中国人口集疏格局与形成机制研究

人口集聚和疏散是人口空间分布格局最直观和最集中的体现,基于人口集聚度的中国人口集疏的空间格局和形成机制的研究,有助于准确把握中国人口空间分布的基本脉络,具有重要的学术价值和实践意义。研究采用了人口集聚度分级评价的方法,依据人口集聚度的不同,将各个地区划分为不同等级的人口集聚区,并对其分别讨论。在此基础上,结合中国人口分布格局、自然条件的空间分布格局、人居环境自然适宜性评价结果以及经济发展格局和城市化格局,对中国的人口集疏的空间格局进行了归纳,并进一步对相应的形成机制进行了探讨,得出了我国人口分布的空间不平衡日益加剧,并呈现沿海、沿江、沿线集聚的态势的基本结论,并对我国人口分布集疏格局的形成进行了探讨,提出了自然因素奠定我国人口分布的基本格局,而经济发展不平衡与城市化成为人口集聚的动力的观点。     

Diffusion mechanism of lindane into wood charcoal

Abstract

The wood charcoal treated by 1N HNO₃ (WCT) was used to remove toxic chlorinated pesticide lindane (y‐HCH) residue from water by the sorption process. Using a simple first order reversible kinetics constants and half time equations, the film and pore diffusion coefficients were determined. Film diffusion was found to be rate limiting step in sorbing lindane by WCT. This was further authenticated by kinetics studies at different initial sorbate concentrations, different sorbent sizes, and different agitation speeds besides interruption test. A pore diffusion model was used to fit the data of kinetics in continuously mixed batch reactors (CMBR), and the tortuosity, external resistance, and surface diffusion effects on lindane sorption by WCT were noticed. The tortuosity values of 15 to 28 were obtained for WCT‐lindane system.     

Outdoor Weathering Evaluation of Carbon-Black-Filled, Biodegradable Copolyester as Substitute for Traditionally Used, Carbon-Black-Filled, Nonbiodegradable, High-Density Polyethylene Mulch Films

Carbon-black-filled, biodegradable, copolyester mulch film (Eastar®, or EA, Tennessee Eastman, Kingsport, TN) and commercial carbon-black-filled, high-density polyethylene (HDPE) mulch film were exposed for 12 weeks to commercial vegetable crop growing conditions by being placed directly on irrigated soil in the field of the University of Tennessee Alcoa Highway State Agriculture Experiment Station (Knoxville, TN) and by being placed on a plywood exposure rack as described by the American Society of Testing and Materials (ASTM) Standard Test Method 1435: Outdoor Weathering of Plastics. Mechanical properties and weather information were collected in order to evaluate the feasibility of using the newly developed biodegradable EA mulch film to replace the nonbiodegradable HDPE mulch film. Results indicate that the EA mulch film exhibited favorable tensile strength and elongation-at-break during outdoor exposure rack testing and outdoor, in-field, placed directly on the soil, exposure testing, suggesting biodegradable EA could be a substitute for the HDPE nonbiodegradable material.     

四川彭县银厂沟峡谷自然景观成因初探

四川省彭县银厂沟峡谷全长21公里,峡谷和原始森林保存完整。时隐时现的“彩虹”出现于峡谷两岸的瀑布上。区内自然景观丰富多彩。本文根据旅游地质调查工作成果,对自然景观的成因作了初步探讨。     

绵阳市大气降水pH值时空分布及酸雨成因研究

通过对绵阳市9个测点1998－1999年大气降水监测数据的统计分析，并结合历史数据，对大气降水pH值的时空分布及酸雨成因进行了研究。结果表明：绵阳市大气降水酸化严重，除主要受本地区大气污染影响外，还受大气中、长距离输送的影响。     

论地膜污染与防治对策

随着地膜覆盖栽培年限的延长，由于残膜回收率低，土壤中残膜量逐步增加，造成地膜污染。通过分析地膜污染对环境和农作物产生的危害，对回收残膜存在的问题，总结出了防治地膜污染的对策与措施。     

