室内空气中污染物的检测技术

室内环境空气污染对人体健康影响很大,文中指出了影响人体健康的致病因子,分析了单个微粒的光通量和粒径之间的关系。鉴于单下颗粒的散射光信号很弱,本文提出一种方法,把激光器的内腔作为颗粒注入区,利用激光器的内腔功率谱密度远大于腔外功率密度的特点,结合先进的激光散控制理论,对空气中的颗粒进行检测。     

Watershed scale assessment of nitrogen and phosphorus loadings in the Indian River Lagoon basin,Florida

There is a growing evidence that the ecological and biological integrity of the lagoon has declined during the last 50 years, probably due to the decline in water quality. Establishment of a watershed scale seagrass-based nutrient load assessment is the major aim of water quality management in the Indian River Lagoon (IRL). Best estimate loadings incorporate wet and dry deposition, surface water, groundwater, sediment nutrient flux, and point source effluent discharge data. On the average, the IRL is receiving annual external loadings of 832, 645 and 94,476kg of total nitrogen (TN) and total phosphorus (TP), respectively, from stormwater discharges and agricultural runoff. The average internal cycling of TN and TP from sediment deposits in the IRL was about 42,640kg TN and 1050kg TPyr(-1). Indirect evidence suggests that atmospheric deposition has played a role in the ongoing nutrient enrichment in the IRL. The estimated total atmospheric deposition of TN and TP was about 32,940 and 824kgyr(-1), while groundwater contribution was about 84,920 and 24,275kgyr(-1), respectively, to the surface waters of the IRL. The estimated annual contribution of point effluent discharge was about 60,408kg TN and 7248kg TP. In total, the IRL basin is receiving an annual loading of about 1,053,553kg TN and 127,873kg TP. With these results, it is clear that the current rate of nutrient loadings is causing a shift in the primary producers of the IRL from macrophyte to phytoplankton- or algal-based system. The goal is to reverse that shift, to attain and maintain a macrophyte-based estuarine system in the IRL.     

Production of radioactive particles for use in environmental studies

This paper presents an aerosol generation technique developed to produce dry aerosol particles of various sizes from aqueous solutions of salt. The technique was tested with sodium chloride, lithium carbonate and uranyl acetate at various aqueous concentrations which produced particles in the size range of 0.13-1.37 microm Mass Median Diameter (MMD). The generated aerosols were acceptably monodisperse with a geometric standard deviation of 1.4-2. Both MMD and Mass Median Aerodynamic Diameter (MMAD) increased significantly (p<0.001) with increased concentration of the salt in solution. The technique can also be used to generate aerosols of different chemical species. The results obtained indicate that the system is convenient for use with various aerosol-forming materials, with a stable particle size distribution being maintained for a long period of steady operation. The technique was successfully applied in wind tunnel studies to simulate the release of submicron radioactive particles and their interception by crops, grass and tree canopies. The relevance and application of the technique in other areas of environmental assessment studies is discussed.     

Nitrogen Budget of a Spruce Forest Ecosystem After Six-year Addition of Ammonium Sulphate in Southwest Sweden

A nitrogen (N) budget was constructed for a period of 6 years (1988–1993) in a Norway spruce stand with current deposition of 19 kg N and 22 kg S ha⁻¹ year⁻¹. The stand was fertilized annually by addition of 100 kg N and 114 kg S ha⁻¹ (NS). Above and below ground biomass, litterfall, fine- root litter production, soil solution and net mineralization were measured to estimate pools, fluxes and accumulation of nitrogen. The average needle litterfall in control (C) and NS plots in 1993 was 2.2 and 2.5 ton ha⁻¹ year⁻¹, respectively. The fine root litter production prior to treatment (1987) was 4.4 ton ha⁻¹ year⁻¹ and after treatment (1993) it was 4.5 and 3.9 ton ha⁻¹ year⁻¹ in C and NS plots, respectively. Net N mineralization in the soil profile down to 50 cm was estimated to be 86 and 115 kg ha⁻¹ year⁻¹ in C and NS plots, respectively in 1992. During the treatment period the uptake of N in the needle biomass in C and NS plots was 29 and 77 kg ha⁻¹ year⁻¹, respectively. No N was accumulated in needles of C plot where the NS plots accumulated 34 kg ha⁻¹ year⁻¹. Of the annually added inorganic N to NS plots 47% was accumulated in the above and below ground biomass and 37% in the soil. N fluxes via fine-root litter production in the C plots were much higher (54 kg ha⁻¹ year⁻¹) than that via litterfall (29 kg ha⁻¹ year⁻¹). The corresponding values in the NS plots were 65 and 43 kg ha⁻¹ year⁻¹, respectively. Most of the net N mineralization occurred in the FH layer and upper mineral soil. It is concluded that fine root litter and litterfall play an important role in the cycling of N. Despite a high N uptake the losses of N in litterfall and fine root litter resulted in an incorporation of N in soil organic matter.     

FACTORS AFFECTING SALINITY REDUCTION IN LAKE TARPON,PINELLAS COUNTY,FLORIDA1

ABSTRACT: Following an enclosure of a sink-hole connecting Lake Tarpon to the Gulf of Mexico, the chloride concentration of lake waters decreased. Water and chloride budgets for the lake in 1975 were prepared, and predictions using the model of Lerman and Brunskill (1971) were made as to the time required for the lake to achieve fresh water status. Model verification indicated good agreement with predictions in 1976; however, data on [C1^-] for 1977 and 1978 are not as supportive of the model used. The information concerning the Lake Tarpon watershed provided by this latter fact is discussed.     

