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911.
The solubilization of four pairs of substituted indole compounds (SICs) by β-cyclodextrin (β-CD) in water was investigated. The results show that 1,2,3,4-tetrahydrocarbazole and N-methyl-1,2,3,4-tetrahydrocarbazole form 1:1 inclusion complexes with β-CD, while the other six SICs form 1:2 inclusion complexes, respectively. To each pair of SICs with similar structures, the differences between their solubilization in β-CD/water solutions has been explained by the difference of their contact area within the β-CD cavity, the difference of their molecule polarity, or the presence of hydrogen bond between SIC molecule and β-CD molecule. 相似文献
912.
Qianfeng Li Di Hu Sirakarn Leungsakul Richard M. Kamens 《Atmospheric environment (Oxford, England : 1994)》2007,41(40):9341-9352
This work merges kinetic models for α-pinene and d-limonene which were individually developed to predict secondary organic aerosol (SOA) formation from these compounds. Three major changes in the d-limonene and α-pinene combined mechanism were made. First, radical–radical reactions were integrated so that radicals formed from both individual mechanisms all reacted with each other. Second, all SOA model species from both compounds were used to calculate semi-volatile partitioning for new semi-volatiles formed in the gas phase. Third particle phase reactions for particle phase α-pinene and d-limonene aldehydes, carboxylic acids, etc. were integrated. Experiments with mixtures of α-pinene and d-limonene, nitric oxide (NO), nitrogen dioxide (NO2), and diurnal natural sunlight were carried out in a dual 270 m3 outdoor Teflon film chamber located in Pittsboro, NC. The model closely simulated the behavior and timing for α-pinene, d-limonene, NO, NO2, O3 and SOA. Model sensitivities were tested with respect to effects of d-limonene/α-pinene ratios, initial hydrocarbon to NOx (HC0/NOx) ratios, temperature, and light intensity. The results showed that SOA yield (YSOA) was very sensitive to initial d-limonene/α-pinene ratio and temperature. The model was also used to simulate remote atmospheric SOA conditions that hypothetically could result from diurnal emissions of α-pinene, d-limonene and NOx. We observed that the volatility of the simulated SOA material on the aging aerosol decreased with time, and this was consistent with chamber observations. Of additional importance was that our simulation did not show a loss of SOA during the daytime and this was consistent with observed measurements. 相似文献
913.
采用O3、UV/O3高级氧化法对水中六氯苯(HCB)的降解效果及机理进行了研究,并对结果进行了比较,结果表明,UV本身对HCB的去除率贡献不大,HCB可被O3、UV/O3快速降解,即UV<O3<UV/O3;O3、UV/O3作用时,提高体系的初始pH值不利于HCB的降解,在pH=3,HCB=0.2 mg/L,反应40 min时,HCB的去除可达50%左右,酸性条件下有利于降解反应的进行;无论是O3单独作用还是UV/O3联合作用,HCB的降解基本上满足准一级反应动力学规律,如果体系的pH值基本保持恒定,这种规律就更为明显。根据离子色谱(IC)、GC对六氯苯降解中间产物进行了测定,探讨了O3、UV/O3降解六氯苯的途径和机理。 相似文献
914.
新型复合球填料为沸石与悬浮球填料的有机组合体,密度约为0.92~0.97g/cm^3,比表面积为711~1185m^2/m^2,表面粗糙,物化性能稳定。在曝气量为20:1,停留时间为6h时,装有新型复合球填料的反应柱挂膜容易,成膜时间短,膜不易脱落,且生物相丰富。膜成熟时对生活污水中的氨氮和COD都有很好的去除效果,出水氨氮浓度≤2mg/L,去除率≥93%;出水COD浓度≤22mg/L,去除率≥80%。新型复合球反应柱在稳定状态处理低浓度的二级出水时,出水氨氮浓度≤2mg/L,去除率89%,出水COD浓度为10~36mg/L,去除率为48%~81%。出水水质符合GB50335-2002标准。 相似文献
915.
钛基燃烧催化剂的抗硫性能 总被引:1,自引:0,他引:1
本文研究了钛基非贵金属燃烧催化剂的硫中毒过程及载体吸硫特性。结果表明,催化剂的抗硫能力与载体吸硫量有关,不同催化剂的抗硫性能为:Cat.3>Cat.4>Cat.5>Cat.1>Cat.2,本文还讨论了硫中毒机理。 相似文献
916.
