Role of secondary aerosols in haze formation in summer in the Megacity Beijing

A field experiment from 18 August to 8 September 2006 in Beijing, China, was carried out. A hazy day was defined as visibility < l0 km and RH (relative humidity) < 90%. Four haze episodes, which accounted for ~ 60% of the time during the whole campaign, were characterized by increases of SNA (sulfate, nitrate, and ammonium) and SOA (secondary organic aerosol) concentrations. The average values with standard deviation of SO₄^2 −, NO₃⁻, NH₄⁺ and SOA were 49.8 (± 31.6), 31.4 (± 22.3), 25.8 (± 16.6) and 8.9 (± 4.1) μg/m³, respectively, during the haze episodes, which were 4.3, 3.4, 4.1, and 1.7 times those in the non-haze days. The SO₄^2 −, NO₃⁻, NH₄⁺, and SOA accounted for 15.8%, 8.8%, 7.3%, and 6.0% of the total mass concentration of PM₁₀ during the non-haze days. The respective contributions of SNA species to PM₁₀ rose to about 27.2%, 15.9%, and 13.9% during the haze days, while the contributions of SOA maintained the same level with a slight decrease to about 4.9%. The observed mass concentrations of SNA and SOA increased with the increase of PM₁₀ mass concentration, however, the rate of increase of SNA was much faster than that of the SOA. The SOR (sulfur oxidation ratio) and NOR (nitrogen oxidation ratio) increased from non-haze days to hazy days, and increased with the increase of RH. High concentrations of aerosols and water vapor favored the conversion of SO₂ to SO₄^2 − and NO₂ to NO₃⁻, which accelerated the accumulation of the aerosols and resulted in the formation of haze in Beijing.     

中亚热带次生林成林规律及经营技术研究——Ⅰ.次生林环境背景分析与类型划分

本文分析了湖南省中亚热带次生林优势种群间的联结和环境梯度。通过研究,将全省次生林划分为8大类型即暖性针叶林、温性针叶林、干热性常绿阔叶林、干暖性常绿阔叶林、暖湿性常绿阔叶林、温湿性常绿阔叶林、暖性落叶阔叶林和温性落叶阔叶林等。     

城市污水二级处理出水用于地下回灌的深度处理技术研究

采用混凝沉降-砂滤-活性炭吸附-消毒工艺,对模拟城市污水处理厂二级处理工艺的SBR中试系统的出水进行了深度处理实验研究。实验结果表明,深度处理后的出水所检测的浊度、pH、COD、NH3-N、细菌总数等5项指标已经达到了《生活饮用水卫生标准》（GB5749—2006）。     

Removal efficiencies of natural and synthetic progesterones in hospital wastewater treated by different disinfection processes

● The concentrations of 61 progesterones in HWW, PFTE, SBTE were evaluated. ● The removal efficiencies of progesterones by PFT and SBT were identified. ● Compared the removal efficiencies of progeste rones in five disinfection processes. Progesterones are ubiquitous in hospital wastewater (HWW) with concentrations much higher than those of estrogens and androgens. To ensure that these water systems are safe to use, disinfection is crucial during HWW treatment by providing “front line” defense against biological contaminations. Here, five disinfection processes, namely, chlorine (Cl₂), chlorine dioxide (ClO₂), ozone (O₃), ultraviolet (UV)), and UV/chlorine (UV/Cl₂), were selected to investigate their removal efficiencies for progesterones in primary filtration and secondary biological treatment effluents. There were 61 natural and synthetic progesterones detected in HWW, with the natural progesterones being the main components with a concentration of 845.51 ng/L and contributing to 75.08% of the total progesterones. The primary filtration treatment presented insignificant removal effects on the progesterones, while the secondary biological treatment significantly reduced the progesterone content by biodegradation. The order of removal efficiencies of total progesterones by different disinfection processes was UV/Cl₂ > Cl ₂ > O ₃ > ClO ₂ > UV. UV/Cl ₂ showed the highest removal efficiency against progesterones mainly due to the activation of Cl₂ by ultraviolet (UV) photolysis, which helps open the heterocyclic, aromatic, and phenolic rings, thus accelerating progesterone degradation. In addition, the removal efficiencies of natural progesterones in the five disinfection processes were higher than those of synthetic progesterones (progesterone derivatives, 19-nortestosterone derivatives, and 17α-hydroxyprogesterone derivatives).     

