limited details on thermal and expander efficiencies of ORC systems. In order to address these gaps, the objective of this study included developing a turbine ORC with a power output exceeding 50 kW and thermal efficiency exceeding 8% for a heat source temperature < 120°C. The experimental results indicated that the system achieved a net power output of 242.5 kW and a thermal efficiency of 8.3% (the highest value for a turbine ORC system for the heat source temperature below 120°C). Thus, the study addressed the gaps identified in the research area of ORCs. 相似文献
94.
Marcela Capcarova Katarina Zbynovska Anna Kalafova Jozef Bulla Peter Bielik 《Journal of environmental science and health. Part. B》2016,51(4):236-244
The contamination of food and feed by mycotoxins as toxic metabolites of fungi is a risk not only for consumers resulting in various embarrassment regarding health status and well-being, but also for producers, companies and export market on the ground of economic losses and ruined stability of economic trade. As it is given in historical evidence, the contamination of food by mycotoxins is a topic as old as a history of mankind, finding some evidence even in the ancient books and records. Nowadays, the mycotoxins are used in modern biotechnological laboratories and are considered an agent for targeting the specific cells (e.g., defected cells to eliminate them). However, this promising procedure is only the beginning. More concern is focused on mycotoxins as abiotic hazard agents. The dealing with them, systematic monitoring, and development of techniques for their elimination from agricultural commodities are worldwide issues concerning all countries. They can be found alone or in co-occurrence with other mycotoxins. Thus, this review aims to provide widened information regarding mycotoxins contamination in environment with the consequences on health of animals and humans. The inevitability for more data that correctly determine the risk points linked to mycotoxins occurrence and their specific reactions in the environment is demonstrated. This review includes various symptoms in animals and humans that result from mycotoxin exposure. For better understanding of mycotoxin's impact on animals, the sensitivities of various animal species to various mycotoxins are listed. Strategies for elimination and preventing the risks of mycotoxins contamination as well as economical approach are discussed. To complete the topic, some data from past as historical evidences are presented. 相似文献
95.
Plaza C Xing B Fernández JM Senesi N Polo A 《Environmental pollution (Barking, Essex : 1987)》2009,157(1):257-263
Binding of two model polycyclic aromatic hydrocarbons (PAHs), phenanthrene and pyrene, by humic acids (HAs) isolated from an organic substrate at different stages of composting and a soil was investigated using a batch fluorescence quenching method and the modified Freundlich model. With respect to soil HA, the organic substrate HA fractions were characterized by larger binding affinities for both phenanthrene and pyrene. Further, isotherm deviation from linearity was larger for soil HA than for organic substrate HAs, indicating a larger heterogeneity of binding sites in the former. The composting process decreased the binding affinity and increased the heterogeneity of binding sites of HAs. The changes undergone by the HA fraction during composting may be expected to contribute to facilitate microbial accessibility to PAHs. The results obtained also suggest that bioremediation of PAH-contaminated soils with matured compost, rather than with fresh organic amendments, may result in faster and more effective cleanup. 相似文献
96.
A new direct thermal desorption-GC/MS method: Organic speciation of ambient particulate matter collected in Golden, BC 总被引:1,自引:0,他引:1
Luyi C. Ding Fu Ke Daniel K.W. Wang Tom Dann Claire C. Austin 《Atmospheric environment (Oxford, England : 1994)》2009,43(32):4894-4902
Particulate matter having an aerodynamic diameter less than 2.5 μm (PM2.5) is thought to be implicated in a number of medical conditions, including cancer, rheumatoid arthritis, heart attack, and aging. However, very little chemical speciation data is available for the organic fraction of ambient aerosols. A new direct thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS) method was developed for the analysis of the organic fraction of PM2.5. Samples were collected in Golden, British Columbia, over a 15-month period. n-Alkanes constituted 33–98% by mass of the organic compounds identified. PAHs accounted for 1–65% and biomarkers (hopanes and steranes) 1–8% of the organic mass. Annual mean concentrations were: n-alkanes (0.07–1.55 ng m−3), 16 PAHs (0.02–1.83 ng m−3), and biomarkers (0.02–0.18 ng m−3). Daily levels of these organics were 4.89–74.38 ng m−3, 0.27–100.24 ng m−3, 0.14–4.39 ng m−3, respectively. Ratios of organic carbon to elemental carbon (OC/EC) and trends over time were similar to those observed for PM2.5. There was no clear seasonal variation in the distribution of petroleum biomarkers, but elevated levels of other organic species were observed during the winter. Strong correlations between PAHs and EC, and between petroleum biomarkers and EC, suggest a common emission source – most likely motor vehicles and space heating. 相似文献
97.