测定单个粒子的薄膜法及其应用

本文介绍改进后的薄膜法,主要是形态分析法和复合薄膜法。它们都是基于粒子和薄膜反应生成物的形态特征通过电镜来确定粒子成分的。前者可以检测单个酸性粒子,检出下限为７ ×１０－ １９ｇ;后者能同时检出一个粒子中所含的ＮＯ－３ 和ＳＯ２ －４ ,检出下限分别为３ ×１０－ １５ｇ 和７ ×１０－ １８ｇ。利用该方法对广州大气粒子进行了观察,结果表明改进后的薄膜法完全适用于对单个粒子的观察和测定。     

The ecological effects of trichloroacetic acid in the environment

Trichloroacetic acid (TCAA) is a member of the family of compounds known as chloroacetic acids, which includes mono-, di- and trichloroacetic acid. The significant property these compounds share is that they are all phytotoxic. TCAA once was widely used as a potent herbicide. However, long after TCAA's use as a herbicide was discontinued, its presence is still detected in the environment in various compartments. Methods for quantifying TCAA in aqueous and solid samples are summarized. Concentrations in various environmental compartments are presented, with a discussion of the possible formation of TCAA through natural processes. Concentrations of TCAA found to be toxic to aquatic and terrestrial organisms in laboratory and field studies were compiled and used to estimate risk quotients for soil and surface waters. TCAA levels in most water bodies not directly affected by point sources appear to be well below toxicity levels for the most sensitive aquatic organisms. Given the phytotoxicity of TCAA, aquatic plants and phytoplankton would be the aquatic species to monitor for potential effects. Given the concentrations of TCAA measured in various soils, there appears to be a risk to terrestrial organisms. Soil uptake of TCAA by plants has been shown to be rapid. Also, combined uptake of TCAA from soil and directly from the atmosphere has been shown. Therefore, risk quotients derived from soil exposure may underestimate the risk TCAA poses to plants. Moreover, TCE and TCA have been shown to be taken up by plants and converted to TCAA, thus leading to an additional exposure route. Mono- and di-chloroacetic acids can co-occur with TCAA in the atmosphere and soil and are more phytotoxic than TCAA. The cumulative effects of TCAA and compounds with similar toxic effects found in air and soil must be considered in subsequent terrestrial ecosystem risk assessments.     

Formation of Soluble Complexes of Metals with Humic Acid and Its Environmental Significance

In order to investigate the role of functional groups present in humic acid(s) (HA) during complex formation, water soluble complexes between HA isolated from soil and metals (Pb, Ca, As, Ni, Cr, Co, Cu, Cd, Fe, Mn, Mg and Zn) were prepared and subjected to infrared (IR) spectroscopy. the IR data revealed the involvement of the - OH group of humic acid in complex formation with all metals except copper and arsenic, whereas the - COOH group of HA was found to be the preferred site of binding for all the metals. the significance of findings in relation to detoxification of environmental pollutants is discussed in this paper.     

降膜对喷淋塔吸收特性的影响

吸收液在喷淋塔内以液滴和降膜两种形式存在,为了深入考察降膜对喷淋塔吸收特性的影响,以多孔分布板代替传统的压力式喷嘴,实现了降膜和液滴流量的可控调节,结合喷淋塔流体力学特性和双膜理论,建立了液滴及降膜的传质模型,并进行了试验验证,通过定量计算,分别考察了喷淋量及空塔气速对降膜吸收速率分率的影响.结果表明:所建模型可以较好地模拟喷淋塔脱氨过程,相对误差小于4％;降膜吸收速率分率几乎不随空塔气速而变化,但随喷淋量增大而减小;当大量吸收液在塔内壁形成降膜时,要达到相同吸收率所需喷淋液量将更大.