AN EXAMINATION OF LAND USE - NUTRIENT EXPORT RELATIONSHIPS1

ABSTRACT: Lake and watershed management strategies and recent environmental legislation dictate that nonpoht nutrient sources associated with storm water runoff must be assessed. Accordingly, a nutrient flu assessment for phosphorus and nitrogen is conducted through an extensive literature review of nutrient export studies. These studies are reevaluated. The nutrient export coefficients are screened according to sampling design criteria and compiled according to land use. The ecological mechanisms within each land use influencing the magnitude of nutrient flux are also discussed     

Pollution levels and characteristics of phthalate esters in indoor air of offices

The pollution status and characteristics of PAEs (phthalate esters) were investigated in indoor air of offices, and PAEs of both gas-phase and particulate-phase were detected in all the samples. The concentration (sum of the gas phase and the particulate phase) was 4748.24 ng/m³, ranging between 3070.09 and 6700.14 ng/m³. Diethyl phthalate, dibutyl phthalate, and di(2-ethylhexyl) phthalate were the most abundant compounds, together accounting for 70% of the Σ6PAEs. Dividing the particulate-phase PAEs into four size ranges (<2.5, 2.5-5, 5-10, >10 μm), the result indicated that PAEs in PM_2.5 were the most abundant, with the proportion of 72.64%. In addition, the PAE concentration in PM_2.5 correlated significantly with the total particulate-phase PAEs (R² = 0.85). Thus, the amount of PAEs in PM_2.5 can be estimated from the total amount of particulate-phase PAEs using this proportion. In a comparison between the offices and a newly decorated study room, it was found that pollution characteristics were similar between these two places. Thus, it is implied that the PAE concentration decreased by 50% 2 yr after decorating.     

Ozone concentrations, flux and potential effect on yield during wheat growth in the Northwest-Shandong Plain of China

Ozone (O₃) concentration and flux (F_o) were measured using the eddy covariance technique over a wheat field in the Northwest-Shandong Plain of China. The O₃-induced wheat yield loss was estimated by utilizing O₃ exposure-response models. The results showed that: (1) During the growing season (7 March to 7 June, 2012), the minimum (16.1 ppbV) and maximum (53.3 ppbV) mean O₃ concentrations occurred at approximately 6:30 and 16:00, respectively. The mean and maximum of all measured O₃ concentrations were 31.3 and 128.4 ppbV, respectively. The variation of O₃ concentration was mainly affected by solar radiation and temperature. (2) The mean diurnal variation of deposition velocity (V_d) can be divided into four phases, and the maximum occurred at noon (12:00). Averaged V_d during daytime (6:00–18:00) and nighttime (18:00–6:00) were 0.42 and 0.14 cm/sec, respectively. The maximum of measured V_d was about 1.5 cm/sec. The magnitude of V_d was influenced by the wheat growing stage, and its variation was significantly correlated with both global radiation and friction velocity. (3) The maximum mean F_o appeared at 14:00, and the maximum measured F_o was − 33.5 nmol/(m²·sec). Averaged F_o during daytime and nighttime were − 6.9 and − 1.5 nmol/(m²·sec), respectively. (4) Using O₃ exposure-response functions obtained from the USA, Europe, and China, the O₃-induced wheat yield reduction in the district was estimated as 12.9% on average (5.5%–23.3%). Large uncertainties were related to the statistical methods and environmental conditions involved in deriving the exposure-response functions.     

Pollution levels and characteristics of phthalate esters in indoor air of offices

The pollution status and characteristics of PAEs(phthalate esters) were investigated in indoor air of offices, and PAEs of both gas-phase and particulate-phase were detected in all the samples. The concentration(sum of the gas phase and the particulate phase) was4748.24 ng/m3, ranging between 3070.09 and 6700.14 ng/m3. Diethyl phthalate, dibutyl phthalate, and di(2-ethylhexyl) phthalate were the most abundant compounds, together accounting for 70% of the ∑ 6PAEs. Dividing the particulate-phase PAEs into four size ranges( 2.5, 2.5–5, 5–10, 10 μm), the result indicated that PAEs in PM2.5were the most abundant,with the proportion of 72.64%. In addition, the PAE concentration in PM2.5correlated significantly with the total particulate-phase PAEs(R2= 0.85). Thus, the amount of PAEs in PM2.5can be estimated from the total amount of particulate-phase PAEs using this proportion. In a comparison between the offices and a newly decorated study room, it was found that pollution characteristics were similar between these two places. Thus, it is implied that the PAE concentration decreased by 50% 2 yr after decorating.     

河流氧化亚氮产生和排放研究综述

氧化亚氮(N2O)是仅次于二氧化碳(CO2)和甲烷(CH4)的重要温室气体.由于人类活动对土地的影响导致河流系统中氮的可利用性增加,河流生态系统的N2O排放量正日益增长.本文对国内外河流水体N2O溶存浓度和饱和度、水-气界面排放通量及沉积物-水界面交换通量等数据进行了收集,并总结和分析了河流生态系统中N2O的产生机制及主要影响因子.