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71.
Abstract Fensulfothion was incubated in nutrient media with a mixed culture of soil microorganisms obtained from sandy loam. The half life of fensulfothion in both inoculated samples and sterile controls was about 16 wk. There was some conversion to fensulfothion sulfone (16% at 6 wk) in inoculated samples, but not in the controls. Traces of fensulfothion sulfide were found in both inoculated samples (<3%) and controls (<2%) . When 1% ethanol was added to the inoculated nutrient mixture the fensulfothion disappeared rapidly (t½>~1½> wk) with 32% conversion at 20 wk to fensulfothion sulfide. 相似文献
72.
73.
Groundwater remediation technologies, such as pump-and-treat (PTS) and funnel-and-gate systems (FGS), aim at reducing locally appearing contaminations. Therefore, these methodologies are basically evaluated with respect to their capability to yield local improvements of an environmental situation, commonly neglecting that their application is also associated with secondary impacts. Life cycle assessment (LCA) represents a widely accepted method of assessing the environmental aspects and potential impacts related to a product, process or service. This study presents the set-up of a LCA framework in order to compare the secondary impacts caused by two conceptually different technologies at the site of a former manufactured gas plant in the city of Karlsruhe, Germany. As a FGS is already operating at this site, a hypothetical PTS of the same functionality is adopted. During the LCA, the remediation systems are evaluated by focusing on the main technical elements and their significance with respect to resource depletion and potential adverse effects on ecological quality, as well as on human health. Seven impact categories are distinguished to address a broad spectrum of possible environmental loads. A main point of discussion is the reliability of technical assumptions and performance predictions for the future. It is obvious that a high uncertainty exists when estimating impact specific indicator values over operation times of decades. An uncertainty analysis is conducted to include the imprecision of the underlying emission and consumption data and a scenario analysis is utilised to contrast various possible technological variants. Though the results of the study are highly site-specific, a generalised relative evaluation of potential impacts and their main sources is the principle objective rather than a discussion of the calculated absolute impacts. A crucial finding that can be applied to any other site is the central role of steel, which particularly derogates the valuation of FGS due to the associated emissions that are harmful to human health. In view of that, environmental credits can be achieved by selecting a mineral-based wall instead of sheet piles for the funnel construction and by minimising the steel consumption for the gate construction. Granular activated carbon (GAC) is exclusively considered as the treatment material, both in-situ and on-site. Here it is identified as an additional main determinant of the relative assessment of the technologies since it is continuously consumed. 相似文献
74.
As complex social phenomena, public involvement processes are influenced by contextual factors. This study examined agency
goals for public involvement and assessed the importance of local context in remedial action planning, a community-based water
resources program aimed at the cleanup of the 42 most polluted locations in the Great Lakes Basin. Agency goals for public
involvement in remedial action plans (RAPs) were agency-oriented and focused on public acceptance of the plan, support for
implementation, and positive agency-public relations. Corresponding to these goals, citizen advisory committees were created
in 75% of the RAP sites as a primary means for public input into the planning process. Factors that influenced the implementation
of public involvement programs in remedial action planning included public orientation toward the remediation issue, local
economic conditions, the interaction of diverse interests in the process, agency and process credibility, experience of local
leadership, and jurisdictional complexity. A formative assessment of “community readiness” appeared critical to appropriate
public involvement program design. Careful program design may also include citizen education and training components, thoughtful
management of ongoing agency-public relations and conflict among disparate interests in the process, overcoming logistical
difficulties that threaten program continuity, using local expertise and communication channels, and circumventing interjurisdictional
complexities. 相似文献
75.
K. Nakamiya T. Furuichi K. Ishii 《Journal of Material Cycles and Waste Management》2003,5(1):0063-0068
The optimal soil-washing conditions for dioxins were estimated on a soil sample from the circumference of an incinerator
in Nose City, Osaka, Japan. The solvents ethanol, methanol, and acetone, together with a surfactant (100% of each) could extract
40% of the dioxins from contaminated soil at room temperature. From among these solvents, ethanol was chosen for a study on
how to optimize the extraction conditions because of its low toxicity and its economic advantages. The time-course of the
agitation showed that the extraction rate increased for 1 min, and thereafter the rate decreased. Therefore, the agitation
time was fixed at 1 min. To estimate the effect of temperature on the extraction rate, the extraction temperature was changed.