Biogenic volatile organic compound emission patterns and secondary pollutant formation potentials of dominant greening trees in Chengdu, southwest China

Integral to the urban ecosystem, greening trees provide many ecological benefits, but the active biogenic volatile organic compounds (BVOCs) they release contribute to the production of ozone and secondary organic aerosols, which harm ambient air quality. It is, therefore, necessary to understand the BVOC emission characteristics of dominant greening tree species and their relative contribution to secondary pollutants in various urban contexts. Consequently, this study utilized a dynamic enclosure system to collect BVOC samples of seven dominant greening tree species in urban Chengdu, Southwest China. Gas chromatography/mass spectrometry was used to analyze the BVOC components and standardized BVOC emission rates of each tree species were then calculated to assess their relative potential to form secondary pollutants. We found obvious differences in the composition of BVOCs emitted by each species. Ficus virens displayed a high isoprene emission rate at 31.472 μgC/(gdw (g dry weight)•hr), while Cinnamomum camphora emitted high volumes of D-Limonene at 93.574 μgC/(gdw•hr). In terms of the BVOC emission rates by leaf area, C. camphora had the highest emission rate of total BVOCs at 13,782.59 μgC/(m²•hr), followed by Cedrus deodara with 5466.86 μgC/(m²•hr). Ginkgo biloba and Osmanthus fragrans mainly emitted oxygenated VOCs with lower overall emission rates. The high BVOC emitters like F. virens, C. camphora, and Magnolia grandiflora have high potential for significantly contributing to environmental secondary pollutants, so should be cautiously considered for future planting. This study provides important implications for improving urban greening efforts for subtropical Chinese urban contexts, like Chengdu.     

Assessing the influence of environmental conditions on secondary organic aerosol formation from a typical biomass burning compound

The atmospheric chemistry in complex air pollution remains poorly understood. In order to probe how environmental conditions can impact the secondary organic aerosol (SOA) formation from biomass burning emissions, we investigated the photooxidation of 2,5-dimethylfuran (DMF) under different environmental conditions in a smog chamber. It was found that SO₂ could promote the formation of SOA and increase the amounts of inorganic salts produced during the photooxidation. The formation rate of SOA and the corresponding SOA mass concentration increased gradually with the increasing DMF/OH ratio. The addition of (NH₄)₂SO₄ seed aerosol accelerated the SOA formation rate and significantly shortened the time for the reaction to reach equilibrium. Additionally, a relatively high illumination intensity promoted the formation of OH radicals and, correspondingly, enhanced the photooxidation of DMF. However, the enhancement of light intensity accelerated the aging of SOA, which led to a gradual decrease of the SOA mass concentration. This work shows that by having varying influence on atmospheric chemical reactions, the same environmental factor can affect SOA formation in different ways. The present study is helpful for us to better understand atmospheric complex pollution.     