The objective of this study was to assess the effects of dredging on the structure and composition of diatom assemblages from a lowland stream and to investigate whether the response of diatom assemblages to the dredging is also influenced by different water quality. Three sampling sites were established in Rodríguez Stream (Argentina); physico-chemical variables and benthic diatom assemblages were sampled weekly in spring 2001. Species composition, cell density, diversity and evenness were estimated. Diatom tolerance to organic pollution and eutrophication were also analyzed. Differences in physico-chemical variables and changes in benthic diatom assemblages were compared between the pre- and post-dredging periods using a t-test. Data were analyzed using Principal Components Analysis (PCA), non-metric multidimensional scaling (MDS) ordination and cluster analysis. The effects of dredging in the stream involve two types of disturbances: (i) in the stream bed, by the removal and destabilization of the substrate and (ii) in the water column, by generating chemical changes and an alteration of the light environment of the stream. Suspended solids, soluble reactive phosphorus and dissolved inorganic nitrogen were significantly higher in post-dredging periods. Physical and chemical modifications in the habitat of benthic diatoms produced changes in the assemblage; diversity and species numbers showed an immediate increase after dredging, decreasing at the end of the study period. Changes in the tolerance of the diatom assemblage to organic pollution and eutrophication were also observed as a consequence of dredging; in the post-dredging period sensitive species were replaced by either tolerant or most tolerant species. These changes were particularly noticeable in site 1 (characterized by its lower amount of nutrients and organic matter previous to dredging), which showed an increase in the amount of nutrients and oxygen demand as a consequence of sediment removal. However, these changes were not so conspicuous in sites 2 and 3, which already presented a marked water quality deterioration before the execution of the dredging works. 相似文献
98.
Silvina Vargas Gil Analia Becker Claudio Oddino Mónica Zuza Adriana Marinelli Guillermo March 《Environmental management》2009,44(2):378-386
Soil microbial populations can fluctuate in response to environmental changes and, therefore, are often used as biological
indicators of soil quality. Soil chemical and physical parameters can also be used as indicators because they can vary in
response to different management strategies. A long-term field trial was conducted to study the effects of different tillage
systems (NT: no tillage, DH: disc harrow, and MP: moldboard plough), P fertilization (diammonium phosphate), and cattle grazing
(in terms of crop residue consumption) in maize (Zea mays L.), sunflower (Heliantus annuus L.), and soybean (Glycine max L.) on soil biological, chemical, and physical parameters. The field trial was conducted for four crop years (2000/2001,
2001/2002, 2002/2003, and 2003/2004). Soil populations of Actinomycetes, Trichoderma spp., and Gliocladium spp. were 49% higher under conservation tillage systems, in soil amended with diammonium phosphate (DAP) and not previously
grazed. Management practices also influenced soil chemical parameters, especially organic matter content and total N, which
were 10% and 55% higher under NT than under MP. Aggregate stability was 61% higher in NT than in MP, 15% higher in P-fertilized
soil, and also 9% higher in not grazed strips, bulk density being 12% lower in NT systems compared with MP. DAP application
and the absence of grazing also reduced bulk density (3%). Using conservation tillage systems, fertilizing crops with DAP,
and avoiding grazing contribute to soil health preservation and enhanced crop production. 相似文献
99.
A decision framework for possible remediation of contaminated sediments in the River Kymijoki, Finland 总被引:1,自引:1,他引:0
Verta M Kiviranta H Salo S Malve O Korhonen M Verkasalo PK Ruokojärvi P Rossi E Hanski A Päätalo K Vartiainen T 《Environmental science and pollution research international》2009,16(1):95-105
Background, aim, and scope The paper describes the spatial contamination of the River Kymijoki, South-Eastern Finland, and the coastal region of the
Gulf of Finland with PCDD/Fs and mercury. The findings of ecotoxicologial and human health studies are also reported, including
environmental and human risk assessments. Sediments from the River Kymijoki, draining into the Gulf of Finland, have been
heavily polluted by the pulp and paper industry and by chemical industries. A wood preservative, known as Ky-5, was manufactured
in the upper reaches of the river between 1940 and 1984 causing severe pollution of river sediments with polychlorinated dibenzo-p-dioxins (PCDD) and dibenzofurans (PCDF). Moreover, the sediments have been polluted with mercury (Hg) from chlor-alkali production
and the use of Hg as a slimicide in pulp and paper manufacturing.
