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811.
812.
813.
Yu Zhang Jiayi Tang Weijun Zhang Jing Ai Yanyang Liu Qiandi Wang Dongsheng Wang 《环境科学学报(英文版)》2021,33(8):83-96
In this work, we employed waste activated sludge (WAS) as carbon source to prepare ultrahigh specific surface area (SSA) biopolymers-based carbons (BBCs) through alkali (KOH) treatment coupled to pyrolysis strategy. Before the pyrolysis process, the involvement of KOH made a great recovery of soluble biopolymers from WAS, resulting in highly-efficient catalytic pyrolysis. The Brunner-Emmett-Teller and pore volume of BBCs prepared at 800°C (BBC800) reached the maximum at 2633.89 m2·g?1 and 2.919 m3·g?1, respectively. X-ray photoelectron spectroscopy suggested that aromatic carbon in the form of C=C was the dominant fraction of C element in BBCs. The N element in BBCs were composed of pyrrolic nitrogen and pyridinic nitrogen at 700°C, while a new graphitic nitrogen appeared over 800°C. As a refractory pollutant of wastewater treatment plants, tetracycline (TC) was selected to evaluate adsorption performance of BBCs. The adsorption behavior of BBCs towards TC was conformed to the pseudo-second-order kinetic and the Langmuir models, signifying that chemisorption of monolayers was dominant in TC adsorption. The adsorption capacity of BBC800 reached the maximum at 877.19 mg·g?1 for 90 min at 298 K. Thermodynamic analysis indicated that the adsorption process was endothermic and spontaneous. Hydrogen bonding and π-π stacking interaction were mainly responsible for TC adsorption, and interfacial diffusion was the main rate-control step in adsorption process. The presence of soluble microbial products (SMPs) enhanced TC removal. This work provided a novel strategy to prepare bio-carbon with ultrahigh SSA using WAS for highly-efficient removal of organic pollutants. 相似文献
814.
Chiemchaisri C Chiemchaisri W Kumar S Hettiaratchi JP 《Environmental monitoring and assessment》2007,135(1-3):41-48
Solid waste characteristics and landfill gas emission rate in tropical landfill was investigated in this study. The experiment
was conducted at a pilot landfill cell in Thailand where fresh and two-year-old wastes in the cell were characterized at various
depths of 1.5, 3, 4.5 and 6 m. Incoming solid wastes to the landfill were mainly composed of plastic and foam (24.05%). Other
major components were food wastes (16.8%) and paper (13.3%). The determination of material components in disposed wastes has
shown that the major identifiable components in the wastes were plastic and foam which are resistant to biodegradation. The
density of solid waste increased along the depth of the landfill from 240 kg m−3 at the top to 1,260 kg m−3 at the bottom. Reduction of volatile solids content in waste samples along the depth of landfill suggests that biodegradation
of solid waste has taken place to a greater extent at the bottom of the landfill. Gas production rates obtained from anaerobic
batch experiment were in agreement with field measurements showing that the rates increased along the depth of the landfill
cell. They were found in range between 0.05 and 0.89 l kg−1 volatile solids day−1. Average emission rate of methane through the final cover soil layer was estimated as 23.95 g−2day−1 and 1.17 g−2day−1 during the dry and rainy seasons, respectively. 相似文献
815.
A reliable estimate of the quantity of solid waste generation in the city is very important for proper solid waste planning
and management. However, reported estimates of solid waste generation vary widely and lead to questionability. The reported
values have been derived on the assumption of demography, standard rate of waste generation by households, density values,
number of trucks engaged for waste transportation and monitoring of truck movement at dump sites, etc. This diverse nature
of the available data and the question of accuracy necessitate a rigorous study that has tried to document the waste quantity
in the recently formulated master plan of Dhaka City. The socio-economic parameters, behavioral characteristics, generation
sources, seasonality, and per capita growth rate are considered in estimating the waste quantity along with its future projections.
The findings from the estimation of waste quantities state that seasonal differences in the municipal solid waste stream are
not substantial. The most seasonably variable material in the municipal solid waste stream is food waste. Residential waste
is relatively homogeneous. Although there are some differences in waste generation depending on demographic and other local
factors, most households dispose of essentially similar types of wastes. Variation occurs in waste composition dependent upon
income levels and category of sources. Variation also occurs based upon the extent of source reduction and recycling opportunities.
As opportunities exist to recycle wastes, the recycling facilities might have to grow at a similar pace to the generation
of waste. Physical and chemical characteristics of solid waste are important to implement the waste disposal and management
plan for the selection of resource and energy recovery potentials. A number of studies have been conducted to determine the
composition of wastes including moisture content and calorific value. The data show that the moisture content in city waste
is significantly higher and the calorific value is much lower, which determines the viability of composting or anaerobic digestions
rather than waste combustion. 相似文献
816.
从环保角度入手,着重调查沈阳市全市范围内殡葬行业现有状况,重点研究了火化机焚烧尸体后产生的废气污染问题,并提出几点对策和建议。监测结果表明,烟尘、二氧化硫和氮氧化物等废气污染物的排放浓度超过国家标准要求。 相似文献
817.
电感耦合等离子体原子发射光谱法测定废水中的铊 总被引:2,自引:0,他引:2
采用电感耦合等离子体原子发射光谱仪(ICP-AES)测定废水中铊,并对测定波长、介质及其酸度、共存元素干扰等因素进行分析和条件优化,使该方法在0 mg/L~5.00 mg/L范围内线性良好,相关系数为0.999 9。方法检出限为22μg/L,该方法对铊标准样品测定的结果在保证值范围内,4份废水样7次测定结果的RSD为0.2%~0.8%,实际废水样品的加标回收率为98.0%~100%。 相似文献
818.
废酸的综合治理与资源化研究进展 总被引:2,自引:0,他引:2
通过对废酸处置行业的现状调查研究,探讨了双极膜法、结晶法、中和法、喷雾焙烧法、离子交换法、化学转化法等典型废酸处置工艺的特点及存在的问题。以提高环境和经济效益为前提,针对废酸处置行业普遍存在的重金属处理问题,提出将电解法、双极膜法和离子交换法等关键技术集成和改性,形成具有耐酸和重金属高效去除等能力的针对废酸特点的新工艺等建议。 相似文献
819.
选取我国废弃电器电子产品中回收处理数量最多、获得政策基金补贴最多的电视机产品,通过对其销量、最长使用年限、报废高峰期、报废系数的分析,采用市场供给A模型测算其报废产生量,并进一步对废弃电视机产生量测算结果与实际处理量做对比分析,提出废电视机产生量的修正方法。最终测算得到废电视机产生量为4 213万台,与同年电视机的实际处理量持平。 相似文献
820.