碳量子点掺杂氮化碳提高的光电化学阴极保护性能研究

目的研究g-C_3N_4/C-Dots-M复合材料的光电化学阴极保护性能。方法采用X射线衍射(XRD)、扫描电子显微镜(SEM)和紫外可见漫反射光谱技术对样品的晶体结构、微观形貌和光吸收性能进行表征。通过电化学测试可见光照射下g-C_3N_4/C-Dots-M复合材料光电极偶联316L不锈钢后的光电化学阴极保护电流密度和电位变化曲线,研究材料的光电化学阴极保护性能。结果可见光照射下,该偶联体系的光致混合电位下降至-0.43 V(vs. Ag/AgCl),光电化学阴极保护电流密度达到4.3μA/cm。结论得益于碳量子点优异的电子传导特性,g-C_3N_4/C-Dots-550复合材料的光电化学阴极保护性能比纯g-C_3N_4的明显增强。该复合材料在光电化学阴极保护方面展现了较大的应用潜力。     

环境样品中 PCBs 的测定

通过碱解、酸洗、萃取、净化、浓缩、脱硫等步骤处理实际样品,利用毛细管柱GC/ECD进行PCBs的定性和定量.方法定性准确,定量良好,具有较高的回收率.各同系物的方法检出限,水样为0.01～0.08ng/L;土壤样为0.003～0.03μg/kg,可以应用于土壤、沉积物、水样、油样等环境样品中PCBs的测定     

Effect of Humic Acid on the Bioavailability of γ-Hexachlorocyclohexane in Marsilea Minuta (L.)

Effect of various concentrations of humic acid (0.2 to 1%) on thebioavailability of -HCH in vegetative clones of theaquatic fern Marsilea minuta was studied in a staticexperimental bioassay system on different photoperiods. Additionof humic acid showed the reduction in the bioavailability of-HCH in all the photoperiods (72 hr light to 144 hrlight) at the interval of 16 hr light (L) and 8 hr dark (D) inboth aerial and submerged portion as compared to controlindicating its protective role in toxicity.     

多氯联苯的气相色谱/质谱/质谱(GC/MS/MS)法测定

采用气相色谱/质谱/质谱(GC/MS/MS)法测定多氯联苯(PCB),具有良好的灵敏度和选择性,在地表水样品检测时,样品只须进行简单的液液萃取-浓缩,不须任何净化过程即可上机分析,方法检出限低于ng/L级。     

Distribution of airborne particles from multi-emission source

The purpose of this work was to study the distribution of airborne particles in the surroundings of an iron and steel factory in southern Finland. Several sources of particulate emissions are lying side by side, causing heavy dust loading to the environment. This complicated multi-pollutant situation was studied mainly by SEM/EDX methodology.Particles accumulated on Scots pine bark were identified andquantitatively measured according to their element content,size and shape. As a result, distribution maps of particulateelements were drawn and the amount of different particle typesalong the study lines was plotted. Particulate emissions fromthe industrial or energy production processes were not themain dust source. Most emissions were produced from theclinker crusher. Numerous stockpiles of the industrial wastesand raw materials also gave rise to particulate emissions as aresult of wind erosion. It was concluded that SEM/EDXmethodology is a useful tool for studying the distribution ofparticulate pollutants.     

微波萃取-气相色谱/质谱法测定土壤中的有机氯农药

通过微波萃取提取土壤中的有机氯农药,萃取溶液经浓硫酸脱色、佛罗里硅土柱净化,最后用气相色谱/质谱法分析.以石英砂为基体进行加标回收测定,有机氯农药的回收率在75.5%～103%之间,检出限为0.01μg/kg.     

环境监测业务管理系统的设计与开发

以郑州市环境监测中心站监测业务流程为例,从技术路线、系统结构设计、系统功能分析和技术实现等方面分析并介绍了环境监测业务管理系统的特点和开发时需解决的技术问题。探讨了建立基于B/S结构、J2EE技术架构、创新的组件装配方式、Oracle9i数据库、中间件和多层体系结构等多项先进技术进行系统实现的设计方案。     

城市空气质量日报自动发布系统的研究与开发

详细介绍了“城市空气质量日报自动发布系统”的开发背景和开发过程 ,并对系统整体的架构和所用到的技术作了针对性的说明 ,阐明了作者对此类系统的前景和发展方向的看法。     

垃圾填埋场渗出液中有害成分的研究

研究垃圾填埋场渗出液中的有害成分。渗出液样品用适当的方法处理后 ,用气相色谱 -质谱联用方法和原子发射光谱法进行定性分析。然后用原子吸收分光光度法和反相高效液相色谱法定量测定样品中微量的 Cu、Zn、Pb、Cr、Cd、Hg、苯酚、对甲苯酚、萘、蒽     

Response of the Ascorbate-Peroxidase of Selenastrum capricornutum to Copper and Lead in Stormwaters

The green alga Selenastrum capricornutum expresses a uniqueascorbate peroxidase, that responds to copper and lead. Attemptswere made to test if this peroxidase could be used to monitor thelevels of copper and lead in natural waters. When S.capricornutum was exposed to a stormwater sample, the specificactivity of the peroxidase in the cell extract was commensuratewith the combined copper and lead contents in the sample. Theperoxidase responses were also correlated with the 96 hr biomasstoxicity assay of S. capricornutum. However, unlike thebiomass toxicity assay, the peroxidase activity was not affectedby the anions in the samples. The use of this peroxidase can beused as a marker for testing heavy metal toxicity in the water.