进水渗滤液总氮和BOD5/TN对填埋场反应器反硝化和厌氧氨氧化协同脱氮的影响

晚期垃圾渗滤液具有氨氮浓度较高、碳氮比(C/N)较低和可生化性差的特点,生物脱氮较困难.本文研究了改变进水总氮负荷和BOD5/TN比值对填埋场生物反应器处理垃圾渗滤液的脱氮效果的影响.结果表明,总氮负荷为15~25g·(m3·d)-1的范围内时,总氮去除负荷稳定为10~12 g·(m3·d)-1,但是总氮去除率随着负荷的增加从67.7%下降至60.2%,说明在一定范围总氮负荷的增加会降低总氮去除率,但不会影响去除负荷.当改变进水的BOD5/TN从0.3提高到0.4后,总氮负荷为9 g·(m3·d)-1时的厌氧、准好氧反应器,总氮去除率可从79.9%分别提高到89.9%和86.2%,表明提高BOD5/TN能够有效促进填埋场生物反应器对总氮污染物的去除,并且厌氧条件下效果更好.脱氮途径分析表明,填埋场生物反应器中厌氧氨氧化和反硝化作用可以协同脱氮.     

厌氧氨氧化与反硝化协同脱氮处理城市污水

利用ABR反应器在温度为27℃,p H为8,HRT为10 h,进水NO-2-N/NH+4-N为1.32条件下,在45 d内成功启动厌氧氨氧化反应,稳定阶段反应器出水TN平均去除率为83%,此阶段的三氮比ΔNH+4-N∶ΔNO-2-N∶ΔNO-3-N为1∶1.31∶0.27.在利用厌氧氨氧化反应器处理实际污水过程中,进水中不可避免地含有一定量的有机碳.在C/N比为0.5时,有机碳对厌氧氨氧化反应无明显影响;厌氧氨氧化菌与反硝化菌的最佳协同作用条件为C/N=1,此时TN平均去除率为93%;在C/N比为2时有机碳会对厌氧氨氧化菌产生抑制作用,导致TN去除率降低;降低进水COD浓度后,厌氧氨氧化菌能在短时间内恢复活性.考察了厌氧氨氧化与反硝化协同作用对城市污水的处理性能,证明ABR协同脱氮反应器适用于处理低氨氮浓度城市污水,出水TN浓度为7.5 mg·L-1左右,平均去除率达86%.     

Identifying and quantifying nitrogen and phosphorus loadings from agriculture and livestock waste in the Penios River Basin District

The nitrogen and phosphorus loadings coming from diffuse, non-point pollution sources related to agriculture and animal husbandry in the Penios river basin in the region of Thessaly, Greece, were estimated. Detailed data on types of crops and field area as well as types and numbers of animals bred in the municipal districts included in the Penios River Basin District were collected from agricultural cooperatives and rural agencies in Thessaly. Related nitrogen and phosphorus loadings were calculated and all data were mapped in a geographic information system (GIS) environment to show how diffuse pollution is spatially distributed in the Penios basin and to identify areas with the highest anthropogenic pressures. This type of data is useful to a driving forces–pressures–state–impacts–responses (DPSIR) analysis – a tool suitable for the analysis of environmental decisions in the direction of sustainable development.     

贵金属负载TiO_2光催化降解甲苯研究

采用Degussa P25 TiO2粉末,利用光沉积法制备贵金属负载光催化剂M/TiO2(M分别为Pt、Pd、Ag和Au)。通过气相甲苯光催化降解实验考察M/TiO2的光催化活性。实验结果表明:负载1.0 wt%的Pt、Pd、Ag和Au四种贵金属均可提高TiO2光催化降解甲苯的效率,其中Pt/TiO2的光催化活性最佳。循环伏安法(CV)、塔菲尔(Tafel)和Mott-Schottky电化学测试证明Pt的负载抑制光生电子和空穴的复合,提高载流子浓度,进而增强TiO2光催化活性。     

URBAN INFLUENCE ON PHOSPHORUS AND SEDIMENT LOADING OF WEST POINT LAKE,GEORGIA1

ABSTRACT: West Point Lake is a 10,360 ha mainstream impoundment of the Chattahoochee River located 95 kilometers downstream of Atlanta, Georgia. Origins and magnitude of external total phosphorus (TP) and total suspended solids (TSS) loads from the West Point Lake basin were estimated over a one-year period. Partitioning the drainage basin allowed the sources of these loads to be determined. The upper subbasin area, from Franklin, Georgia, to the headwaters of the Chattahoochee River, contributed 96 percent of the discharge and 97 percent of the TP and TSS loads into West Point Lake. The lower subbasin area, from Franklin to West Point Lake dam, only contributed 3 percent of the TP and TSS loads. Ninety-one percent and 87 percent of the TP and TSS loads, respectively, from the upper subbasin originated from the Atlanta area. Point sources discharged 70 percent and 3 percent of the upper subbasin TP and TSS loads, respectively. A large portion (66 percent) of the TP from the upper subbasin was in the bioavailable form.     

