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311.
Long-term depletion of calcium and other nutrients in eastern US forests 总被引:10,自引:0,他引:10
C. Anthony Federer James W. Hornbeck Louise M. Tritton C. Wayne Martin Robert S. Pierce C. Tattersall Smith 《Environmental management》1989,13(5):593-601
Both harvest removal and leaching losses can deplete nutrient capital in forests, but their combined long-term effects have not been assessed previously. We estimated changes in total soil and biomass N, Ca, K, Mg, and P over 120 years from published data for a spruce-fir site in Maine, two northern hardwood sites in New Hampshire, central hardwood sites in Connecticut and Tennessee, and a loblolly pine site in Tennessee. For N, atmospheric inputs counterbalance the outputs, and there is little long-term change on most sites. For K, Mg, and P, the total pool may decrease by 2%–10% in 120 years depending on site and harvest intensity. For Ca, net leaching loss is 4–16 kg/ha/yr in mature forests, and whole-tree harvest removes 200–1100 kg/ha. Such leaching loss and harvest removal could reduce total soil and biomass Ca by 20%–60% in only 120 years. We estimated unmeasured Ca inputs from rock breakdown, root-zone deepening, and dry deposition; these should not be expected to make up the Ca deficit. Acid precipitation may be the cause of current high leaching of Ca. Although Ca deficiency does not generally occur now in acid forest soils, it seems likely if anthropogenic leaching and intensive harvest removal continue. 相似文献
312.
Robert C. Borden Philip B. Bedient 《Journal of the American Water Resources Association》1987,23(4):629-636
ABSTRACT: A three well injection-production test was performed at the United Creosoting Company (UCC) site in Conroe, Texas, to estimate the effective in situ retardation factors for adsorption and to evaluate the significance of biotransformation in limiting the transport of polycydic aromatics present in the shallow aquifer. The field test was also used as a model to determine if this type of testing would be feasible at other hazardous waste sites. During the test, chloride, a non-reactive tracer and two organic compounds, naphthalene and paradichlorobenzene (pDCB), were injected into a center well for 24 hours followed by clean ground water for six days. Ground water was continuously produced from two adjoining wells and monitored to observe the breakthrough of these compounds. Data from the test were analyzed by comparing the statistical moments of the chloride and organics distributions. Retardation factors for naphthalene and pDCB were estimated to be 1.03 and 0.97 by comparison of the statistical moments. A significant loss of naphthalene and pDCB was also observed during the three well test, apparently due to biotransformation. These results suggest that biotransformation is the major process limiting the transport of naphthalene and similar compounds at the UCC site. 相似文献
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314.
采用机械球磨法对膨润土、硅藻土、高岭土3种天然黏土材料进行预处理,通过超声法将纳米TiO_2附着于其上制得复合材料,考察了不同复合材料加入量及养护时间条件下复合材料对电解锰渣中Mn的吸附固定效果。3种天然黏土材料中,硅藻土的平均粒径最小,比表面积和总孔隙度最大,对水中Mn的吸附量也最大。黏土材料附着纳米TiO_2后对电解锰渣中Mn的吸附固定效果较单纯黏土材料有明显改善。在养护时间为12 d、硅藻土附着纳米Ti O_2复合材料加入量为10%(w)的最佳条件下,Mn的TCLP浸出量较原电解锰渣下降了83.04%。 相似文献
315.
Bennett EM 《Environmental management》2003,32(4):476-487
Understanding the magnitude and location of soil phosphorus (P) accumulation in watersheds is a critical step toward managing runoff of this pollutant to aquatic ecosystems. Here, I examine the usefulness of urban–rural gradients, an emerging experimental design in urban ecology, for predicting extractable soil P concentrations across a rapidly urbanizing agricultural watershed in southern Wisconsin. I compare several measures of an urban–rural gradient to predictors of soil P such as soil type, slope, topography, land use, land cover, and fertilizer and manure use. Most of the factors that were expected to drive differences in soil P concentrations were found to be poor predictors of Bray-1 (extractable) soil P, which ranged from 4 to 660 ppm; while there were several significant relationships, most explained only a small proportion of the variation. A multiple linear regression model captured approximately 37% of the variation in the data using the urban–rural gradient, topography, land use, land cover, manure use, and soil type as predictors. There was a significant relationship between Bray-1 P concentration and each of the urban–rural gradients, but these relationships explained only between 2.6% and 3.3% of the variation in P concentrations. Extractable P concentration in soils, unlike some other ecosystem properties, is not well predicted by urban–rural gradients. 相似文献
316.
