Water pressure head and temperature impact on isoxaflutole degradation in crop residues and loamy surface soil under conventional and conservation tillage management

Laboratory incubations were performed in order to evaluate the dissipation of the proherbicide isoxaflutole in seedbed layer soil samples from conventional and conservation tillage systems and in maize and oat residues left at the soil surface under conservation tillage. The effects of temperature and water pressure head on radiolabelled isoxaflutole degradation were studied for each sample for 21 d. Mineralisation of isoxaflutole was low for all samples and ranged from 0.0% to 0.9% of applied ¹⁴C in soil samples and from 0.0% to 2.4% of applied ¹⁴C in residue samples. In soil samples, degradation half-life of isoxaflutole ranged from 9 to 26 h, with significantly higher values under conservation tillage. In residue samples, degradation half-life ranged from 3 to 31 h, with significantly higher values in maize residues, despite a higher mineralisation and bound residue formation than in oat residues. Whatever the sample, most of the applied ¹⁴C remained extractable during the experiment and, after 21 d, less than 15% of applied ¹⁴C were unextractable. This extractable fraction was composed of diketonitrile, benzoic acid derivative and several unidentified metabolites, with one of them accounting for more than 17% of applied ¹⁴C. This study showed that tillage system design, including crop residues management, could help reducing the environmental impacts of isoxaflutole.     

A Note on the Use of Conservation Practices in U.S. Agriculture

This article measures the effect of an increase in productivityattributable to an increase in soil organic carbon associated with theincrease in the use of conservation practices in agriculture in theUnited States. Both the direct and indirect effects are calibrated. Theanalytical approach used consists of a dynamic computable generalequilibrium model composed of 14 producing sectors, 10 consumingsectors, seven household categories classified by income, and agovernment. The results suggest that the impact of a change inproductivity is an increase in output over a six year period starting in1998 in field crops. The most significant impact is felt in thelivestock sector. This is because field crops are a major input in theproduction of livestock. The food processing sector also exhibits arelatively large increase because of the increase in inputs of both fieldcrops and livestock. Manufacturing output increases primarily becauseoverall investment rises and most investment utilizes manufacturinggoods. The other producing sectors are generally unaffected by theincrease in agricultural production due to an increase in soil organiccarbon. Coincident with the increase in the production of field cropsis a relatively large decrease in the price of field crops. Othernoticeable price reductions occur in the livestock sector and the foodprocessing sector. For the consuming sectors, the consumption offood and alcohol and tobacco increase but consumption in all of theother sectors remains basically unchanged. Prices in the food andalcohol and tobacco sectors decline by about 1% while theprices in the other sectors remain static. Household welfare increasesin the aggregate by only 0.1% with this increase occurringuniformly across all household categories. Revenue received by thegovernment increases a modest 2% in response to an increase inoutput and, hence, an increase in taxes paid. The results indicate thatthere are significant production benefits for several sectors that can berealized by an increase in the use of conservation practices inagricultural production which, in turn, enhances soil organic carbon.There are a number of policy options available to promote the use ofconservation practices. These include education and technicalassistance, financial assistance, research and development, landretirement, and regulation and taxes.     

SOIL EROSION AWARENESS AND USE OF CONSERVATION TILLAGE FOR WATER QUALITY CONTROL1

Water pollution through loss of topsoil from farmland continues to be a major problem, despite nearly 50 years of providing farmers technical and financial assistance for soil and water conservation. The technology for controlling erosion and water pollution is available, but farmers have been slow in implementing control practices. Past research has shown that farmers tend to be unaware of the seriousness of the erosion problem on their own operations. Using a random sample of farmers from central Iowa, the relationship is examined between awareness of a soil erosion problem and the use of conservation tillage. Results indicate that awareness of a soil erosion problem effects the use of conservation tillage, and that awareness can be enhanced by experiential educational strategies such as the development and implementation of a soil and water conservation plan.     

EFFECTS OF CROPPING SYSTEMS ON NO3-N LOSSES TO TILE DRAIN1

Abstract: Diverse cropping systems can have significant impacts on nutrient losses through tile drain systems and to surface water bodies (rivers and streams). Increased transport of nitrogen to water bodies can reduce dissolved oxygen and enrich the supply of nutrients, resulting in hypoxic zones. With the objective of reducing the transport of nutrients from agricultural watersheds, long term studies (1990 to 1998) were conducted in Iowa to investigate the impact of tillage, crop rotation, and N-management practices on NO₃-N leaching losses to tile drain water. Results of these studies indicated that continuous corn production systems required higher input of nitrogen fertilizers and resulted in significantly higher NO₃-N leaching losses compared to rotated corn in plots either fertilized with manure or urea ammonium nitrate. Also, rotated corn gave higher corn yields, 8 megagrams per hectare (Mg/ha) versus 6 Mg/ha, than continuous corn. The higher N application rates resulted in increased NO₃-N concentrations in tile water. A strip cropping system with alfalfa lowered NO₃-N concentrations in tile water to less than 10 mg/l. These studies indicated that better land use practices can reduce NO₃-N leaching losses to surface and ground water systems and will help in mitigating environmental concerns of the production agriculture.     

