Application of a Physical Input–Output Table to Evaluate the Development and Sustainability of Continental Water Resources in Spain

Continental waters are complex resources in terms of a measurable physical quantity, and measuring them requires a good knowledge of total water availability. In this research, an accounting physical input–output table (PIOT) was applied to evaluate total water resources and gross annual availabilities at each stage of the natural-artificial water cycle. These stages are considered subsystems of a continental water resource system describing water transfers for an average year within 13 administrative basins of Spain. Water transfers between various subsystems are characterized by internal flows decreasing the water resource availabilities. The PIOT analysis establishes these internal flows, and the origins and final uses of the total resources for each subsystem. The input-output balance registered an unsustainable negative net accumulation in eight water basins. The PIOT analysis also allowed the calculation of significant indicators such as water resource developments (RDI) and their sustainable use (SUI). RDI and SUI demonstrate that groundwater is a critical resource affecting the environment (e.g., wetlands in the upper Guadiana) and the water supply (e.g., irrigation in the Segura basin). The results of this model suggest that above-/below-ground hydrological links are important when decisions have to be made in order to provide a satisfactory supply of water in Spain. The model integrates the different water basins under territorial criteria, and therefore it may be useful for the Spanish National Hydrological Plan.     

Leaching assessment of concrete made of recycled coarse aggregate: Physical and environmental characterisation of aggregates and hardened concrete

Each year, millions of tonnes of waste are generated worldwide, partially through the construction and demolition of buildings. Recycling the resulting waste could reduce the amount of materials that need to be manufactured. Accordingly, the present work has analysed the potential reuse of construction waste in concrete manufacturing by replacing the natural aggregate with recycled concrete coarse aggregate.However, incorporating alternative materials in concrete manufacturing may increase the pollutant potential of the product, presenting an environmental risk via ground water contamination.The present work has tested two types of concrete batches that were manufactured with different replacement percentages. The experimental procedure analyses not only the effect of the portion of recycled aggregate on the physical properties of concrete but also on the leaching behaviour as indicative of the contamination degree. Thus, parameters such as slump, density, porosity and absorption of hardened concrete, were studied. Leaching behaviour was evaluated based on the availability test performed to three aggregates (raw materials of the concrete batches) and on the diffusion test performed to all concrete.From an environmental point of view, the question of whether the cumulative amount of heavy metals that are released by diffusion reaches the availability threshold was answered. The analysis of concentration levels allowed the establishment of different groups of metals according to the observed behaviour, the analysis of the role of pH and the identification of the main release mechanisms. Finally, through a statistical analysis, physical parameters and diffusion data were interrelated. It allowed estimating the relevance of porosity, density and absorption of hardened concrete on diffusion release of the metals in study.     

Measurement of atmospheric nanoparticles: Bridging the gap between gas-phase molecules and larger particles

Atmospheric nanoparticles are crucial components contributing to fine particulate matter(PM2.5), and therefore have significant effects on visibility, climate, and human health. Due to the unique role of atmospheric nanoparticles during the evolution process from gas-phase molecules to larger particles, a number of sophisticated experimental techniques have been developed and employed for online monitoring and characterization of the physical and chemical properties of atmospheric nanoparticles,...     

超微淀粉基薄膜环境降解特性研究

采用物理方法制备超微淀粉，并研究了超微淀粉基薄膜的环境降解特性，结果表明，物理法制备超微淀粉没有废水产生。超微淀粉平均粒径为3.3μm，结晶度降至13.1%；超微淀粉基薄膜中淀粉质量分数可高达55％，高质量分数的超微淀粉对于薄膜的光降解有促进作用，而土埋120d后，该薄膜生物降解率达52％。     

再沸器管箱封头环焊缝裂纹形成机理研究

某化工厂的一分塔再沸器在定期检验过程中,发现材质为奥氏体不锈钢的管箱封头环焊缝存在穿透性纵向裂纹缺陷。为了进一步了解裂纹形成的原因,避免类似缺陷再次产生。本文通过对案例背景介绍,在定期检验结果的基础上,通过对缺陷部位进行取样,在实验室采用理化检验方法,结合设计和使用参数,对裂纹的形成机理进行分析并得出结论。     

预处理-生化-气浮工艺处理精制棉废水

以某精制棉生产有限公司精制棉废水处理工程为例,介绍预处理-生化处理-气浮工艺处理精制棉废水的工程应用,总结并分析了工程设计及运行经验。设计处理流量2 000 m3/d,进水CODCr,BOD5,SS质量浓度分别为1 200,623,567 mg/L;运行结果表明:经该组合工艺处理后,出水CODCr,BOD5,SS等水质指标均满足GB 8978—1996《污水综合排放标准》中的二级排放标准。     

