双柱双检测器气相色谱法同时进样分析非甲烷烃

介绍了用双柱双氢火焰离子化检测器同时进样气相色谱法分析气体样品中非甲烷烃.经过与现有方法的比较,该方法具有平行性更好、数据更准确、分析速度快等优点,各项指标均大大优于现行标准HJ/T 38-1999中的数据.通过软硬件的改进,解决了以前非甲烷烃在分析中由于在时间上所引起的数据倒置、分析误差等问题.     

Determination of Water-soluble Atmospheric Aerosols Using Ion Chromatography

A field study was established to investigate the chemical composition of atmospheric aerosols in Chicago, IL. One goal of this study was to determine the influence of precursor trace gases and local meteorology on concentrations of secondary aerosol ionic species. This paper describes the method details, shows the method is analytically valid, and reports overall as well as some specific results found during the field study. Two particulate air samples were collected per day onto quartz fiber filters at the Loyola University Chicago Air Station during the summer months in 2002–2004. In parallel, mixing ratios of ozone and nitrogen oxides were monitored and weather parameters were recorded. Particulates were extracted from the filter substrates and the subsequent solutions were analyzed by ion chromatography for anions, including low molecular weight organic acids, and cations. A washing procedure was implemented to reduce the high background values of the quartz fiber filters. Method validation showed that the collection method was efficient for all ions with exception of nitrate, whose efficiency of 70% indicated losses caused by volatilization. The extraction method also proved efficient for both field and laboratory samples, and the repeatability of the method was high with relative standard deviations less than 10% for all ions. Reproducibility of the results was determined by comparison of sulfate to sulfur analyzed by total reflection X-ray fluorescence spectrometry and proved to be high as well. Concentrations differed significantly between the three summer studies due to varying levels of precursor species as a consequence of distinct temperatures and wind direction profiles.     

Minimization of the environmental impact of chrome tanning: a new process with high chrome exhaustion

In all tanning technology operations wastes are generated. These reach the environment as residual waters, solid and liquid waste as well as atmospheric emissions and odours.

This study tests an alternative method to the traditional tanning method at an industrial level. The new method is based on tanning without float and by significantly increasing the temperature at the end of the tanning process. The properties of the leathers obtained using the two methods have been compared and the results indicate that those leathers have similar physical, chemical, and organoleptic properties. However, the differences existing from the environmental point of view are significant. It is not necessary to use clean water for this tanning. Moreover, there is a 75% reduction of the residual float, a 91% reduction of the chrome discharged, and a 94% reduction of the chlorides discharged. A financial assessment was carried out to demonstrate that the newly proposed system is 32% more economic than the traditional one.     

气相色谱-质谱法测定土壤中的汽油及其组分含量

对土壤中的汽油,采用外标法,经吹扫捕吸仪浓缩后,用气相色谱-质谱法分析定量。同时,用峰面积归一化法,可以测定土壤中汽油的组分含量。     

Equity and productivity assessments in the Olifants River basin, South Africa

Emerging approaches to water resources development and management typically highlight equity and productivity as two main objectives. In the context of integrated water resources management within a river basin, managers and stakeholders often need a comparative assessment of different options for water augmentation and/or allocation. Pitting such options against predefined objectives, such as equity and productivity, requires an assessment of the effects that available options will have on these objectives. Available documentation indicates that not only does the interpretation of such objectives vary widely, but also the available methods for assessing equity and productivity run into significant limitations in the availability of adequate data. This limitation has largely kept decision makers from gaining a comprehensive overview of equity and productivity scenarios, whether within or across sectors, that could facilitate better‐informed decisions. To address this methodological gap, this article scrutinizes different notions associated with equity and water productivity, and limitations in prevalent assessment methods with the view to develop and demonstrate pragmatic methodologies for assessing equity and productivity in data‐scarce contexts. The discussion and findings are based on a review of relevant literature and empirical and consultative research work in the Olifants River basin in South Africa. The demonstrated methodologies for assessing equity and productivity, besides being useful in data‐scarce contexts, are insightful for initiating several policy measures and also for exploring the relationship between equity and water productivity.     

