Relation between senior managers’ safety leadership and safety behavior in the Chinese petrochemical industry

Senior managers in organizations are authorized and obliged to maintain organizational safety. However, to date, little research has considered the relation of senior managers' safety leadership to safety behavior. This study addresses this gap by using path analysis to confirm the validity of a hypothetical model that relates six dimensions of senior managers' safety leadership to two safety behaviors through the safety climate in the petrochemical industry. A questionnaire survey was sent randomly to workers (other than senior managers) in two petrochemical companies in China, and data from 155 usable responses were compiled for the path analysis. Results indicate that in the petrochemical industry, senior managers' safety leadership has a positive impact on safety behavior, and the safety climate plays an intermediary role between them. From the perspective of the dimensions of senior managers' safety leadership and safety behavior, safety concern has the greatest positive effect on safety compliance. Moreover, safety vision has the greatest positive impact on safety participation, whereas safety inspiration and safety awards and punishment have negative effects on safety compliance. Personal character does not directly influence any dimension of safety behavior but indirectly does so by influencing the safety climate. On the basis of these results, measures of improving senior managers' safety leadership in the petrochemical industry are presented to help improve the overall safety performance of the industry. A new view is provided for the petrochemical industry in China to suggest that senior managers’ safety leadership can be treated earnestly.     

化工园区规划环评中应重点关注的问题分析——以新疆吐鲁番市沈宏化工园区为例

化工园区开发建设项目具有建设内容复杂、建设范围大、建设周期长等特点,且不确定性强,产生污染物种类多、数量大,对周边区域的环境影响复杂,其规划环境影响评价应主要依据《开发区区域环境影响评价技术导则》编制。根据化工园区开发项目的环境影响特点,选址、功能区布局、产业规划及可持续发展能力分析作为化工园区规划环评中重点关注的问题,并给予重点评价。     

资源型城市产业协同机会和能力评价研究

我国资源型城市在建设过程中为国家发展提供了大量的能源和原材料,但随着资源的耗费和受经济体制改革等因素的影响,资源型城市的发展遇到了前所未有的挑战.关注资源型城市的产业协同发展可以为资源型城市的可持续发展提供有益的借鉴.但如何发现并开展资源型城市产业协同项目尚缺乏有效的方法和途径.本文在重点关注开展产业协同影响要素的基础上,借鉴澳大利亚奎纳纳地区的产业协同实践和产业协同能力评价模型,通过国外产业协同机会确认模型的介绍,结合澳大利亚奎纳纳地区的三个产韭协同实践案例,分别介绍伴生产品协同和基本生产资料协同两种产业协同的主要实现方式.通过产业协同实现地区和产业的可持续发展.其主要的影响因素包括可行的技术、可靠的企业和运行许可.这些模型运用到实践均可促进我国资源型城市的良好发展.     

Compound specific carbon and hydrogen stable isotope analyses of volatile organic compounds in various emissions of combustion processes

This study presents carbon (δ¹³C) and hydrogen (δD) isotope values of volatile organic compounds (VOCs) in various emission sources using thermal desorption-gas chromatography-isotope ratio mass spectrometry (TD-GC-irMS). The investigated VOCs ranged from C6 to C10. Samples were taken from (i) car exhaust emissions as well as from plant combustion experiments of (ii) various C3 and (iii) various C4 plants. We found significant differences in δ values of analysed VOCs between these sources, e.g. δ¹³C of benzene ranged between (i) −21.7 ± 0.2‰, (ii) −27.6 ± 1.6‰ and (iii) −16.3 ± 2.2‰, respectively and δD of benzene ranged between (i) −73 ± 13‰, (ii) −111 ± 10‰ and (iii) −70 ± 24‰, respectively. Results of VOCs present in investigated emission sources were compared to values from the literature (aluminium refinery emission). All source groups could be clearly distinguished using the dual approach of δ¹³C and δD analysis. The results of this study indicate that the correlation of compound specific carbon and hydrogen isotope analysis provides the potential for future research to trace the fate and to determine the origin of VOCs in the atmosphere using thermal desorption compound specific isotope analysis.     

废酸的综合治理与资源化研究进展

通过对废酸处置行业的现状调查研究,探讨了双极膜法、结晶法、中和法、喷雾焙烧法、离子交换法、化学转化法等典型废酸处置工艺的特点及存在的问题。以提高环境和经济效益为前提,针对废酸处置行业普遍存在的重金属处理问题,提出将电解法、双极膜法和离子交换法等关键技术集成和改性,形成具有耐酸和重金属高效去除等能力的针对废酸特点的新工艺等建议。     

石化污水处理场排放废气中有机污染的分析与评价

采用预浓缩、气相色谱-质谱联用及脉冲火焰光度检测的方法对石化污水处理场排放的废气污染物进行了定性与定量分析,并采用相应的污染物排放标准及其人体感知嗅阈值进行了污染程度评价.结果表明,污水处理场在各个采样点位均有挥发性有机污染物和恶臭污染物检出,其中以污水进口最为严重.从检出物的浓度水平而言,苯系物和恶臭污染物均存在超标现象,而且检出的恶臭污染物浓度水平远高于人体感知嗅阈值.     

大型石化项目环境监理实践及工作方法探讨

基于某大型石化项目的环境监理实践,从环境监理方案及实施细则的编制、设计阶段环境监理、施工阶段环境监理3个方面阐述此类项目环境监理的要点及工作方法。设计阶段的主要工作是对环保设计文件、设计图纸及基础设计资料等材料的审查,审查的重点是项目的平面布置、生产规模、工艺路线、污染物特征及各污染物控制节点、环保治理设施的处理工艺及规模等与环评报告及批复的相符性。施工阶段环境监理的工作重点是施工单位环境管理、施工期环保达标监理、隐蔽工程监理、环境风险防范措施监理、环保设施符合性核查、批建相符性核查等几方面。并简要分析了环境监理成果的体现方式。     

清洁生产在铸造业应用初步分析

清洁生产是实现铸造业可持续发展的重要组成部分,提出铸造业的具体清洁生产实施措施,阐明环境管理系统的建立是实施清洁生产的重要保障。     

用循环经济理念构建沈阳西部生态工业走廊

从沈阳市建设西部工业走廊的实际出发,提出运用循环经济理念,切实实现沈阳市西部工业走廊中化工、冶金、建材三个园区内各个企业内部、各园区内部企业之间、三个园区之间的物质集成、水和能量的梯级使用与信息集成,以及资源减量化、废物资源化的目标,为沈阳市西部工业走廊建设提供了有益的建议。     

基于循环经济理念构建我国未来的造纸业

造纸工业是我国制造业中为数不多的朝阳产业,也是污染较为严重的行业。在结合目前国内外造纸业发展现状的基础上,基于循环经济理念,从三个层面上探讨了如何构建我国未来的造纸业,提出了我国未来造纸业可持续发展模式:先组织企业内部的物质循环和能量梯级利用,其次结合自身和周边环境的特点构建有效产业链,同时积极开展废纸资源的回收利用以形成社会层面上的大循环,最终实现造纸业的可持续发展。