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511.
石油污染土壤生物修复 总被引:21,自引:0,他引:21
概述了石油降解微生物的种群组成,介绍了几种主要的石油污染土壤的生物修复技术以及这一领域的研究现状,讨论了应用前景。 相似文献
512.
混凝气浮-臭氧生物活性碳串联工艺深度处理炼油废水的应用研究 总被引:1,自引:0,他引:1
采用混凝气浮-臭氧生物活碳串联工艺深度处理炼油废水技术可行,主要污染物的去除效果明显,系统抗冲击能力强.处理费用低,具有推广价值。 相似文献
513.
饮用水消毒过程中卤代烃的形成和控制 总被引:4,自引:0,他引:4
研究了饮用水消毒过程中卤代烃形成的各种条件及控制技术。结果表明:加氯量多时卤代烃形成多、水温高时卤代烃生成快、加凝聚剂后因pH值下降能控制卤代烃形成、加氨氮后生成氯胺可进一步降低饮用水中的卤代烃。 相似文献
514.
环境中多环芳烃污染规律及其生物净化技术 总被引:22,自引:0,他引:22
综述环境中多环芳烃的毒性、分布、积累状况、迁移变化的规律及其生物净化技术研究进展,提出利用生物技术治理环境中的PAHs的思路及具体措施。 相似文献
515.
Unai?IriarteEmail author Jon?I?aki?álvarez-Uriarte Rubén?López-Fonseca Juan?Ramón?González-Velasco 《Environmental Chemistry Letters》2003,1(1):57-61
The relatively recent discovery of disinfection by-products has driven the main regulatory organisms to set maximum contaminant
levels for certain substances in drinking water. Trihalomethanes can be deemed as the most important group of by-products
in chlorinated surface waters. The present work has focused on trihalomethane formation in a full-scale water treatment plant.
We studied the effect of several factors, including ozonation, on trihalomethane levels in chlorinated treated water. The
treatment scheme also includes an ozonation step.
Electronic Publication 相似文献
516.
Zeban Shah Renato C. Veses Julio C. P. Vaghetti Vanessa D. A. Amorim Rosangela da Silva 《International Journal of Green Energy》2019,16(4):350-360
The Bio-oil was produced from the pyrolysis of agricultural wastes (Eucalyptus sawdust) and discarded soybean frying oil. The temperature of the pyrolysis system was initiated at 28°C and increased to 850°C. Atmospheric distillation of crude bio-oil was performed and a fraction at a temperature range 160–240°C (pyrolysis oil) was separated and subjected to GC-MS, 1H-NMR, TGA and FTIR analysis to identify the different properties and compounds present in pyrolysis oil. It was noticed that there was an abundance of oxygen and nitrogen containing compounds as well as other reactive species in pyrolysis oil. To reduce the amount of these species, the pyrolysis oil was subjected to hydrogenation in the presence of NiMo as a catalyst. After hydrogenation, the atmospheric distillation of hydrogenated bio-oil was performed and another fraction at temperature range 160–240°C (hydrogenated bio-oil) was separated and analyzed by the same techniques. It was noticed that during hydrogenation, more than 60% oxygenated and other reactive species were converted into hydrocarbons. Hydrogenated bio-oil showed very similar physico-chemical properties such as distillation curve, density, viscosity, freezing point, flash point, the presence of hydrocarbons and enthalpy of combustion as aviation kerosene also known as QAV-1. 相似文献
517.