The amount of dioxins extracted was largest at the boiling point of ethanol (78.3°C), giving about 76% extraction. Furthermore,
at this temperature, almost 100% of the dioxins in the contaminated soil were extracted when the ratio of water to ethanol
was 20%.
Received: March 6, 2002 / Accepted: September 9, 2002 相似文献
76.
Richard A. Lillie 《Journal of the American Water Resources Association》2003,39(2):389-400
ABSTRACT: Fifty‐four Wisconsin wetlands were surveyed in spring 1996 to determine relationships between macroinvertebrate community structure and a suite of 11 environmental attributes. Canonical correspondence analysis (CCA) showed that, after alkalinity, hydroperiod was the next most significant environmental factor influencing macroinvertebrate community structure within the wetlands sampled. CCA and direct gradient biplots were used to identify indicator taxa characteristic of the spring macroinvertebrate communities in persistent and ephemeral wetlands, and taxa characteristic of semi‐terrestrial habitats adjacent to wetlands. Two models were developed to permit the prediction of a wetland's hydroperiod class. One model assigns a range of probabilities that a wetland has a hydroperiod longer or shorter than eight months based on the occurrence or abundance of fairy shrimp, mayflies, scuds, mosquitoes, and phantom midges. A second model predicts that a wetland's hydroperiod is longer or shorter than five months based on the joint occurrences of seven persistent indicator taxa. Data used in both models were derived from a rapid bioassessment of three shoreline D‐frame net sweeps. The use of a coarse level taxonomic identification (primarily order and family) allows the approach to be performed in the field or laboratory. The macroinvertebrate models allow a manager to estimate a wetland's hydroperiod when long term water duration records do not exist. This ability is important to water resource managers because hydroperiod classification (i.e., water permanency) is one criterion used in differentiating wetlands from lakes in Wisconsin and because Wisconsin's legal system affords lakes substantially greater protection than wetlands. 相似文献
77.
This paper expands on air travel accident research by examining the relationship between air travel accidents and airline traffic or volume in the period from 1927–2006. The theoretical model is based on a representative airline company that aims to maximise its profits, and it utilises a fractional integration approach in order to determine whether there is a persistent pattern over time with respect to air accidents and air traffic. Furthermore, the paper analyses how airline accidents are related to traffic using a fractional cointegration approach. It finds that airline accidents are persistent and that a (non‐stationary) fractional cointegration relationship exists between total airline accidents and airline passengers, airline miles and airline revenues, with shocks that affect the long‐run equilibrium disappearing in the very long term. Moreover, this relation is negative, which might be due to the fact that air travel is becoming safer and there is greater competition in the airline industry. Policy implications are derived for countering accident events, based on competition and regulation. 相似文献
78.
79.
在分析当前我国土壤受石油污染的状况基础上,介绍目前修复石油污染场地土壤的技术,包括物理修复、化学修复和生物修复等.并对各种技术的修复原理、研究进展、优缺点及其发展趋势进行了综述,结合我国的研究现状与工作基础对该领域今后的研究方向与重点进行了展望. 相似文献
80.
本文报道灭幼脲Ⅲ号杀虫剂在大白菜和土壤中的残留试验结果.经在南北两地连续两年的田间试验表明,灭幼脲Ⅲ号属非持久性农药,在作物和土壤中都较快地消失,在大白菜上的半衰期为3.8—14.0d,在土壤中为8.8—27.0d.用25%灭幼脲Ⅲ号胶悬剂稀释2500倍,每亩每次按常规用药10g或加倍药量20g(有效成分)施药,喷施2或3次,距最后一次施药三周时,灭幼脲Ⅲ号杀虫剂在大白菜的最大残留量为2.67ppm,在土壤中为13.81ppm.建议该农药在大白菜上的最高允许残留量(MRL)为3ppm,安全间隔期为21d. 相似文献