IMPROVEMENT OF LEACHATE PREDICTION THROUGH MUNICIPAL SOLID WASTE LAYERS1

ABSTRACT: Existing leachate prediction models over- or underestimate leachate generation by up to three orders of magnitude. Practical experiments show that channeled flow in waste leads to rapid discharge of large leachate volumes and heterogeneous moisture distributions. In order to more accurately predict leachate generation, leachate models must be improved. To predict moisture movement through waste, the one-domain water balance model HELP, and two-domain PREFLO, are tested. Experimental waste and leachate flow values are compared with model predictions. When calibrated with experimental parameters, the HELP model yields reasonable predictions of cumulative leachate flow and PREFLO provides estimates of breakthrough time. In the short term, field capacity has to be reduced to 0.12 and effective storage and hydraulic conductivity of the waste must be increased to 0.2 and 2.2 cm/s respectively. In the long term, a new modeling approach must be developed to adequately describe the moisture movement mechanisms.     

垃圾渗滤液-沉积污泥微生物燃料电池的产电性能

采用单室沉积型微生物燃料电池（SMFC）处理垃圾渗滤液与沉积污泥,考察电池的产电性能及污染物去除效果。SMFC输出电压呈周期性变化趋势,最大输出电压251 mV,最大功率密度为10.35 mW·m-2,功率密度随电流的增加先增大后减小,燃料电池内阻为2 653Ω。COD、氨氮去除率分别达96.18%和80.60%。SMFC的平均输出电压随污染物的降解呈波浪型上升趋势。MLSS、MLVSS去除率分别为24.40%和30.32%。实验结束后,MLVSS/MLSS的比值由0.70降至0.65,在SMFC产电过程中,污泥中的有机物得到有效降解。因此,SMFC可实现污水净 化、污泥减量及产电一体化的效果。     

Co-Cu双金属氧化物活化过一硫酸盐去除水中磺胺甲噁唑

采用钴铜双金属氧化物(Co-Cu)为催化剂,活化过一硫酸盐(PMS)降解水中的磺胺甲噁唑(SMX).使用场发射扫描电镜(FESEM)、透射电镜(TEM)、X射线光电子能谱(XPS)、X射线衍射(XRD)对催化剂的形貌和元素组成进行表征.考察了催化剂和PMS浓度、无机阴离子和富里酸(FA)对Co-Cu/PMS体系降解SMX的影响.结果表明,当pH为7.0时,在催化剂用量为50mg·L-1,PMS浓度为0.5 mmol·L-1条件下,50 mg·L-1 的SMX在30 min内去除率为95.6％,增加PMS浓度或提高催化剂用量均可加快SMX的降解速率.水中FA与HCO3-对SMX的去除率有一定的抑制作用,而Cl-和SO42-对反应无影响.淬灭实验与电子顺磁共振(EPR)结果显示,硫酸根自由基(SO4-)和单线态氧(1O2)为Co-Cu/PMS体系中主要的活性氧物种(ROS).XPS分峰结果表明,在钴铜双反应活性中心中Cu+/Cu2+循 环是活化PMS的主要成分.     

Waste Management in Guangdong Cities: The Waste Management Literacy and Waste Reduction Preferences of Domestic Waste Generators

A questionnaire survey was conducted in 2002 on 1365 households in two prefectural-level cities in the Pearl River Delta, Jiangmen and Zhongshan. Three groups of issues are covered in this paper: 1) waste management literacy, concerns, and public participation; 2) waste recycling practices and the potential for waste avoidance; and 3) public environmental literacy. This study confirms findings from previous surveys and provides new information on important issues such as imposing monetary charges on waste and environmental activities, littering, source separation programs (SSPs), and public participation and expectations in local waste management. Saving up recyclable materials for redemption in waste depots is commonly practiced in mainland China regardless of the level of development of a city, although at the household level, high-income families tend to place less value on the revenues to be gained from redemption than lower income groups do. Data from the previous and the present studies indicate that such voluntary but largely economically driven waste recovery behavior diverts at least 10% of the household waste from the waste stream. Although uncompensated SSP is less appealing in the two cities than compensated SSP, it was found that when the median per capita income of a city reaches RMB2000 per month, a high participation rate for uncompensated waste recovery is more likely to occur. Education and income levels are the chief factors affecting littering behavior and the potential for waste avoidance. Contrary to general belief, the local Chinese community is active in microwaste management. The concern, however, is over the inability of the grassroots bureaucracy to deal with rising expectations for waste collection services and neighborhood cleanliness.     

谈高效节能的褐煤应用技术

褐煤,一种煤化程度较低的易燃化石,在全球的煤炭储量中占据40％。在目前全球以化石能源为主体的结构下,褐煤的综合利用越来越受到世界能源专家的重视。本文主要讨论褐煤在发电、深加工等方面的节能利用技术。     

等离子体热解气化有机废弃物制氢的关键技术分析

等离子体热解气化有机固体废物制氢是一种先进高效的废物处理及资源化利用技术.首先,本文讨论了等离子体热解气化有机废弃物的机理,也概括了等离子体发生器的类型及其特点,其次分析了等离子体处理固体废弃物的影响因素,认为输入功率和载气类型等是影响等离子体处理的主要因素,最后总结了等离子体处理医疗垃圾、农林生物质、污泥等的应用现状与前景,指出等离子体热解气化固体废弃物是一种很有潜力的制氢方法.     

流动人口居留意愿的梯度变动与影响机制

随着城乡利益格局的变化,新生代流动人口的居留意愿呈现出新的特征,其变动与城市类型密切相关。利用调查数据进行分析,发现新生代流动人口的居留意愿表现出随流入地的城市类型而梯度变动的特征,即呈现出在大城市的居留意愿强,中小城市的流动性强和特大城市的返乡意愿强的特征,大城市是新生代流动人口实现留城理想与个人发展最佳的平台。但是总的来说,新生代流动人口的流动行为与第一代流动人口同中存异,没有出现根本性的改变。利用多层模型,对新生代流动人口居留意愿的影响机制进行了实证分析,发现城市类型、经济收入、社会融入与身份认同、家庭迁居、户籍可获得性是影响居留意愿的重要因素。此外,户籍可获得性与新生代流动人口身份认同交互作用显著的影响了新生代流动人口的居留意愿,并进一步增强了居留意愿在不同城市类型的差异。这体现出户籍制度对流动者的影响逐步由早期的福利隔绝向心理隔绝转变。对不同城市类型新生代流动人口居留意愿的差异进行量化分析发现,特大城市和大城市流动者的居留意愿呈现刚性,而超大城市和中小城市流动者居留意愿具有弹性。根据上述分析提出政策建议:将大城市作为吸纳流动人口的主导区域构建城市发展规划策略,发挥特大城市和大城市的集聚效应,促进区域的产业发展;在城市社区建设和城市文明建设方面,为流动人口与城市居民的相互融合提供政策支持;依托政府、社会组织与学校,提升新生代流动人口的人力资本。