APPLICATION OF AN ENVIRONMENTAL AND ECONOMIC MODELING SYSTEM FOR WATERSHED ASSESSMENTS1

ABSTRACT: A National Pilot Project (NPP) on Livestock and the Environment was initiated in 1992 to help provide solutions to environmental problems associated with livestock production. A major development of the NPP was the Comprehensive Economic and Environmental Optimization Tool‐Livestock and Poultry (CEEOT‐LP), an integrated modeling system designed to produce economic and environmental indicators for alternative policy scenarios applied to intensive livestock production watersheds. The system consists of a farm‐level economic model (FEM) and two environmental models: the field‐scale APEX model and the watershed‐level SWAT model. To date, CEEOT‐LP has been applied to two watersheds in Texas and one in Iowa. Predicted reductions in P losses for two P‐based manure application rate scenarios, relative to baseline conditions, ranged from ?4 to ?54 percent across the three watersheds; however, N loss impacts ranged from a decrease of 34 percent to an increase of 79 percent. For five other alternative scenarios that were simulated for only one watershed, N and P loss impacts ranged between a reduction of 78 percent to an increase of 20 percent. Aggregate watershed‐level economic impacts of the seven scenarios spanned a spectrum of a 27 percent decrease to a 25 percent increase in profit, relative to the baseline.     

EFFECTS OF SLUDGE AND CHEMICAL FERTILIZER APPLICATION ON RUNOFF WATER QUALITY1

ABSTRACT: Simulated rainfall was used on experimental field plots to compare the effect of chemical fertilizer and sludge application on sediment, nitrogen, and phosphorus in runoff from no-till and conventional tillage systems. Chemical fertilizer application under the no-till system resulted in the least amount of total N and P in surface runoff. However, sludge application under the no-till system resulted in the least amount of NO₃-N and sediment in surface runoff. The worst water quality scenarios were observed when either sludge or chemical fertilizer were surface-applied under a conventional tillage system. Nitrogen losses from the conventional tillage system were minimized when sludge was incorporated into the soil. However, phosphorus and sediment yield from such a system were significantly higher when compared to phosphorus and sediment yield from the no-till system. The results from this study indicate that the use of sludge on agricultural land under a no-till system can be a viable alternative to chemical fertilizer for nitrogen and phosphorus control in runoff. A more cautious approach is recommended when the sludge is incorporated into the soil in a conventional tillage system because of potential for high sediment and phosphorus yield in surface runoff.     

Contour Farming Based on Natural Vegetative Strips: Expanding the Scope for Increased Food Crop Production on Sloping Lands in Asia

In the agriculture of the future, there is a compelling place for agroecologically-based practices alongside practices based on the best available chemical, genetic, and engineering components. This paper explores this issue in the context of the development and spread of a conservation farming system based on natural vegetative contour buffer strips in smallholder production systems in southeast Asia. Farmers adapted contour hedgerow farming practices into a simpler, buffer-strip system as a labor-saving measure to conserve soil and sustain yields on steeply sloping cropland in Claveria, Mindanao, Philippines. Permanent-ridge tillage systems were also adapted to smallholder farming systems by researchers. Natural vegetative buffer strips resulted in gradually increasing yields, with an estimated benefit of 0.5t/ha/crop. They were seen to increase land values, facilitate investment in more intensive and profitable cropping systems, and expand the land base for food crop agriculture. They induced an institutional innovation of farmer-led Landcare organizations, which have spread this and other agroforestry practices to thousands of households in the southern Philippines.     

Dynamic behaviour of direct spring loaded pressure relief valves in gas service: II reduced order modelling

A previous study of gas-service direct-spring pressure relief valves connected to a tank via a straight pipe is continued by deriving a reduced-order model for predicting oscillatory instabilities such as valve flutter and chatter. The reduction process uses collocation to take into account a finite number N of acoustic pressure waves within the pipe, resulting in a set of 2N+3 ordinary differential equations. Following a novel non-dimensionalization, it is shown analytically that the model can exhibit, at experimentally realistic parameter values, instabilities associated with coupling between the valve and acoustic waves in the pipe. The thresholds for each instability are such that for a given flow rate, the first mode to go unstable as the inlet pipe length increases is the quarter-wave mode, then a three-quarter wave, a 5/4-wave etc. Thus the primary mode of instability should always be due to the quarter wave. In the limit of low flow rates, a simple approximate expression is found for the quarter-wave instability threshold in the form of inlet pipe length against mass flow rate. This threshold curve is found to agree well with simulation of the full model. For higher flow rates there is a need to include fluid convection, inlet pressure loss and pipe friction in order to get good agreement. The reduced model enables the dependence of the stability curve on key dimensionless physical parameters to be readily computed.     

Biogenic volatile organic compound analyses by PTR-TOF-MS: Calibration, humidity effect and reduced electric field dependency

Green leaf volatiles(GLVs) emitted by plants after stress or damage induction are a major part of biogenic volatile organic compounds(BVOCs). Proton transfer reaction time-of-flight mass spectrometry(PTR-TOF-MS) is a high-resolution and sensitive technique for in situ GLV analyses, while its performance is dramatically influenced by humidity, electric field,etc. In this study the influence of gas humidity and the effect of reduced field(E/N) were examined in addition to measuring calibration curves for the GLVs. Calibration curves measured for seven of the GLVs in dry air were linear, with sensitivities ranging from 5 to10 ncps/ppbv(normalized counts per second/parts per billion by volume). The sensitivities for most GLV analyses were found to increase by between 20% and 35% when the humidity of the sample gas was raised from 0% to 70% relative humidity(RH) at 21°C, with the exception of(E)-2-hexenol. Product ion branching ratios were also affected by humidity,with the relative abundance of the protonated molecular ions and higher mass fragment ions increasing with humidity. The effect of reduced field(E/N) on the fragmentation of GLVs was examined in the drift tube of the PTR-TOF-MS. The structurally similar GLVs are acutely susceptible to fragmentation following ionization and the fragmentation patterns are highly dependent on E/N. Overall the measured fragmentation patterns contain sufficient information to permit at least partial separation and identification of the isomeric GLVs by looking at differences in their fragmentation patterns at high and low E/N.