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581.
582.
对炼油废水处理场现有工艺进行流程优化,将MBR装置调整在接触氧化池之后运行.优化流程后氨氮平均去除率可从近于0提高至71.70%;COD平均去除率可从50.00%提高至72.00%.通过对工艺流程的对比,分析了现有工艺氨氮质量浓度难以降低的原因,指出废水中存在的某些污染物对硝化细菌起到抑制作用,减少了反应器中硝化细菌的... 相似文献
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585.
以Ti3AlC2为原料,采用HF刻蚀工艺制备出12种Ti3C2纳米层状材料,对其形貌进行了表征,并考察了以其作为光催化剂对废水中Cr(Ⅵ)的处理效果。实验结果表明:HF体积分数为80%、刻蚀时间为48 h时得到的MX-80-48的形貌较好;MX-80-48具有类似石墨烯的二维层状结构,纳米层厚度约20~50 nm,孔径2~10 nm,比表面积14.8 m2/g,在400~700 nm可见光范围内表现出强烈的吸光性;当Cr(Ⅵ)的初始质量浓度为40.00 mg/L、MX-80-48投加量为200 mg/L、pH=2、反应时间4 h(暗反应1 h+光照3 h)时,Cr(Ⅵ)去除率可达100%。 相似文献
586.
Subgrade biogeochemical reactors (SBGRs) are an in situ remediation technology shown to be effective in treating contaminant source areas and groundwater hot spots, while being sustainable and economical. This technology has been applied for over a decade to treat chlorinated volatile organic compound source areas where groundwater is shallow (e.g., less than approximately 30 feet below ground surface [ft bgs]). However, this article provides three case studies describing innovative SBGR configurations recently developed and tested that are outside of this norm, which enable use of this technology under more challenging site conditions or for treatment of alternative contaminant classes. The first SBGR case study addresses a site with groundwater deeper than 30 ft bgs and limited space for construction, where an SBGR column configuration reduced the maximum trichloroethene (TCE) groundwater concentration from 9,900 micrograms per liter (μg/L) to <1 μg/L (nondetect) within approximately 15 months. The second SBGR is a recirculating trench configuration that is supporting remediation of a 5.7‐acre TCE plume, which has significant surface footprint constraints due to the presence of endangered species habitat. The third SBGR was constructed with a new amendment mixture and reduced groundwater contaminant concentrations in a petroleum hydrocarbon source area by over 97% within approximately 1 year. Additionally, a summary is provided for new SBGR configurations that are planned for treatment of additional classes of contaminants (e.g., hexavalent chromium, 1,4‐dioxane, dissolved explosives constituents, etc.). A discussion is also provided describing research being conducted to further understand and optimize treatment mechanisms within SBGRs, including a recently developed sampling approach called the aquifer matrix probe. 相似文献
587.
Investigation of titanium liquid/gas diffusion layers in proton exchange membrane electrolyzer cells
Stuart M. Steen III Jingke Mo Zhenye Kang Gaoqiang Yang 《International Journal of Green Energy》2017,14(2):162-170
In a proton exchange membrane electrolyzer cell (PEMEC), liquid/gas diffusion layer (LGDL) is expected to transport electrons, heat, and reactants/products to and from the catalyst layer with minimum voltage, current, thermal, interfacial, and fluidic losses. In addition, carbon materials, which are typically used in PEM fuel cells (PEMFCs), are unsuitable in PEMECs due to the high ohmic potential and highly oxidative environment of the oxygen electrode. In this study, a set of titanium gas diffusion layers with different thicknesses and porosities are designed and examined coupled with the development of a robust titanium bipolar plate. It has been found that the performance of electrolyzer improves along with a decrease in thickness or porosity of the anode LGDL of titanium woven meshes. The ohmic resistance of anode LGDL and contact resistance between anode LGDL and the anode catalyst play dominant roles in electrolyzer performance, and better performance can be obtained by reducing ohmic resistance. Thin titanium LGDLs with straight-through pores and optimal pore morphologies are recommended for the future developments of low-cost LGDLs with minimum ohmic/transport losses. 相似文献
588.
Damjana Drobne ?iva Pipan Tkalec 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1157-1164
A single-species laboratory test with terrestrial invertebrates was used to identify the hazard of nanosized TiO2. Feeding parameters, weight change, mortality, and the activities of catalase and glutathione-S-transferase were evaluated after 3 or 14 days of dietary exposure. The effects of nano-TiO2 were dependent on exposure concentration and duration, total consumed quantity, size and pre-treatment of particles. The intensity of a response was ruled by duration of exposure and not by consumed quantity of nano-TiO2 or exposure concentration as expected. The response to nano-TiO2 is described as threshold-like. The exposure concentrations 10-1000 μg TiO2/g dry food (1.35-1025 μg of total consumed quantity of TiO2/g animal wet wt.) were identified as safe for tested species after tested exposure period. We conclude that the response to nanoparticles is different from that of soluble chemicals therefore these two types of data should be interpreted and processed differently. 相似文献
589.
Fate of pharmaceuticals and personal care products in wastewater treatment plants - Conception of a database and first results 总被引:1,自引:0,他引:1
C. Miège J.M. Choubert L. Ribeiro M. Eusèbe M. Coquery 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1721-1726
We created a database in order to quantitatively assess the occurrence and removal efficiency of pharmaceuticals and personal care products (PPCPs) in wastewater treatment plants (WWTPs). From 117 scientific publications, we compiled 6641 data covering 184 PPCPs. Data included the concentrations of PPCPs in WWTP influents and effluents, their removal efficiency and their loads to the aquatic environment. The first outputs of our database allowed to identify the most investigated PPCPs in WWTPs and the most persistent ones, and to obtain reliable and quantitative values on their concentrations, frequency of detection and removal efficiency in WWTPs. We were also able to compare various processes and pointed out activated sludge with nitrogen treatment and membrane bioreactor as the most efficient ones. 相似文献
590.
A.O. Babatunde Y.Q. Zhao M.A. Morris 《Environmental pollution (Barking, Essex : 1987)》2009,157(10):2830-2836
Aluminium-based water treatment residual (Al-WTR) is the most widely generated residual from water treatment facilities worldwide. It is regarded as a by-product of no reuse potential and landfilled. This study assessed Al-WTR as potential phosphate-removing substrate in engineered wetlands. Results indicate specific surface area ranged from 28.0 m2 g−1 to 41.4 m2 g−1. X-ray Diffraction, Fourier transform infrared and energy-dispersive X-ray spectroscopes all indicate Al-WTR is mainly composed of amorphous aluminium which influences its phosphorus (P) adsorption capacity. The pH and electrical conductivity ranged from 5.9 to 6.0 and 0.104 dS m−1 to 0.140 dS m−1 respectively, showing that it should support plant growth. Batch tests showed adsorption maxima of 31.9 mg P g−1 and significant P removal was achieved in column tests. Overall, results showed that Al-WTR can be used for P removal in engineered wetlands and it carries the benefits of reuse of a by-product that promotes sustainability. 相似文献