聚硅硫酸钛（PTSiS）的合成及形貌分析

以硅酸钠和硫酸钛为原料,用共聚法制备了不同硅钛比(硅钛摩尔比分别为3∶1、1∶1和1∶3)的新型绿色无机高分子絮凝剂——聚硅硫酸钛(PTSiS)。用紫外连续扫描光谱仪(UV/Vis)、红外光谱仪(IR)、X-射线衍射(XRD)、扫描电镜(SEM)和倒置生物显微镜对样品中钛硅的微观品貌进行了多方面物性分析。结果表明:当硅钛比为3∶1时,硅酸钠和硫酸钛反应完全。此时,聚硅酸的骨架硅(Si—O—Si)与钛元素发生同晶取代或与钛离子水解形成的表面羟基发生络合,形成的聚硅硫酸钛(PTSiS)是一种高分子的硅钛聚合物,而不是单纯的原料混配。另外,聚硅硫酸钛(PTSiS)具有枝杈长链的网络结构,其骨架主要由框架钛结构(Ti—O—Si)组成。     

Estimating the economic value of improvements in river ecology using choice experiments: an application to the water framework directive

The Water Framework Directive is a major regulatory reform of water resources management within the European Union. Integrated catchment management plans must be prepared for all river basins, in order to achieve 'good ecological status' in all EU waters. Ecological status is a broader measure of water quality than the chemical and biological measures that were previously dominant. The Directive calls for a consideration of the economic costs and benefits of improvements to ecological status. In this paper, we use the choice experiment method to estimate the value of improvements in three components of ecological status. Given the high resource cost of valuation studies, benefits transfer methods will be needed in implementing the Directive. We thus also test the ability of choice experiments for benefits transfer across two very similar rivers in the UK.     

Sediment-based investigation of naturally or historically eutrophic lakes -- implications for lake management

Implementation of the EU Water Framework Directive will call for new lake monitoring and management strategies. Therefore, different methods need to be tested in order to achieve reliable assessment of lake background conditions and water quality. Sediment-based techniques provide one such tool for lake management. In this work, 10 lakes, presumed to be naturally eutrophic, were investigated with a paleolimnological short core study. The aim of the study was to examine the composition of the diatom assemblages in their natural state, estimate their change over time and assess the background nutrient levels. One sediment profile from each lake was divided into six sub-samples that were analyzed for diatoms (60 samples). Diatom-based inference models were applied to reconstruct the past total phosphorus concentration and assess the eutrophication. The results indicated that all the lakes studied had already been nutrient-rich before the impact of modern agriculture. However, diatom assemblages have changed remarkably over time and total phosphorus concentrations have generally increased, so at present only two of the study lakes are close to their natural status. This suggests that naturally eutrophic lakes will probably require management actions to fulfill the new directive requirements in the future.     

我国生态保护与建设支出账户框架构建研究

生态保护与建设是我国生态文明建设的重要任务,生态保护与建设支出账户核算是环境经济核算的重要内容,但我国目前尚未开展系统的生态保护与建设支出核算。本文首先梳理了生态保护与建设支出核算的国际经验,指出我国生态保护与建设支出账户核算面临统计口径不完善、统计体系尚未建立、统计主体和对象仍不完整、统计数据呈部门化和分散化等问题。在此基础上,本文从生态保护与建设支出主体、支出分类、支出资金来源等方面初步构建了支出账户核算体系,并以2013年为例进行了初步估算。结果表明,我国财政资金用于生态保护与建设的支出总量不足,仅占当年GDP的0.25%。为推动生态保护与建设支出账户核算工作,建议应从预算科目、统计口径、统计主体、统计对象等方面不断完善生态保护与建设统计体系,加快推进生态保护与建设支出账户的构建与核算,并争取尽快纳入国民经济核算体系,以推进生态文明体制改革与制度建设的进程,促进我国生态保护与经济社会的协调发展。     

安全生产规划体系框架探讨

阐述了建立安全生产规划体系的必要性,探讨了安全生产规划的定义、研究对象、目的和内容,指出安全生产规划是为使安全生产与经济社会协调发展而预先对未来一段时间内各项安全生产工作所做的时间和空间的合理安排,具有整体性、综合性、动态性、前瞻性、信息密集和政策性强等特征。同时设计了"四级、三层"的安全生产规划体系,即在行政层级上分为国家级、省级、市级和县级四个层级,在协调作用上分为宏观指导层、项目布局层和方案实施层三个层次。国家安全生产规划从宏观上对全国安全生产工作做出谋划与部署,省级安全生产规划要接受国家安全生产规划宏观指导性的引导和要求,并结合各地实际进行项目布局,同时借助专项规划分解内容,制定市、县级规划实施方案。     