Machine learning and theoretical analysis release the non-linear relationship among ozone, secondary organic aerosol and volatile organic compounds

Fine particulate matter (PM_2.5) and ozone (O₃) pollutions are prevalent air quality issues in China. Volatile organic compounds (VOCs) have significant impact on the formation of O₃ and secondary organic aerosols (SOA) contributing PM_2.5. Herein, we investigated 54 VOCs, O₃ and SOA in Tianjin from June 2017 to May 2019 to explore the non-linear relationship among O₃, SOA and VOCs. The monthly patterns of VOCs and SOA concentrations were characterized by peak values during October to March and reached a minimum from April to September, but the observed O₃ was exactly the opposite. Machine learning methods resolved the importance of individual VOCs on O₃ and SOA that alkenes (mainly ethylene, propylene, and isoprene) have the highest importance to O₃ formation; alkanes (C_n, n ≥ 6) and aromatics were the main source of SOA formation. Machine learning methods revealed and emphasized the importance of photochemical consumptions of VOCs to O₃ and SOA formation. Ozone formation potential (OFP) and secondary organic aerosol formation potential (SOAFP) calculated by consumed VOCs quantitatively indicated that more than 80% of the consumed VOCs were alkenes which dominated the O₃ formation, and the importance of consumed aromatics and alkenes to SOAFP were 40.84% and 56.65%, respectively. Therein, isoprene contributed the most to OFP at 41.45% regardless of the season, while aromatics (58.27%) contributed the most to SOAFP in winter. Collectively, our findings can provide scientific evidence on policymaking for VOCs controls on seasonal scales to achieve effective reduction in both SOA and O₃.     

兰州市排污权交易制度研究

作为市场手段和环境治理结合所产生排污权交易制度,被越来越多的国家和地区证明其对缓解环境问题有着独特的、重要的作用。随着我国市场经济的深入发展、市场条件的日趋成熟,排污权交易也在国内许多省市进行深入试点,并产生了一定的效益。本文从排污权交易理论出发,结合兰州的污染现状,论证兰州市实行排污权交易的必要性和可行性。最后,在借鉴国内外排污权交易成功经验的基础上,对兰州市排污权交易制度的构建提出建议。     

Effect of shock strength on dust entrainment behind a moving shock wave

Secondary dust explosion is a serious industrial issue because it occurs under conditions corresponding to an increased quantity and concentration of dispersed, combustible dust when compared with the primary explosion. The problems of lifting and dispersion of a dust layer behind a propagating shock wave must therefore be understood to ensure safety regarding secondary dust explosion hazards. Using a new shock-tube facility for studying shock propagation over dust layers, limestone dust was subjected to Mach numbers ranging from 1.10 to 1.60. A shadowgraph technique was applied by using a high-speed camera (15,000 fps) for visualization of the dust-layer height change behind the moving shock wave. Also, the effect of dust-layer thickness on the entrainment process was observed by performing tests with two different layer depths, namely 3.2- and 12.7-mm thicknesses. New correlations were developed between the shock strength and the dust entrainment height as a function of time for each layer depth. In general, the results herein are in agreement with trends found in previous work, where there is a linear relationship between dust growth rate and shock Mach number at early times after shock passage. Also, new data were collected for image analyses over longer periods, where the longer observation time and higher camera framing rates led to the discovery of trends not previously observed by earlier studies, namely a clear transition time between the early, linear growth regime and a much-slower average growth regime. This second regime is however accompanied by surface instabilities that can lead to a much larger variation in the edge of the dust layer than seen in the early growth regime. In addition, for the linear growth regime, there was no significant difference in the dust-layer height growth between the two layer thicknesses; however, the larger thickness led to higher growth rates and much larger surface instabilities at later times.     

四角切圆燃烧锅炉冷态空气动力场试验研究

通过对330MW四角切圆锅炉燃烧器进行了炉内冷态空气动力场试验的研究，分析了B层燃烧器区域空气速度分布和衰减情况，研究了一次风速，一、二次风动量比和周界风风量等因素对四角切圆燃烧方式的炉内空气动力场的影响规律。试验结果表明，四角的一次风射流衰减特性基本一致，射流刚性良好。在改变二次凤与一次风动量比后，对炉内实际切圆直径影响较小。周界风可以增强一次风射流的刚性，燃烧器上下摆动只改变了炉膛火焰中心的位置，并未改变切圆大小。这为燃烧器安全稳定运行提供技术依据和运行参考。