改性木屑吸附剂对印染废水的脱色性能研究 总被引:1,自引:0,他引:1
本文介绍了以廉价易得的杨树木屑为原料,经环氧氯丙烷交联,制备的一种新的生物吸附剂,研究各种反应因素(氢氧化钠浓度、环氧氯丙烷用量、反应温度、木屑粒径等)对反应过程和吸附剂性能的影响,检验了其对品红及孔雀石绿在不同条件下的吸附性能,并探讨了它的吸附动力学曲线和再生性能。 相似文献
317.
318.
Witold W. Spieszalski Harry D. Niemczyk David J. Shetlar 《Journal of environmental science and health. Part. B》2013,48(6):1117-1136
Abstract Chemical transport in soil is a major factor influencing soil and water contamination. Four soils and turfgrass thatch, representing a wide range of organic carbon OC content were studied to determine sorption Kd and Kf parameters for the insecticides chlorpyrifos and fonofos. The batch equilibrium method was used. The concentration of insecticide was measured in the solution as well as in the solid phase to determine the most accurate sorption data. Four soils and thatch were equilibrated for 24 h at 22 ± 1OC with aqueous insecticide solutions. Four concentrations of the insecticides, each <50% of their respective water solubilities, were selected for the experiments. After extraction with an organic solvent, the concentration of insecticides in the aqueous solution was determined by gas liquid chromatography using electron capture detection for chlorpyrifos, and nitrogen/phosphorus detection for fonofos. Data obtained were fitted to the log and simple linear form of the Freundlich equation. Mass balance Freundlich isotherm exponents n ranged between 0.82 and 0.93 for chlorpyrifos. 0.82 and 1.21 for fonofos, with r2 ≥ 0.97. Koc (percent of organic carbon %OC normalized Sorption coefficient) values were calculated by using experimentally developed Kd and Kf coefficients in relation to OC levels from 0.29 to 34.85%. Kd and Kf coefficients of both insecticides were positively correlated with OC (r2 ≥ 0.96). organic matter OM (r2 ≥ 0.96), and cation exchange capacity CEC (r2 ≥ 0.90). 相似文献
319.
本文研究了改性活性炭纤维对炸药废水中TNT的吸附行为。研究表明:1 mol/L HNO3改性的活性炭纤维吸附效果最好,其对炸药废水中TNT的最佳吸附条件为:吸附剂用量为0.6 g/25 m L,吸附平衡时间为60 min,升温有利于吸附进行。Langmuir和Freundlich吸附等温线均能较好地描述活性炭纤维对TNT的吸附,吸附动力学分析表明,吸附过程遵循准二级动力学规律。 相似文献
320.
构造煤孔隙结构与瓦斯耦合特性研究 总被引:2,自引:0,他引:2
利用压汞法、低温氮吸附法、瓦斯等温吸附和解吸试验对平煤八矿构造煤和共生原生结构煤进行综合分析,探讨了构造煤孔隙结构与瓦斯耦合特性.结果表明,构造煤以微孔为主,中孔和大孔相对发育且含较多细颈瓶孔,孔隙连通性差.与共生原生结构煤相比,构造煤各孔径阶段的孔容和孔比表面积都有所增加.构造煤比表面积的增加具有阶段性,即孔径< 1.2 nm时为慢增加阶段,孔径=1.2 ~ 4.9nm时为快增加阶段,孔径>4.9 nm时为稳定阶段.构造煤极限瓦斯吸附量a的增大与比表面积快增加阶段关系密切,但小于其BET比表面积的增幅.瓦斯解吸初期0~2 min内构造煤瓦斯解吸速度和解吸量明显大于共生原生结构煤,与中孔和大孔的变化一致,2 min以后瓦斯解吸迅速衰减.低煤体强度、高瓦斯含量的构造煤以气-煤共溶体形式储集更多弹性潜能,突然卸压时瓦斯膨胀能迅速释放,煤层中发育的构造煤增加了煤与瓦斯突出的危险性. 相似文献