企业安全效益的量化

安全就是效益 ,而安全效益的量化问题一直是企业非常关心的问题。笔者通过安全效益的论述、量化分析 ,提出了企业安全效益由安全管理所创造的直接经济效益、间接经济效益、安全投入转化的经济效益、潜在经济效益四部分组成的新观点 ;推导出安全效益的量化公式 ,从而揭示了安全与效益的辩证统一关系 ;得出了安全效益从定性走向定量是必然的规律和安全效益完全可以进行量化计算的重要结论。     

自然资源与环境价值评估:条件估值法及应用原则探讨

自然资源与环境价值评估是当前环境经济学的研究热点,条件估值法C(VM)在国外经过近40年的发展已较为完善并已成为自然资源和环境价值评估的主要技术方法之一。但由于缺少一套完备的原则框架加以指导,国内具体实证研究存在不同的问题和困惑。论文系统回顾了条件价值法的国内外主要研究进展,基于国际上已建立的CVM原则并结合我国自然资源与环境价值评估的实际情形,提出了当前国内CVM研究可供遵循的9条建议性原则,涉及问卷设计与预调查、调查实施、数据分析和费用效益分析等各步骤。以此为基础对国内CVM价值评估研究存在的一些问题作了初步探讨。最后指出,环境资源价值评估CVM研究需要遵循的原则和注意的问题,可能还不止于所建原则,具体操作过程可能需要适时适地地调整并需要继续完善。     

地表水质灰关联评价中水环境质量系数的研究

分析和阐明地表水环境质量灰关联评价中关联度向量r中各分量的信息荷载,在满足定量、连续、分级的条件下构造了水环境质量系数C,C由首数水质级别数K和尾数水质差异E组成。水环境质量系数既能表示水质级别,又能准确区别同级水质差异。在应用特例中介绍了模糊级别的区分和级别跳跃现象。最后介绍了应用中注意的问题。     

并联式TBCC发动机排气系统性能数值模拟

针对一个并联式涡轮基组合循环(Turbine Based Combined Cycle, TBCC)发动机排气系统的气动方案,对其在整个飞行包线范围内典型工作点上的流场进行了数值模拟研究,获得了飞行包线范围内排气系统相应的推力系数、升力、俯仰力矩随飞行马赫数的变化关系。计算结果显示,在整个飞行包线范围内,排气系统的轴向推力系数随着飞行马赫数先减小后增大,在跨声速飞行时降到最低 Ma=0.9,涡喷不加力时为0.562,加力时0.662),在设计点附近达到最大;升力和俯仰力矩性能在亚声速及跨声速飞行时较差,在超声速飞行时随着飞行马赫数增加逐渐好转。表明排气系统在跨声速飞行范围内工作时应采取措施以改善其性能。      

流域生态补偿意愿的WTP与WTA差异性研究: 基于辽河中游地区居民的CVM调查

如何揭示利益相关者生态补偿的真实意愿不但是生态系统服务支付研究的难点问题,也是政府及管理部门制定生态补偿政策的关键问题。为此,论文通过对辽河流域中游地区的7个主要城市进行实地调研,采用条件价值评估法,利用同一受访者同时测量其支付意愿值(WTP)和受偿意愿值(WTA)的技术手段来检验其真实补偿意愿,研究结果显示,受访地区居民保护流域生态环境和水资源的WTP为59.39元／(人·a),WTA为248.56／(人·a);同时,针对同一受访者给出的WTP与WTA之间的较大差异性利用回归分析方法,得出其呈现不对称性的主要原因是受访者的收入水平和年龄。最后,在对研究结果进行差异性分析的基础上,提出了辽河流域生态补偿意愿差异性的研究结论和政策建议。