Determination of toxic metals in discarded Liquid Crystal Displays (LCDs)

This study focused on the determination of the toxic metal content of Liquid Crystal Displays (LCDs) present in various Waste Electrical and Electronic Equipment (WEEE). The main objective was the identification and quantification of toxic metals detected in LCD panels. An experimental procedure which involved dismantling, shredding, pulverization, digestion and chemical analysis was followed for the sorting, separation and analysis of LCD monitors from various electronic devices that are currently on the market. Nine selected devices were examined, originated from four different types of e-waste (WEEE); TVs, computers, mobile phones and tablets. Eleven metals were measured in all examined samples. In addition, concentration values of chromium (Cr), cadmium (Cd), lead (Pb) and mercury (Hg) were compared with the respective limits set by the RoHS 2002/95/EC Directive that was recently renewed by the 2012/19/EU recast. The comparison revealed that the examined toxic metals on LCD panels did not exceed the limits set by the European Union (EU). Furthermore, when results were compared to the TTLC regulatory limits it was revealed that in three samples As concentrations were higher than the limit. Finally, when the TCLP test was implemented the aforementioned samples did not exhibit proportionally elevated values in their leachates.     

The comparative effectiveness of persuasion,commitment and leader block strategies in motivating sorting

Household waste management has become essential in industrialized countries. For the recycling programs to be a success, all citizens must comply with the developed residential procedures. Governmental bodies are thus dependent on as many people as possible adhering to the sorting systems they develop. Since the 1970s oil crisis, governments have called upon social psychologists to help develop effective communication strategies. These studies have been based on persuasion and behavioral commitment (Kiesler, 1971). Less common are studies based on developing participative communication (Horsley, 1977), a form of communication that relies on individuals to pass on information. After going through the main communication perspectives as they relate to the sorting of household waste, a comparative field study will be presented on the effectiveness of persuasive, committing and participative communication. Participative communication relied on users to pass along information to their neighbors. The results show that the participants who spread information in this way, along with those who made a commitment, changed their behavior to a greater degree than the other participants.     

Future waste treatment and energy systems – examples of joint scenarios

Development and use of scenarios for large interdisciplinary projects is a complicated task. This article provides practical examples of how it has been carried out in two projects addressing waste management and energy issues respectively. Based on experiences from the two projects, recommendations are made for an approach concerning development of scenarios in projects dealing with both waste management and energy issues. Recommendations are given to develop and use overall scenarios for the project and leave room for sub-scenarios in parts of the project. Combining different types of scenarios is recommended, too, in order to adapt to the methods and tools of different disciplines, such as developing predictive scenarios with general equilibrium tools and analysing explorative scenarios with energy system analysis tools. Furthermore, as marginals identified in differing future background systems determine the outcomes of consequential life cycle assessments (LCAs), it is considered advisable to develop and use explorative external scenarios based on possible marginals as a framework for consequential LCAs. This approach is illustrated using an on-going Danish research project.     

Environmental and economic impact assessment of construction and demolition waste disposal using system dynamics

Construction and demolition wastes (CDW) have increasingly serious problems in environmental, social, and economic realms. There is no coherent framework for utilization of these wastes which are disposed both legally and illegally. This harms the environment, contributes to the increase of energy consumption, and depletes finite landfills resources. The aim of this paper is to evaluate the impacts of two alternatives for the management of CDW, recycling and disposing. The evaluation is carried out through developing a dynamic model with aid STELLA software by conducting the following steps: (1) quantifying the total cost incurred to mitigate the impacts of CDW landfills and uncollected waste on the environment and human health; (2) quantifying the total avoided emissions and saved energy by recycling waste; (3) estimating total external cost saved by recycling waste and; (4) providing a decision support tool that helps in re-thinking about waste disposal. The proposed evaluation methodology allows activating the stringent regulations that restrict waste disposal and developing incentives to encourage constructors to recycle their wastes. The research findings show that recycling CDW leads to significant reductions in emissions, energy use, global warming potential (GWP), and conserves landfills space when compared to disposal of wastes in landfills. Furthermore, the cost of mitigating the impact of disposal is extremely high. Therefore, it is necessary to recycle construction and demolition wastes.     

An analysis of the use of life cycle assessment for waste co-incineration in cement kilns

Life cycle assessment, LCA, has become a key methodology to evaluate the environmental performance of products, services and processes and it is considered a powerful tool for decision makers. Waste treatment options are frequently evaluated using LCA methodologies in order to determine the option with the lowest environmental impact. Due to the approximate nature of LCA, where results are highly influenced by the assumptions made in the definition of the system, this methodology has certain non-negligible limitations. Because of that, the use of LCA to assess waste co-incineration in cement kilns is reviewed in this paper, with a special attention to those key inventory results highly dependent on the initial assumptions made. Therefore, the main focus of this paper is the life cycle inventory, LCI, of carbon emissions, primary energy and air emissions. When the focus is made on cement production, a tonne of cement is usually the functional unit. In this case, waste co-incineration has a non-significant role on CO₂ emissions from the cement kiln and an important energy efficiency loss can be deduced from the industry performance data, which is rarely taken into account by LCA practitioners. If cement kilns are considered as another waste treatment option, the functional unit is usually 1 t of waste to be treated. In this case, it has been observed that contradictory results may arise depending on the initial assumptions, generating high uncertainty in the results. Air emissions, as heavy metals, are quite relevant when assessing waste co-incineration, as the amount of pollutants in the input are increased. Constant transfer factors are mainly used for heavy metals, but it may not be the correct approach for mercury emissions.     

