染料废水处理的工艺实验研究

采用中和 -电解 -臭氧氧化工艺首先对高浓度染料生产工艺废水进行预处理 ,再与低浓度废水混合混凝、吸附处理。经电解正交实验设计及工艺实验确定本研究工艺实验为 :废水pH中性、电解条件为电解时间 2h ,电解电压10V ,电流密度 0 0 18A cm2 、O3氧化时间 2h、混凝剂 1#、3#浓度均为 2 5 0mg L、炉渣吸附时间 30min。总脱色率与CODCr总去除率均达 99% ,可以达标排放     

活性碳纤维吸附CS2蒸气的热力学研究

通过吸附热力学研究,计算出CS_2蒸气在活性碳纤维(ACF)上的吸附热、吸附功和吸附熵.结果表明,吸附属物理吸附范畴,所用吸附剂样品表面是不均匀的.     

Effect of sorbed and desorbed Zn(Ⅱ) on the growth of a green alga (Chlorella pyrenoidosa)

Toxic effect of Zn(Ⅱ)on a green alga(ChloreUa pyrenoidosa)in the presence of sepiolite and kaolinite was investigated.The Zn-free clays were found to have a negative impact on the growth of C.pyrenoidosa in comparison with control samples(without adding any clay or Zn(Ⅱ)).When Zn(Ⅱ)was added,the algae in the presence of clays could be better survived than the control samples,which was actually caused by a decrease in Zn(Ⅱ)concentration in the solution owing to the adsorption of Zn(Ⅱ)on the clays.When the solution system was diluted,the growth of algae could be further inhibited as compared to that in a system which had the same initial Zn(Ⅱ)concentration as in the diluted system.This in fact resulted from desorption of Zn(Ⅱ)from the zinc-contaminated clays,although the effect varied according to the different desorption capabilities of sepiolite and kaolinite.Therefore the adsorption and desorption processes of Zn(Ⅱ)played an important part in its toxicity,and adsorption and desorption of pollutants on soils/sediments should be well considered in natural eco-environmental systems before their risk of toxicity to aquatic organisms was assessed objectively.     

壳聚糖/PVA微粒上Cu2+的吸附平衡与动力学

采用粒径＜200μm、在酸碱介质中溶胀率小且能稳定存在的壳聚糖/PVA微粒对Cu2+的吸附进行了研究,结果表明,在pH 6,室温条件下,其饱合吸附量达56.0mg/g,随温度升高,吸附量降低.通过计算不同温度下各热力学参数△G0、△H0和△S0,证实该吸附为自发的放热过程.对实验数据运用相关数学模型拟合,显示等温吸附平衡符合Langmuir模型,吸附过程动力学更适合二级反应,被吸附在壳聚糖/PVA微粒上的Cu2+,可被0.01mo/L的EDTS或HNO3溶液快速地脱附出来,其洗脱率分别为85.3%和65.9%.     

Adsorption and correlation with their thermodynamic properties of triazine herbicides on soils

IntroductionAdsorptionofherbicidesonsoilfromwaterisanimportantfactoraffectingtheirfate,biologicalactivity,andpersistenceinsoil watersystem .Itisoftenaffectedbyseveralpropertiesofsoil.Betterunderstandingofadsorptionanditsaffectingfactorswillmakeitpossibletoadjusttheherbicidedosageaccordingtosoilproperties,thusreducingtheenvironmentalpollutionofherbicidesintheenvironment.Fig .1　StructuresofthreetriazineherbicidesAmongthepost emergentherbicides,triazineherbicidesaremostcommonlyusedworldwideonco…     

微型反应柱在含铬废水处理试验研究中的应用

针对镀铬车间废水,采用活性炭吸附处理法对Cr6 和Cr3 的去除效果进行了系统的试验.通过微型反应柱集成装置对穿透时间、吸附容量及活性炭再生方法进行了研究,动态试验表明该装置能有效地处理含铬废水.     

重金属在淀山湖沉积物上的吸附研究

本文以淀山湖沉积物作为研究对象 ,研究了 Cu、Zn、Pb和 Cd在淀山湖沉积物上的等温吸附和沉积物对重金属吸附的影响因素。结果表明 ,重金属 Cu、Zn、Pb和 Cd在淀山湖沉积物上的等温吸附符合 L angmuir模型 ,淀山湖沉积物对重金属饱和吸附量的大小顺序为 Zn>Cu>Pb>Cd。淀山湖沉积物的组成对重金属吸附有较大的影响 ,其中沉积物中粘粒对 Cu、Zn、Pb和 Cd的吸附最强。沉积物中有机质对 4种重金属也有较强的吸附 ,特别对 Zn的吸附最强。碳酸盐对 Zn的吸附较弱 ,而对 Cu、Pb和 Cd有较强的吸附。 p H值对重金属吸附也有较大的影响 ,吸附量随着 p H值的升高而增大。温度对吸附的影响则较小     

低床层烟炱吸附法脱硫试验及机理探讨

研究了以锅炉烟气沉降物为吸附剂的烟炱吸附法脱除SO2的工艺条件，结果表明该法较适宜的工艺条件为SO2浓度小于2400mg/L,烟气流速小于36m/h，烟气温度低于100℃，此时脱硫效率可达30％以上。初步探讨了烟炱吸附法脱硫的作用机理。     

不同前处理方法对活性炭吸附一氧化碳的影响

本文采用颗粒状活性炭（GH-A)作吸附剂，通过不同的前处理方法，以一氧化碳CO与空气的混合物为分离测定对象，用气固色谱法测定被活性炭充分吸附前、后的混合气体中CO的含量，对比评价几种前处理方法。结果表明，对CO的吸附量显著提高的前处理方法分别是研磨筛分至32—38目、酸洗、添加改性剂So而水洗则降低了活性炭吸附CO的能力。     

Possible Utilization of Silica Gel Sludge for the Removal of Phenol from Aqueous Solutions: Laboratory Studies

This paper discusses the adsorption capacity of silica gel sludge for phenol removal from aqueous solution. Kinetic experiments showed that phenol adsorption was completed after 2 h. Adsorption isotherms were measured for phenol from aqueous solution onto silica gel sludge under various pHs and temperatures. Results showed that the adsorption capacities for phenol was increased as pH decreased from 6.5 to 2. Temperature also was found to affect the adsorption isotherm. As temperature increases from 30 to 50°C, the adsorption capacity increases. The adsorption equilibrium of phenol on silica gel sludge was described by the linear Freundlich and Langmuir models. Furthermore, results showed that the isotherm parameters fit both linearized Langmuir and Freundlich adsorption isotherms. The Freundlich and Langmuir parameters at optimum pH was found as K _f=2.89, 1/n=0.23 and K _d=22.0, q _m=7.98, respectively. Whereas, for those at optimum temperature it was observed as K _f=2.87, 1/n=0.16 and K _d=20.93, q _m=7.91, respectively.