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91.
A random sample of 1 000 subjects (20–65 years old) from the national population of Sweden received a questionnaire; 70% (n = 695) replied, of whom 532 were occupationally active. Female gender, working with neck and/or body bent forward, arms above shoulders, and precision work tasks were predictors of musculoskeletal symptoms. Neck, shoulder, and upper back symptoms were more common in a strained situation at work (high demands, low control) (adjusted odds ratios [adjOR] 2.76, 2.80, and 2.26, respectively). Among females, neck and shoulder symptoms were more common in an iso-strain situation (high demands, low control and low social support) (adjOR 4.43 and 3.69, respectively), and low back symptoms were more common at low social support combined with a passive work situation (adjOR 3.35). No associations were found between iso-strain model and symptoms among males. In conclusion, iso-strain work situation was associated with neck symptoms among females, even when controlling for ergonomic factors.  相似文献   
92.
The formation of man-made reservoirs generates several impacts on water quality. In order to minimize some of these impacts mathematical models are currently used. This paper aims to discuss the issue associated with the degradation of plant resources (leaves, branches, barks and litter) that remain within the watershed of the new man-made lakes and parameterize a kinetic model related to decay of plant detritus. In these environments, the short-term variation of limnological parameters is mainly connected with biomass decay drowned during the filling operation. The kinetics of the degradation processes in reservoirs are discussed on the basis of information with related to detritus sources and the chemical properties of different types of compounds (i.e. labile and refractory fractions). Overall, the parameterization of the (first order) kinetic model showed that refractory fractions (ca. 86%) are predominant and the mineralization is a slow process, constituting the main route for decomposition and being affected by changes of environmental variables. The mineralization of labile and hydrosoluble compounds (ca. 14%) is responsible for the short-term water quality variation owing to decomposition; basically, the intensities of these changes depend on the labile/soluble compounds content of detritus and its chemical composition.  相似文献   
93.
Herein, we found that anthraquinone (AQ) acted as a catalyst for the rapid and effective removal of triphenylmethane dye containing tertiary amino group (TDAG). Results showed that AQ had an enhanced catalytic reactivity towards the removal of TDAG compared to hydro-quinone, which was further proved and explained using density functional theory (DFT) calculations. AQs could achieve a TDAG removal efficiency and rate of approximately 100% and 0.3583 min−1, respectively, within 20 min. Quenching experiments and electron paramagnetic resonance (EPR) tests indicated that the superoxide radical (O2•−) generated through the catalytic reduction of an oxygen molecule (O2) by AQ contributed to the effective removal of the TDAG. In addition, it was found that the electrophilic attack of the O2•− radical on the TDAG was the driving force for the dye degradation process. Decreasing the pH led to protonation of the substituted group of AG, which resulted in formation of an electron deficient center in the TDAG molecule (TDAG-EDC+) through delocalization of the π electron. Therefore, the possibility of the electrophilic attack for the dye by the negative O2•- radical was significantly enhanced. This study revealed that the H+ and the O2•− generated by the catalytic reduction of O2 have synergistic effects that led to a significant increase in the dye removal rate and efficiency, which were higher than those obtained through persulfate oxidation.  相似文献   
94.
The quantity and biochemical composition of organic matter (OM) in the sediments underlying and below oxygen minimum zone (OMZ) in the Arabian Sea were studied to provide information on the diagenetic processes of organic carbon under different environmental conditions. Concentrations of total organic carbon (TOC), total nitrogen (TN) and total hydrolysable amino acids (THAA) were significantly higher in sediments within rather than below OMZ, while those of total carbohydrates (TCHO) were slightly lower in the latter, suggesting the presence of a larger supply of labile compounds into the sea bottom at the shallower site (i.e. within OMZ). Hydrolysable amino acid and carbohydrate contribution to TOC were even lower (about 10% in surficial sediments) than the values obtained from the abyssal oligotrophic North Pacific, suggesting that OM food availability in the Oman Margin sediments within OMZ was lower than that observed at abyssal depths. The presence of the highest THAA and TCHO concentrations in the top 40?mm of the sediment core at both sites reflected the presence of bioturbation processes. In contrast with the general view of the deep sea as a stable and constant system, below OMZ in the Arabian Sea sediments, some differences were observed in the two investigated cores indicating the presence of a certain spatial variability in OM content and diagenesis.  相似文献   
95.
• Pt/CZL exhibits the optimum catalytic performance for HC and NOx elimination. • The strong PM-Ce interaction favors the oxygen mobility and DOSC. • Pd/CZL shows higher catalytic activity for CO conversion due to more Olatt species. • Great oxygen mobility at high temperature broadens the dynamic operation window. • The relationship between DOSC and catalytic performance is revealed. The physicochemical properties of Pt-, Pd- and Rh- loaded (Ce,Zr,La)O2 (shorted for CZL) catalysts before/after aging treatment were systematically characterized by various techniques to illustrate the relationship of the dynamic oxygen storage/release capacity and redox ability with their catalytic performances for HC, NOx and CO conversions. Pt/CZL catalyst exhibits the optimum catalytic performance for HC and NOx elimination, which mainly contribute to its excellent redox ability and dynamic oxygen storage/release capacity (DOSC) at lower temperature due to the stronger PM (precious metals)-support interaction. However, the worse stability of Pt-O-Ce species and volatile Pt oxides easily result in the dramatical decline in catalytic activity after aging. Pd/CZL shows higher catalytic activity for CO conversion by reason of more Olatt species as the active oxygen for CO oxidation reaction. Rh/CZL catalyst displays the widest dynamic operation window for NOx elimination as a result of greater oxygen mobility at high temperature, and the ability to retain more Rh-O-Ce species after calcined at 1100°C effectively restrains sintering of active RhOx species, improving the thermal stability of Rh/CZL catalyst.  相似文献   
96.
97.
南汇大治河化学需氧量(CODcr)含量的调查结果表明,大治河的CODcr含量逐年上升,水质从Ⅲ级水体下降到Ⅳ级水体,个别断面有恶化到Ⅴ级水源的趋势,通过分析认为CODcr含量的上升与工业废水大量不达标排放以及生活污水的乱排放有关。  相似文献   
98.
通过实验和理论计算的方法对座舱爆炸减压过程中压力变化进行了研究 ,推导了座舱减压时间的计算公式 ;并就座舱减压时间的变化对应急供氧参数进行了分析。结果表明 :减压时间与座舱的容积成正比 ,与爆炸孔的有效面积成反比 ;减压时间的不同 ,对爆炸减压峰值有影响 ,而对剩余压力、稳定值影响不大。研究结果为今后进行供氧系统的爆炸减压实验提供了依据  相似文献   
99.
详细介绍了战斗机飞行员新型YM9915加压供氧面罩和TK - 11飞行保护头盔配套的高空供氧防护性能生理评价实验结果。分析讨论了新型加压供氧面罩与飞行保护头盔配套的供氧防护性能特点 ,并针对其不足提出改进建议  相似文献   
100.
在实际工作中,运用测量过程的合并样本标准差来评定A类不确定度比较客观。本文根据JJF1059—1999《测量不确定度评定与表示》,通过实例,阐述了用稀释接种法测定水中生化需氧量不确定度的评定方法。  相似文献   
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