A simple Lagrangian model to simulate temporal variability of algae in the Elbe River

We present a five-year (1997–2001) numerical simulation of daily mean chlorophyll a concentrations at station Geesthacht Weir on the lower Elbe River (Germany) using an extremely simple Lagrangian model driven by (a) water discharge, global radiation, water temperature, and (b) silica observations at station Schmilka in the upper reach of the Elbe River. Notwithstanding the lack of many mechanistic details, the model is able to reproduce observed chlorophyll a variability surprisingly well, including a number of sharp valleys and ascents/descents in the observed time series. The model's success is based on the assumption of three key effects: prevailing light conditions, sporadic limitation of algal growth due to lack of silica and algae loss rates that increase above an empirically specified temperature threshold of 20 °C. Trimmed-down model versions are studied to analyse the model's success in terms of these mechanisms.In each of the five years the model consistently fails, however, to properly simulate characteristic steep increases of chlorophyll a concentrations after pronounced spring minima. Curing this model deficiency by global model re-calibration was found to be impossible. However, suspension of silica consumption by algae for up to 10 days in spring is shown to serve as a successful placeholder for processes that are disregarded in the model but apparently play an important role in the distinctly marked period of model failure. For the remainder of the year the very simple model was found to be adequate.     

Prevalence-adjusted optimisation of fuzzy models for species distribution

Most performance criteria which have been applied to train ecological models focus on the accuracy of the model predictions. However, these criteria depend on the prevalence of the training set and often do not take into account ecological issues such as the distinction between omission and commission errors. Moreover, a previous study indicated that model training based on different performance criteria results in different optimised models. Therefore, model developers should train models based on different performance criteria and select the most appropriate model depending on the modelling objective. This paper presents a new approach to train fuzzy models based on an adjustable performance criterion, called the adjusted average deviation (aAD). This criterion was applied to develop a species distribution model for spawning grayling in the Aare River near Thun, Switzerland. To analyse the strengths and weaknesses of this approach, it was compared to model training based on other performance criteria. The results suggest that model training based on accuracy-based performance criteria may produce unrealistic models at extreme prevalences of the training set, whereas the aAD allows for the identification of more accurate and more reliable models. Moreover, the adjustable parameter in this criterion enables modellers to situate the optimised models in the search space and thus provides an indication of the ecological model relevance. Consequently, it may support modellers and river managers in the decision making process by improving model reliability and insight into the modelling process. Due to the universality and the flexibility of the approach, it could be applied to any other ecosystem or species, and may therefore be valuable to ecological modelling and ecosystem management in general.     

Impacts of environmental heterogeneity on alternative mating tactics in the threadtail damselfly

Environmental heterogeneity, including variation in the physical environment, may be key to understanding the evolution and maintenance of alternative mating tactics, but its influence is rarely examined. Males of the threadtail damselfly Protoneura amatoria reversibly use two alternative mating tactics (perching vs. hovering) and have previously been found to modulate their use of these tactics in response to variation in both light conditions and the density of ovipositing females. Here, I show that mating success payoffs of the two tactics are differentially influenced by these factors. The payoff of the perching tactic was greater than that of the hovering tactic under low light conditions and at low densities of ovipositing females. The payoff of the hovering tactic was greater under high light conditions and higher densities of ovipositing females. The differential success of the two mating tactics in response to light conditions is discussed in light of flight dynamics, vision, and predation.     

Fluid bed gasification – Plasma converter process generating energy from solid waste: Experimental assessment of sulphur species

Often perceived as a Cinderella material, there is growing appreciation for solid waste as a renewable content thermal process feed. Nonetheless, research on solid waste gasification and sulphur mechanisms in particular is lacking. This paper presents results from two related experiments on a novel two stage gasification process, at demonstration scale, using a sulphur-enriched wood pellet feed.Notable SO₂ and relatively low COS levels (before gas cleaning) were interesting features of the trials, and not normally expected under reducing gasification conditions. Analysis suggests that localised oxygen rich regions within the fluid bed played a role in SO₂’s generation. The response of COS to sulphur in the feed was quite prompt, whereas SO₂ was more delayed. It is proposed that the bed material sequestered sulphur from the feed, later aiding SO₂ generation. The more reducing gas phase regions above the bed would have facilitated COS – hence its faster response. These results provide a useful insight, with further analysis on a suite of performed experiments underway, along with thermodynamic modelling.