Kangwei Li Chao Lin Chunmei Geng Stephen White Linghong Chen Zhier Bao Xin Zhang Yanyun Zhao Lixia Han Wen Yang Merched Azzi 《环境科学学报(英文版)》2020,32(9):14-22
A new state-of-the-art indoor smog chamber facility (CAPS-ZJU) has been constructed and characterized at Zhejiang University, which is designed for chemical mechanism evaluation under well-controlled conditions. A series of characterization experiments were performed to validate the well-established experimental protocols, including temperature variation pattern, light spectrum and equivalent intensity (JNO2), injection and mixing performance, as well as gases and particle wall loss. In addition, based on some characterization experiments, the auxiliary wall mechanism has been setup and examined. Fifty chamber experiments were performed across a broad range of experimental scenarios, and we demonstrated the ability to utilize these chamber data for evaluating SAPRC chemical mechanism. It was found that the SAPRC-11 can well predict the O3 formation and NO oxidation for almost all propene runs, with 6 hr Δ(O3 – NO) model error of –3% ± 7%, while the final O3 was underestimated by ~20% for isoprene experiments. As for toluene and p-xylene experiments, it was confirmed that SAPRC-11 has significant improvement on aromatic chemistry than earlier version of SAPRC-07, although the aromatic decay rate was still underestimated to some extent. The model sensitivity test has been carried out, and the most sensitive parameters identified are the initial concentrations of reactants and the light intensity as well as HONO offgasing rate and O3 wall loss rate. All of which demonstrated that CAPS-ZJU smog chamber could derive high quality experimental data, and could provide insights on chamber studies and chemical mechanism development. 相似文献
518.
Weiran Li Meifang Chen Yi Chen Shengrui Tong Maofa Ge Yucong Guo Yunhong Zhang 《环境科学学报(英文版)》2020,32(9):23-32
Reaction rate constants and products of 1-octen-3-one, 3-octen-2-one and 4-hexen-3-one with ozone were studied in a 100-L fluorinated ethylene propylene (FEP) Teflon film bag using absolute rate method at 298 ± 1 K and atmospheric pressure. The rate constants were (1.09 ± 0.12) × 10?17, (3.48 ± 0.36) × 10?17 and (5.70 ± 0.60) × 10?17 cm3/(molecule?sec), respectively. According to the obtained rate constants, the effects of carbonyl were discussed. The carbonyl group in β position has a net withdrawing effect with respect to an olefinic bond, then causing the decline of rate constants. The quantum chemical calculation was used to explain the results of rate constants. The products of ozonolysis were mainly aldehydes, which have significant influence on the formation of SOA, and hence play an important role in the atmosphere. In this work, we detected the main products of reaction and proposed the reaction mechanism by combining the results of quantum chemical calculations. Atmospheric lifetime for three unsaturated ketones reacted with ozone was 36.4, 11.4 and 6.9 hr for 1-octen-3-one, 3-octen-2-one and 4-hexen-3-one, respectively. 相似文献
519.
Xiaoqing Ye Wuye Pan Chunming Li Xiaochen M Shanshan Yin Jianhong Zhou Jing Liu 《环境科学学报(英文版)》2020,32(5):1-9
Polycyclic aromatic hydrocarbons (PAHs) are a typical class of persistent organic pollutants that is ubiquitous worldwide. Previous animal studies suggested that PAHs had adverse effects on female reproduction. However, the human data regarding relationship of PAHs exposure with women reproductive health, such as ovarian dysfunction, are scarce. In this case-control study, the associations of serum levels of PAHs with the risk of premature ovarian failure (POF) and reproductive hormones in Chinese women were investigated, with recruiting 157 POF patients and 217 healthy women. The serum levels of 12 types of PAHs, as well as reproductive hormones, including follicle-stimulating hormone, luteinizing hormone and anti-mullerian hormone, were determined. In the logistic regression models, most individual PAH congeners showed significantly positive correlations with the risk of POF (p < 0.05), except for fluorine and pyrene. Benzo(a)pyrene (BaP), as the most carcinogenic PAH congener, was observed to be significantly positively associated with the risk of POF. After adjustment for age, body mass index, educational levels and household income, per one-unit increase in the log-transformed BaP concentration was significantly correlated with 2.191-fold increased risk of POF (OR = 2.191, 95%CI: 1.634–2.938, p < 0.05). To the best of our knowledge, this is the first study to report an association between internal exposure levels of PAHs and the increased risk of POF in women. 相似文献
520.