Materials and methods An extensive sediment survey was conducted as well as sediment transport modeling, toxicity screening of sediment invertebrates,
and a survey of contaminant bioaccumulation in invertebrates and fish. Studies on human exposure to PCDD/Fs and the possible
effects on hypermineralization of teeth as well as an epidemiological study to reveal increased cancer risk were also conducted.
An assessment of the ecological and human health risks with a null hypothesis (no remediation) was undertaken.
Results The sediment survey revealed severe contamination of river and coastal sediments with PCDD/Fs and Hg. The total volume of
contaminated sediments was estimated to reach 5 × 106 m3 and hot spots with extremely high concentrations (max 292,000 ng g−1 or 1,060 ng I-TEQ g−1 d.w.) were located immediately downstream from the pollution source (approximately 90,000 m3). Sediment contamination was accompanied by changes in benthic assemblages, but direct effects were masked by many factors.
The fish showed only slightly elevated PCDD/F levels in muscle, but orders of magnitude higher in the liver compared with
reference freshwater sites and the Baltic Sea. The concentrations in human fat did not reveal high human exposure in the Kymijoki
area in general and was lower than in sea fishermen. The relative risk for total cancer among farmers was marginally higher
(RR = 1.13) among those living close to the river, compared with farmers living further away, and the possibility of increased
cancer risk cannot be ruled out. A conservative risk assessment revealed that the present probability of exceeding the WHO
upper exposure limit of 4 pg WHO-TEQ kg−1 d−1 for PCDD/Fs and DL-PCBs was 6%. The probability of exceeding the WHO limit value of 0.23 μg kg−1 d−1 for methyl mercury was estimated to be notably higher at 62%. Based on these studies and the estimated risks connected with
different remediation techniques a general remediation plan with cost benefit analysis was generated for several sub-regions
in the river. Dredging, on-site treatment, and a close disposal of the most contaminated sediments (90,000 m3) was suggested as the first phase of the remediation. The decision regarding the start of remediation will be made during
autumn 2008.
Conclusions The sediments in the River Kymijoki are heavily polluted with PCDD/Fs and mercury from earlier chlorophenol, chlor-alkali,
and pulp and paper manufacturing. A continuous transport of contaminants is taking place to the Gulf of Finland in the Baltic
Sea. The highly increased PCDD/F and Hg levels in river sediments pose an ecotoxicological risk to benthic fauna, to fish-eating
predators and probably to human health. The risks posed by mercury exceed those from PCDD/Fs and need to be evaluated for
(former) chlor-alkali sites and other mercury releasing industries as one basis for remediation decision making.
Recommendations and perspectives The studies form the basis of a risk management strategy and a plan for possible remediation of contaminated sediments currently
under consideration in the Southeast Finland Regional Environment Centre. It is recommended that a detailed restoration plan
for the most seriously contaminated areas should be undertaken. Based on current knowledge, the restoration of the whole river
is not feasible, considering the current risk caused by the contaminated sediment in the river and the costs of an extensive
restoration project. The experiences gained in the present case should be utilized in the evaluation of PCDD/F- and mercury-contaminated
sites in other countries. The case demonstrates that the historic reservoirs are of contemporary relevance and should be addressed,
e.g., in the national implementation plans of the Stockholm Convention.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
100.
Verania Andria Angela Sessitsch 《Environmental pollution (Barking, Essex : 1987)》2009,157(12):3347-3350
For phytoremediation of organic contaminants, plants have to host an efficiently degrading microflora. To assess the role of endophytes in alkane degradation, Italian ryegrass was grown in sterile soil with 0, 1 or 2% diesel and inoculated either with an alkane degrading bacterial strain originally derived from the rhizosphere of Italian ryegrass or with an endophyte. We studied plant colonization of these strains as well as the abundance and expression of alkane monooxygenase (alkB) genes in the rhizosphere, shoot and root interior. Results showed that the endophyte strain better colonized the plant, particularly the plant interior, and also showed higher expression of alkB genes suggesting a more efficient degradation of the pollutant. Furthermore, plants inoculated with the endophyte were better able to grow in the presence of diesel. The rhizosphere strain colonized primarily the rhizosphere and showed low alkB gene expression in the plant interior. 相似文献