Detection of organic pollutants in sandy soils via TDR and eigendecomposition

In this study, organic pollutants in sandy soils are detected using a time domain relectrometry (TDR) probe system and eigendecomposition technique. As a demonstration, four types of organic fluids (motor oil, diesel oil, methanol and ethanol) were examined. Samples were prepared with different combinations of deionized water and organic fluid contents. For each experiment, reflected signals were captured by an oscilloscope, and their characteristics were identified using eigendecomposition technique. Autoregressive modeling and singular value decomposition methods were utilized for calculating the eigenvalues. The most significant eigenvalues were then identified based on their relative magnitude. Experimental results indicated that the presented system is sensitive to both water and pore fluid organic contents. For saturated conditions, signature curves were determined for identification of organic and/or water contents in soil pore fluids.     

电气浮含油污水处理工艺工业性试验研究

电解气浮含油污水处理工艺是一种新型的污水处理技术。基于室内试验及现场小试的研究成果,对该技术进行了放大的工业性试验研究,设计了试验流程及装置,取得了阶段性的试验结果。研究结果表明,经电气浮处理后除油率最高可达89%,悬浮固体去除率最高为73%,最低为30%;杀菌率达到99.6%~100%,达到了电气浮除油的要求。电气浮含油污水处理工艺与其他含油污水处理工艺相比,药剂投加量为常规工艺的1/3,运行电耗为0.2 kW.h/m3,总的运行费用约为常规工艺的40%~60%。研究成果为电气浮工艺在石油化工废水处理中的广泛应用奠定了基础。     

Composition of wet and bulk deposition in Erzurum, Turkey

Seasonal variations in the chemical characteristics of wet and bulk deposition samples collected in Erzurum were investigated for the period March 2002-January 2003. Major cations (Ca2+, K+, Mg2+) and major anions (SO4(2-),NO3-) were determined in bulk and wet deposition samples; pH was also measured in wet deposition. The average pH of the wet deposition at Erzurum was 6.6 due to extensive neutralization of the acidity. A strong relationship between pH and SO4(2-) concentrations was observed in all seasons; however, only a weak relationship was found between pH and NO3-. On a seasonal basis, the correlation between Ca2+ and SO4(2-) concentrations was stronger in winter than in summer. Seasonal variations of ions were examined in both wet and bulk deposition samples. Although maximum concentrations of anions generally occurred during winter and spring, cation concentrations peaked in summer for both wet and bulk deposition. Results indicated that Ca2+ was the dominant cation and SO4(2-) the dominant anion in all deposition samples at Erzurum. Even though correlations among the crustal ions (calcium, magnesium and potassium) were high, the relationship between anthropogenic ions (sulfate and nitrate) was less clear in bulk deposition.     

改性粉煤灰及其处理废水的机理

应用正交设计的基本理论,研究了PDMDAAC(聚二甲基二烯丙基氯化铵)改性粉煤灰的最佳条件,并将改性粉煤灰用于模拟印染废水的处理,探索了改性粉煤灰处理废水的机理。结果表明,在原PDMDAAC的pH下．控制PDMDAAC的浓度为40g／L,恒温30℃．反应1h为最佳改性工艺,改性粉煤灰处理废水的机理以吸附电中和为主。     

生化防护材料的探讨

本文详述了生化防护材料的种类、性能特点,与防护服配件的协调、使用耐久性能以及成本等问题,得出了生化防护材料选用及设计的一般性结论。     

采掘诱发地震的成因及对策

根据煤或岩体的赋存特征及采动后的受力特点，将采矿及掘进等工程进行过程中诱发的地震灾害分为三类，即完整煤岩体受压应力作用的失稳、顶底板受拉应力型地震及断层走滑受剪型诱发地震。文章在分别分析其成因的基础上，研究了采矿诱发三种类型地震的发生条件，提出了防治发生诱发地震的对策。     

Misoperation monitoring and early warning during startup and shutdown of petrochemical units

Most petrochemical units run under extreme conditions, such as high temperatures, pressures, and speeds. Consequently, the equipment operators may commit errors because the startup and shutdown processes usually involve complicated operation steps; moreover, the operators may lack experience in handling abnormal situations. Misoperation can lead to accidents, including fires and explosions. Thus, risk analysis for process operations and the development of preventive measures have become an effective means of avoiding misoperation-related accidents. However, it is challenging to ensure the comprehensiveness of risk-analysis results. In this paper, we present a method for misoperation monitoring and early warning in the startup and shutdown processes of petrochemical units. The mechanisms of misoperation occurrence are summarized based on investigations of serious accidents in the recent past. Knowledge regarding the mechanisms of misoperation is crucial for the risk analysis of petrochemical units. The potential risk information, such as causes, adverse consequences, key monitoring parameters, and prevention control solutions, should be acquired and be employed to construct an early-warning knowledge database. Furthermore, misoperation judgment rules need to be formulated to identify misoperations. The data obtained from the monitoring module, misoperation judgment rules, and analysis results can aid in developing schemes to avoid possible abnormal situations. This paper reports a misoperation monitoring and early-warning system for a hydrogenation unit. As demonstrated, conducting risk analysis to determine the potential operational risks and formulating misoperation judgment rules to analyze the process data are essential for enabling early warning. The application of this method will contribute to operational guidance, economic loss reduction, and accident avoidance.     

西部水资源开发利用风险现状评价

我国实施西部大开发战略后,西部水资源开发利用问题变得越来越突出.为了弄清楚西部水资源开发利用存在的风险现状,本文在风险概念的基础上探讨了水资源开发利用风险概念和影响因素,并构建了西部水资源开发利用风险评价指标体系.根据水资源系统表现出多模态、突跳和发散的基本突变特征,论述了运用突变理论评价水资源开发利用风险具有一定的可行性,将突变理论引入到水资源开发利用风险评价中,对西部水资源开发利用风险进行评价.首先对各项风险评价指标按照重要性排序,并对各指标值进行无量纲化;然后利用突变模型的归一公式和突变模型的评价准则进行递归运算,最后求出各层指标相对风险值(突变隶属度),将评价结果与风险等级对照,综合判断和分析各层各项指标相对风险状况.计算结果表明:在西部12个省份中,各层指标的风险值差异显著,但是水资源开发利用综合风险值分布在0 66-0.92之间,总体上属于中高度风险水平,12省份风险从小到大排序为:西藏→陕西→重庆→四川→青海→云南→贵州→广西→内蒙→甘肃→新疆→宁夏,这一结果与西部12省份水资源开发利用实际状况相符,可以为西部大开发过程水资源合理有效利用和管理提供风险决策参考依据.     

三峡二期工程与湖北的机遇和挑战

１９９７年１１月１８日,三峡工程大江截流成功,标志着第一期工程结束、进入第二期工程实施阶段。长江三峡水利枢纽具有防洪、发电、航运和供水等巨大综合效益,是跨世纪特大型水利工程。它的建设,不仅对我国能源秘至整个经济布局产生极大的影响,而且对湖北长江经济带的形成与发展具有决定性的意义。