协作网络在跨区域灭火应急救援中的应用研究

为有效解决跨区域灭火应急救援工作中统一指挥难、行动协调难、资源调配难和协同效应难等问题,基于网络在跨区域管理工作中的重要性以及协同原理理论,提出跨区域灭火应急救援协作网络的概念,并分析跨区域灭火应急救援协作网络在跨区域灭火应急救援工作中的功能与作用,最后提出了跨区域灭火应急救援协作网络的结构框架及运行机制。结果表明:协作网络与跨区域灭火应急救援工作相结合具有重要意义,今后的工作重点应是研究构建跨区域灭火应急救援协作网络的影响因素、可行性、实用性以及相关配套设施和宏观运行环境等。     

Cost-Effective Mitigation of Diffuse Pollution: Setting Criteria for River Basin Management at Multiple Locations

A case study of the Yorkshire Derwent (UK) catchment is used to illustrate an integrated approach for assessing the viability of policy options for reducing diffuse nitrate losses to waterbodies. For a range of options, modeling methods for simulating river nitrate levels are combined with techniques for estimating the economic costs to agriculture of modifying those levels. By incorporating spatially explicit data and information on catchment residence times (which may span many decades particularly in areas of groundwater discharge) a method is developed for efficient spatial targeting of measures, for example, to the most at-risk freshwater environments. Combining hydrological and economic findings, the analysis reveals that, in terms of cost-effectiveness, the ranking of options is highly sensitive to both (i) whether or not specific stretches of river within a catchment are regarded as a priority for protection, and (ii) the criterion of nitrate concentration deemed most appropriate as an indicator of the health of the environment. Therefore, given the focus under European legislation upon ecological status of freshwaters, these conclusions highlight the need to improve understanding of mechanistic linkages between the chemical and biological dynamics of aquatic systems.     

A framework to guide the conservation of species hybrids based on ethical and ecological considerations

Species hybrids have long been undervalued in conservation and are often perceived as a threat to pure species. Recently, the conservation value of hybrids, especially those of natural origin, has gained recognition; however, hybrid conservation remains controversial. We reviewed hybrid management policies, including laws, regulations, and management protocols, from a variety of organizations, primarily in Canada and the United States. We found that many policies are based on limited ethical and ecological considerations and provide little opportunity for hybrid conservation. In most policies, hybrids are either unrepresented or considered a threat to conservation goals. This is problematic because our review of the hybrid conservation literature identified many ethical and ecological considerations relevant to determining the conservation value of a hybrid, all of which are management‐context specific. We also noted a lack of discussion of the ethical considerations regarding hybrid conservation. Based on these findings, we created a policy framework outlining situations in which hybrids could be eligible for conservation in Canada and the United States. The framework comprises a decision tree that helps users determine whether a hybrid should be eligible for conservation based on multiple ecological and ethical considerations. The framework may be applied to any hybrid and is flexible in that it accommodates context‐specific management by allowing different options if a hybrid is a threat to or could benefit conservation goals. The framework can inform policy makers and conservationists in decision‐making processes regarding hybrid conservation by providing a systematic set of decision criteria and guidance on additional criteria to be considered in cases of uncertainty, and it fills a policy gap that limits current hybrid management.     

No Sustainability without Technical,Fiscal and Social Innovation

Abstract

Migration process has become increasingly important in recent research on population and the environment. A majority of the existing migration and environment literature has focused on the environmental causes and determinants of migration. With the largest rural-to-urban migration flow in world history, and growing concerns about the environmental problems accompanying its fast economic development, China provides a particularly important case for migration and environment research. This paper reviews major migration theories and recent research on environmental effects on migration, with specific attention to the influences of environmental factors on rural-to-urban labor migration in China. A comprehensive multilevel conceptual framework is developed for studying the environmental causes of rural-to-urban migration in China. The effects of land resources on household labor migration decisions in rural China are explored to illustrate the application of this framework.     

An integrated framework of safety performance evaluation for oil and gas production plants: Application to a petroleum transportation station

Safety performance evaluation is a significant way to ensure the safety of oil and gas production plants. Various evaluation methods have been proposed to make safety evaluation more consistent and scientific. However, a major concern is that many existing safety evaluation measurements are still subjective and are not easy to obtain in a uniform way, which can be attributed to the challenges that process plants faced such as people having different knowledge levels, equipment with dispersed locations and management with many processes. This paper aims to display the impact of risk factors on system safety level in a succinct and visual way that may be expected to overcome subjective opinions from experts and provide a more pertinent and practical safety strategies. To this end, an integrated framework is developed, which considers crucial risk factors from pipeline, static equipment, dynamic equipment and management. First, Fault tree analysis (FTA) is used to explicitly determine the crucial r risk factors. Then, a novel fuzzy cognitive map cooperating with relative degree analysis model (FCM-RDA) is proposed to deal with the weigh distribution opinions. Finally, considering the oil and gas production process is a complex system, a fuzzy comprehensive evaluation (FCE) is employed to calculate the overall safety level.