Yorianta?Sasaerila Regine?Gries Gerhard?Gries Grigori?Khaskin Skip?King Stephen?Takács Hardi?) 《Chemoecology》2003,13(2):89-93
Summary. During peak calling activity by male oil palm bunch
moths, Tirathaba mundella Walker (Lepidoptera: Pyralidae), their
hairpencils, wings or entire body were extracted in hexane. Gas
chromatographic-electroantennographic detection (GC-EAD) analyses of
hair pencil extracts revealed four compounds that consistently elicited
responses from female antennae. The NMR spectrum of isolated compound 1,
and mass spectra and retention indices of compounds 1–4 suggested that
they were (3S,6S)-2,2,6-trimethyl-6-vinyl-tetrahydro-pyran-3-ol (1),
4-hydroxy-3-methoxy-benzaldehyde (2, vanillin),
6,10,14-trimethyl-2-pentadecanone (3), and
6,10,14-trimethyl-2-pentadecanol (4). Comparative GC and GC-MS analyses
of hair pencils extract and synthetic standards confirmed these
structural assignments. Moreover, comparative chromatography of
synthetic and hairpencil-isolated 1 on a Cyclodex-B column (which
separated the four stereoisomers with baseline resolution) revealed that
male T. mundella produce the SS-stereoisomer (SS-1). In field cage
bioassay experiments in Palembang, Indonesia, synthetic SS-1 and
vanillin in combination, but not singly, attracted female T. mundella.
SS-1 plus vanillin were as effective as male T. mundella in attracting
females. Compounds 3 and 4 did not enhance the blend's attractiveness.
Received October 11 2002; accepted March 14, 2003.
R1D="
Correspondence to: Gerhard Gries, email: gries@sfu.ca 相似文献
917.
邻苯二酚2,3-双加氧酶基因克隆、定位和高效表达 总被引:8,自引:2,他引:8
采用特异性引物,以菲、芘降解菌株ZL5的代谢性质粒为模板,扩增出邻苯二酚2,3—双加氧酶(C23O)基因,将该基因和表达载体pET—30a( )连接,转化E.coli JM109(DE3),获得了高效表达的转化子,SDS—PAGE结果表明,转化子的C23O蛋白不仅在细胞内存在,而且能被分泌到胞外,薄层扫描显示,转化子细胞内和细胞外表达蛋白总量占细胞总蛋白的42%,酶活分析表明,分布在转化子细胞内、外的表达蛋白都具有较高的C23O比活力,Southern杂交将菌株ZL5的C23O基因定位在内生质粒的不同酶切片段上。图5表1参12。 相似文献
918.
S.L. Liu Y.M. Luo Z.H. Cao L.H. Wu K.Q. Ding P. Christie 《Environmental geochemistry and health》2004,26(2):285-293
Mycorrhizal and non-mycorrhizal alfalfa (Medicago sativa) was grown in pots containing soil artificially contaminated with various levels of benzo[a]pyrene (B[a]P)(0, 1, 10 and 100 mg kg–1). Soil and plants were sampled after 30, 40, 50, 60 and 90 days and compared with unlanted pots. The percentage of mycorrhizal root length colonized by Glomus caledoniun was not significantly affected by the addition of B[a]P up to 10 mg kg–1 but was significantly lower at 100 mg kg–1B[a]P compared with low concentrations (p < 0.05). There was no difference in soil polyphenol oxidase and dehydrogenase activity among the controls and applications of 1 and 10 mg kg–1 of B[a]P. However, enzyme activities were significantly higher at 100 mg kg–1B[a]P compared with the other three treatments, and there was no mycorrhizal effect. Over a period of 90 days the concentration of B[a]P in soil in which alfalfa was grown was significantly lower than in unplanted soil (p < 0.05). Degradation rates of B[a]P added at 1, 10 and 100 mg kg–1 without G. caledonium were 76, 78 and 53%, and with mycorrhizal inoculation were 86, 87 and 57%. The degradation rate in unplanted soil was significantly lower than in planted soil, and was significantly higher in medium- and low-B[a]P treatments than in the high B[a]P concentration tested. There is a possibility of enhancement phytoremediation of PAHs in rhizosphere soil with arbuscular mycorrhizal fungi. 相似文献
919.
920.
本文介绍了光、温敏核不育水稻在生态及生理生化方面取得的主要成就.着重概述了光、温敏核不育水稻雄性育性转换的光温生态条件,育性转换过程中蛋白质、氨基酸、酶活性、ATP及内源植物激素持续变化.另外,对光、温敏不育水稻研究存在的问题进行了分析. 相似文献