用扫描电镜分析表征大气气溶胶单颗粒

1　IntroductionAtmosphericaerosolsarecomplexmixture,originatedfromavarietyofsources.Mostoftheanalyticaltechniquesusedforitscharacterizationarebulkmethodsthatgenerateonesetofdatapersample,describingtheoverallcompositionofthesample .Toworkoutusefulinformationonpollu tionsources,itrequiresdataofagreatnumberofsamplesandmultivariatedataanalysismethodsusuallyareneeded .Ontheotherhand ,scanningelectronmicroscope energydispersiveX rayanaly sissystem (SEM EDX)isabletoprovideanalyticaldataforeachsing…     

近岸水域船舶溢油应急保障能力评估

为了降低溢油事故对近岸水域造成的影响,提高近岸水域船舶溢油事故应急响应系统的能力,采用结构方程模型,评价船舶溢油应急保障能力。在分析近岸水域船舶溢油应急响应系统影响因素的基础上,构建了船舶溢油应急保障能力评价的指标体系,引入结构方程模型,建立船舶溢油应急保障能力分析的路径模型,分析应急保障变量之间的互动关系及其影响程度,研究其算法,并以实例验证模型的可行性。结果表明,人员保障在溢油应急保障能力中起主导作用,其次是物资保障和技术保障。     

茂名高岭土矿高岭石的矿物学特征及其涂布性能

茂名高岭土矿的高蛉石,有序度高,晶粒细小(<2微米),沿α、b轴横向连结,无书册状、蠕虫状的大集晶,SiO_2/Al_2O_3值接近高岭石的理论值,Fe_2O_3、TiO_2等杂质含量低于0.5％,并可加工分离,为当前有开发前景的优质涂布原料。     

低浓度有机废气纳米TiO2光催化处理技术

对常用有机废气净化技术进行了比较分析,以活性炭过滤网的强吸附性复合TiO2光催化剂研究为主,分析了纳米TiO2光催化处理低浓度有机废气的反应原理,叙述了几种常见负载型TiO2光催化剂的制备方法,影响TiO2光催化效率的因数及提高TiO2光催化剂的催化性能方式.     

地铁乘客疏散帮助行为及其影响因素的SEM模型*

为研究地铁疏散中乘客帮助行为及其影响因素之间的作用机制,通过对武汉市地铁站乘客疏散行为进行问卷调查,从普通乘客特征、特殊群体特征、安全认知、疏散环境和恐慌心理5个维度出发,构建地铁乘客疏散帮助行为及其影响因素的结构方程模型。研究结果表明:普通乘客特征、特殊群体特征、安全认知对帮助行为具有直接正向影响,其中安全认知对乘客是否提供帮助行为的影响最大;恐慌心理、疏散环境对帮助行为具有直接负向影响,其中恐慌心理影响较大;安全认知还通过中介变量普通乘客特征、特殊群体特征、疏散环境和恐慌心理对帮助行为产生间接影响。     

武汉市主要绿化树种滞尘效应研究

本实验对武汉市城区主干道主要绿化树种的滞尘效应与叶表面结构进行了研究。结果表明：（1）同一尘源条件下,不同树种的滞尘能力差异显著。乔木中悬铃木滞尘能力较高,可达6.9345 g/m²;小乔木中紫薇和紫叶李是滞尘能力较高的树种,滞尘能力分别为1.9543 g/m²和1.8790 g/m²;灌木中红花檵木和杜鹃等有较强的滞尘能力,分别可达4.0373 g/m²和3.8875 g/m²;（2）利用扫描电镜观察叶表面结构发现：叶表具毛被、褶皱、较深的不规则网格等特征的树种滞尘能力较高,叶表平滑或叶表网格结构规则且较浅时滞尘能力较低;（3）同一树种在不同的尘源条件下滞尘能力差异显著,空气中颗粒物浓度越高,滞尘能力也越大。以车流量近似模拟尘源条件表明,滞尘能力与车流量呈正相关。     

Preparation of Alginic Acid and Metal Alginate from Algae and their Comparative Study

Alginic acid and metal alginates are prepared from fresh algae using extraction method. A FTIR spectrum indicates that alginic acid is converted into the metal alginate. Comparing calcium and cobalt alginates, asymmetric stretching of free carboxyl group of calcium alginate at 1630 cm⁻¹ is shifted to 1585 cm⁻¹ in cobalt alginate, due to the change of charge density, radius and atomic weight of the cation, creating a new environment around the carbonyl group. The strong exothermic peak of alginic acid in DSC thermogram indicates the decomposition of biopolymer, whereas strong exothermic peak of metal alginate in DSC thermogram attributed to the decomposition of biopolymer and formation of respective carbonate. Based on DSC study, the decomposition of cobalt alginate occurs at higher temperature comparing to those of sodium and calcium alginate, which may conclude into the higher stability of cobalt alginate. TGA results reveal that, cobalt alginate is more stable than calcium and sodium alginate at 300 °C temperature. Surface morphology (at same magnification), as well as porosity (%) and pore size distribution results change with metals present in different metal alginates.     

Analysis of Heavy Metals in the Endometrial Tissue Using Electron Microscope

Objective This study was done to estimate whether heavy metals in the air may affect endometrial chemical composition. Materials and Methods A total of 30 albino Wistar rats were employed and randomly divided into three groups. The rats of Group 1 and 2 were acutely and sub-chronically exposed to the gas form of heavy metals, respectively. Group 3 was used as a control group. Endometrial tissue worth of heavy metals of the groups was measured in through using scanning electron microscope. Results A statistically no significant difference was found for endometrial chemical composition of all of the heavy metals (chrome, manganese, iron, cobalt, nickel, zinc and lead) between group 1 and 2 (p > 0.05). On the other hand, there was statistically significant difference for all of the heavy metals between group 1 and group 3 (p < 0.05), while there was statistically significant difference for chrome, manganese, iron, cobalt and nickel (p < 0.05), but zinc and lead (p > 0.05) between group 2 and 3. Conclusion Air pollutants of Pb and Zn resulting mostly from combustion of fossil fuels and certain special industrial process in Kirikkale may be a risk factor for the high pregnancy loses by changing endometrial homeostasis.     

可见光均相氧化法降解吖啶橙染料的特性

一种难降解的染料吖啶橙 (AO)在可见光照射下的 photo-Fenton降解实验结果表明 ,在三价铁离子和双氧水存在下吖啶橙可以被降解 ,且可见光可以极大地加快降解的速度 .另外 ,还对降解过程中的 pH、Fe²⁺以及草酸盐和表面活性剂对降解速度的影响进行了研究 ,发现草酸盐的加入降低了降解速度而表面活性剂十二烷基苯磺酸钠 (DBS)提高了降解的速度 .     

基于结构方程模型的安全文化影响因子分析

为进一步研究安全文化,采用结构方程模型(SEM)对安全文化的关键要素、构成因子以及因子间的因果关系进行研究。利用SPSS对山东4个国有煤矿355名员工安全文化定量测量数据进行分析。采用主成分抽取方法对安全文化关键要素进行因子分析,抽取特征根大于1的5个因子,解释变量的累积百分比为69.35%。同时运用结构方程模型软件(AMOS)构建安全文化结构模型以及安全文化因子间因果关系结构模型,证实领导责任因子对安全理念、安全认知和员工参与有直接正面影响。其中,对安全认知的影响最为显著(其路径系数为0.76);领导责任因子对安全业绩具有间接正面影响;安全理念、安全认知和员工参与对安全业绩具有直接正面影响。