SPRINGFLOW EFFECTS ON CHEMICAL LOADS IN THE SNAKE RWER,SOUTH-CENTRAL IDAHO1

ABSTRACT: The 150-kilometer middle reach of the Snake River (middle Snake) in south-central Idaho receives large quantities of water from springs discharging along the north side of the river from the regional Snake River Plain aquifer. Water-quality samples collected from nine north-side springs in April 1994 indicated that springs in the upstream part of the reach had larger concentrations of dissolved solids, dissolved nitrate, total nitrogen, tritium, and heavy isotopes of hydrogen and oxygen than to springs in the downstream part of the reach. Because the spring chemistry varies in the reach, discharge from the springs resulted in a degradation in water quality in some parts of the middle Snake and improvements in water quality in other parts. Depending on the annual discharge in the Snake River, the contribution from the north-side springs represented 33 to 66 percent of the discharge, 32 to 57 percent of the dissolved solids, 26 to 50 percent of the total nitrogen, and 7 to 14 percent of the total phosphorus transported annually from the middle Snake. Synoptic sampling showed that the north-side springs contributed 84 percent of the discharge and 35, 40, and 10 percent of the dissolved solids, total nitrogen, and total phosphorus load, respectively, to the Snake River during the peak of the irrigation season in 1994.     

THE EFFECTS OF ARTIFICIAL CIRCULATION ON A SMALL NORTHEASTERN IMPOUNDMENT1

ABSTRACT: Artificial circulation was applied at East Sidney Lake, a small, eutrophic impoundment in New York, to improve the water quality of the reservoir and tailwater. Treatment was successful at both reducing the stability of the reservoir and maintaining higher mean oxygen concentrations in the bottom waters. Discharge waters had lower metals and phosphorus concentrations during treatment years. However, vertical temperature differences, although minimal, were still sufficient to permit chemical stratification and some phosphorus release from the sediments. Frequent mixing events during periods of low stability, and runoff from storm events, also appeared to increase transport of phosphorus into the epilimnion. Overall, treatment did not result in decreases in algal populations or improvements in water clarity.     

Nonpoint Source Loading Rates From Selected Land Uses1

ABSTRACT: Loading rates derived from monitoring natural runoff from selected land uses are compared. Land uses selected for evaluation are construction sites, barnyards, and agriculture (dairying). Runoff volumes, sediment, and nutrient fractions were monitored and expressed as areal loadings for comparison purposes. Sediment yield and total phosphorus (total P) loss was directly proportional to runoff (m³/ha). In decreasing order, the loadings for sediment and total P were as follows: construction site > barnyard > general dairying. Runoff from the barnyard area was approximately 10 times higher in soluble phosphorus and ammonium nitrogen than the other land uses under investigation. Areal loss for nitrate nitrogen was highest from the construction site and was attributed to the higher volume of runoff per unit area. Results show that barnyards in a dairying watershed are potentially a major source of sediment and nutrients, especially those dissolved fractions which have the potential for immediate water quality impacts. Relative to general agricultural land, urban construction sites also appear to be a major source of sediment and nutrients. As with barnyard sites, however, the effect of such sites on water quality likely depends on proximity to surface water bodies and other watershed characteristics affecting delivery ratios of contaminants.     

间歇曝气系统中硝酸盐氮负荷对脱氮效率的影响

本试验主要考察间歇反应器缺氧阶段硝酸盐氮负荷ＮＮＯ－ｘ－Ｎ（ＫｇＮＯ－ｘ－Ｎ／ＫｇＭＬＳＳｄ）对脱氮效率的影响。试验结果表明：在一定水温和ＢＯＤ５／ＮＯｘ－Ｎ下,ＮＮＯｘ－Ｎ负荷对脱氮效率有显著影响。在反应器中采用高浓度污泥是降低ＮＮＯｘ－Ｎ的有效途径,有利于反应器脱氮速率ＶＤＮ（ｍｇ／ｌ·ｍｉｎ）的提高。此外,通过正交试验得出了在ＢＯＤ５／ＮＯ－ｘ一定时,ＮＮＯ－ｘ－Ｎ、Ｔ℃与脱氮效率ηＮＯ－ｘ－Ｎ之间的数量关系式     

Eutrophication of Buttermilk Bay,a cape cod coastal embayment: Concentrations of nutrients and watershed nutrient budgets

Nutrient concentrations in Buttermilk Bay, a coastal embayment on the northern end of Buzzards Bay, MA, are higher in the nearshore where salinities are lower. This pattern suggests that freshwater sources may contribute significantly to nutrient inputs into Buttermilk Bay. To evaluate the relative importance of the various sources we estimated inputs of nutrients by each major source into the watershed and into the bay itself. Septic systems contributed about 40% of the nitrogen and phosphorus entering the watershed, with precipitation and fertilizer use adding the remainder. Groundwater transported over 85% of the nitrogen and 75% of the phosphorus entering the bay. Most nutrients entering the watershed failed to reach the bay; uptake by forests, soils, denitrification, and adsorption intercepted two-thirds of the nitrogen and nine-tenths of the phosphorus that entered the watershed. The nutrients that did reach the bay most likely originated from subsoil injections into groundwater by septic tanks, plus some leaching of fertilizers.Buttermilk Bay water has relatively low nutrient concentrations, probably because of uptake of nutrients by macrophytes and because of relatively rapid tidal flushing. Annual budgets of nutrients entering the watershed showed a low nitrogen-to-phosphorus ratio of 6, but passage of nutrients through the watershed raised N/P to 23, probably because of adsorption of PO₄ during transit. The N/P ratio of water that leaves the watershed and presumably enters the bay is probably high enough to maintain active growth of nitrogenlimited coastal producers. There is a seasonal shift in N/P in the water column of Buttermilk Bay. N/P exceeded the 161 Redfield ratio during midwinter; the remainder of the year N/P fell below 161. This suggests that annual budgets do not provide sufficiently detailed data with which to interpret nutrient-limitation of producers. Further, some idea of water turnover is also needed to evaluate impact of loading rates. Urbanization of watersheds seems to increase loadings to nearshore environments, and to shift the nutrient loadings delivered to coastal waters to relatively high N-to-P ratios, potentially stimulating growth of nitrogen-limited primary producers.