Recycling in Brazil: Challenges and prospects

This article presents a comparative analysis of the performance in formal and informal areas that deal with solid waste in Brazil. The article demonstrates that there has been significant progress in areas related to recycling and that this progress has been based mainly on informality and on the precarious labour conditions for the pickers of recyclable materials. The article also focuses on the problems found in the model for waste recovery that is being implemented in Brazil and that is based on allocation of precarious waste recovery facilities; this model has mostly small operational capabilities even in large municipalities. These problems are discussed in contrast to the great challenges imposed by the new legal framework of the country. Finally, the article proposes a categorisation of the technological models of material recovery facilities (MRFs) based on their degree of automation and nominal capacities in a manner similar to that used worldwide for incineration plants.     

Facilitating access to the algal economy: Mapping waste resources to identify suitable locations for algal farms in Queensland

Algae offer a multiple-benefit opportunity as the products that can result from algal cultivation are numerous and diverse. However, commercial production of algal-derived materials is scarce and in Queensland Australia is virtually non-existent, partly due to challenges around readily available resources. In this work, the potential to regionally recycle waste nitrogen (N), phosphorus (P) and CO₂ to support algal production is considered. A feature of the work is mapping the availability of the three resources for algal cultivation (N, P and CO₂) together with climatic and land use considerations. Mapping resolution is defined by the boundaries of Queensland's (Australia) regional authorities. Layering the maps enables identification of regional hotspots for growing algae. Waste resources are shown to be most abundant in Mackay, Burdekin, Toowoomba, Cassowary and Bundaberg; regions which also have favourable eco-climatic conditions. Waste nitrogen is the limiting waste stream, in these and most other regions however additional requirements can be fixed atmospherically, whereas waste CO₂ is shown to be abundant relative to waste nutrients. It is found that, based on the availability of waste phosphorus, the top 5 most suitable regions have sufficient resources to produce around 1.1 million t/y of algal biomass. This could potentially produce 309 ML of biodiesel which is 5% of Queensland's 2011 diesel oil sales. The outcomes of this work highlight new opportunities for industrial ecology in non-urban regions.     

Coupling magnetic particles with flocculants to enhance demulsification and separation of waste cutting emulsion for engineering applications

Magnetic particles were coupled with a flocculant to enhance the demulsification and separation of waste cutting emulsions. The optimal magnetic particle size and critical magnetic field conditions were investigated to achieve large-scale engineering application of magnetic demulsification separation for waste cutting emulsion treatment. The micro-scale magnetic particles were found to show comparable effects to nano-scale magnetic particles on enhancing the demulsification and separation of cutting emulsions, which are beneficial for broadening the selectivity of low-cost magnetic particles. The critical magnetic separation region was determined to be an area 40 mm from the magnetic field source. Compared to the flocculant demulsification, the magnetic demulsification separation exhibited a significant advantage in accelerating flocs–water separation by decreasing the separation time of flocs from 180–240 min to less than 15 min, compressing the flocs by reducing the floc volume ratio from 60%–90% to lower than 20%, and showing excellent adaptability to the variable properties of waste cutting emulsions. Coupled with the design of the magnetic disk separator, continuous demulsification separation of the waste cutting emulsion was achieved at 1.0 t/hr for at least 10 hr to obtain clear effluent with 81% chemical oxygen demand removal and 89% turbidity reduction. This study demonstrates the feasibility of applying magnetic demulsification separation to large-scale continuous treatment of waste emulsion. Moreover, it addresses the flocs–water separation problems that occur in practical flocculant demulsification engineering applications.     

废旧轮胎在国内外道路工程中的应用现状

汽车工业的发展和汽车数量的增加,在给人民生活带来方便的同时,也产生了大量的废旧轮胎。废旧轮胎的堆积和不当处理,将对生态环境带来严重的污染,国内外学者对废旧轮胎的综合利用开展了大量的研究,将废旧轮胎经粉碎等处理制成橡胶沥青,应用于道路工程不仅提高了道路的耐热等性能,而且减少了生态环境污染,具有良好的社会效益、经济效益和环境效益。本文介绍了国内外对废旧轮胎在道路工程中的应用情况,通过与国外研究和工程实践的对比,指出了我国在此方面研究中存在的问题,为进一步废旧轮胎在道路工程中综合利用提供指导作用。