环状扩散管-分级采样器的建立和细粒子酸性的测定

建立了国内第一台扩散管－分级采样器，用来研究大气气胶溶胶的组成和细粒子的酸性，实验证明该采样系统能够有效地避免大气中的碱性物质对颗粒物采样的干扰。在北京，湖南等地进行了现场实验，测定了气溶胶的酸性。     

全球环境变化与全球不平等南北方的不同立场

全球环境变化给发展中国家和南北关系带来深刻影响，理解环境问题的全球不平等需要以发展中国家80年代开始的经济结构调整和沉重债务为背景。南方的环境政策优先在很大程度上与其生活的可持续性相连，而不是通常与全球环境变化的长期性风险相关，然而，全球环境变化又与发展中国家贫困人口的日常生活紧密相关。从南方的立场看，当“问题”对他们不十分迫切时，就很难同意采取措施，仅此原因，北方对全球环境变化的关切要得到成功回应，真正的全球契约就需要解决基本“发展”问题，主要是贫困。     

ICP/MS法测定酸雨中的Pb

采用 ICP/MS法分析酸雨中的 Pb元素 ,在优化的工作条件下 ,研究可能的干扰影响及选择合适的内标元素( Y89) ,同时测定 Pb的同位比以确定大气中 Pb的污染。 Pb的检出限 0 .0 0 2～ 0 .0 0 3ppb,相对标准偏差 0 .0 2 %～ 2 .0 1%     

物化—生化组合工艺在鱼油工业废水处理中的应用

针对鱼油工业废水排放特点及处理技术难点，结合实例，采用混凝、破乳进行物化预处理；采用A／O生化处理技术，提出合适的工艺流程。     

Experimental and theoretical studies on NO selective catalytic oxidation over α-MnO2

Based on the experimental and theoretical methods, the NO selective catalytic oxidation process was proposed. The experimental results indicated that lattice oxygen was the active site for NO oxide over the $\mathrm{\alpha }$-MnO₂(110) surface. In the theoretical study, DFT (density functional theory) and periodic slab modeling were performed on an $\mathrm{\alpha }$-MnO₂(110) surface, and two possible NO oxidation mechanisms over the surface were proposed. The non-defect $\mathrm{\alpha }$-MnO₂(110) surface showed the highest stability, and the surface O_s (the second layer oxygen atoms) position was the most active and stable site. O₂ molecule enhanced the joint adsorption process of two NO molecules. The reaction process, including O₂ dissociation and O=N-O-O-N=O formation, was calculated to carry out the NO catalytic oxidation mechanism over $\mathrm{\alpha }$-MnO₂(110). The results showed that NO oxidation over the $\mathrm{\alpha }$-MnO₂(110) surface exhibited the greatest possibility following the route of O=N-O-O-N=O formation. Meanwhile, the formation of O=N-O-O-N=O was the rate-determining step.     

多级A/O工艺在国内的应用现状

多级A/O工艺目前在国内市政和部分工业污水处理领域应用较多,具有预处理和污泥处理系统简单,污泥负荷低、处理效果好且稳定,投资低,曝气系统效率高、运行成本较低,维护管理简便等特点,但是在实际运行中也发现存在一些问题,如土池结构不适合地下水位高的地区的局限性,沉淀池效果较差、稳定池多余占地且污泥淤积难以清除,关键设备国产质量有待提高,工业污水处理少数水质指标偏高,需要设计人员选择适合其条件的场合应用,并进一步总结、改进和完善.     

Catalytic dechlorination of o-chlorophenol by nanoscale Pd/Fe

IntroductionTheuseofzerovalentironforthetreatmentofchlorinatedorganiccompounds (COCs )inwaterandgroundwaterhasbeenthefocusofmuchrecentresearch .Thestudieswereconcernedwithcompoundssuchascarbontetrachloride(Bradley ,1995 ) ,trichloroethene(Orth ,1996 ;Chen ,2 0 0 1)andpesticidesandrelatedcompounds(Sayles,1997;Monson ,1998;Eykholt,2 0 0 1;Dombek ,2 0 0 1) .Whenironisincontactwithalessreductivemetal,themetalcouplecanformgalvaniccells.ThishasledtothediscoveryofPd Febimetalliccomplexinwhichpal…     

2-Chlorophenol oxidation kinetic by photo-assisted Fenton process

Experimental data are presented to test and validate a kinetic model for the oxidation of 2-chlorophenol wastewater by photo-assisted Fenton process. The data showed that this process had produced good effects under acidic conductions. Up to 90% 2-chlorophenol was removed after 90-minute reaction time with H2O2 of 25% CODCr. in, while in UV/H2O2 system ordy 16.8% 2-chlorophenol was removed after one hour treatment. The optimal pH in this reaction occurred between pH 3.0 and pH 4.0. The reaction kinetics for photo-assisted Fenton process experimented in this research was investigated. Kinetic models were proposed for the treatment of 2-chlorophenol wastewater. The reaction was found to follow the 2nd order. The equations of reaction kinetics are as follows:-d[RH]/dt=KRH[RH][H2O2]0exp(-KH2o2t);-d[CODCr]/dt=KCODCr[CODCr][H2O2]0exp(-K′t).The prediction of the models was found to be in a good agreement with experimental results, thus confimfing the proposed reaction mechanism.     

Catalytic dechlorination of chlorobenzene in water by Pd/Fe bimetallic system

IntroductionChlorinatedorganiccompoundshavebeenusedonalargescaleinthechemical,petrochemical,andelectronicindustries.Inrecentyears ,worldwideattentionhasbeengiventotheenvironmentalandhealthimpactofthemasaclassofcontaminants .Severalareknowntocauseozonedepletion ,whileothersproduceadverseeffectsonthehumancentralnervoussystemandhavebeenlinkedtodiseasessuchascancer.Almostallofthechlorinatedaromaticcompoundsaretoxicandthermallystable .Oncereleasedintoenvironment,theywillaccumulateinthesurroundings…     

Catalysts for decomposing ozone tail gas

The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity.