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排序方式: 共有196条查询结果,搜索用时 187 毫秒
41.
42.
A new environmental chamber for evaluation of gas-phase chemical mechanisms and secondary aerosol formation 总被引:1,自引:0,他引:1
William P.L. Carter David R. Cocker III Dennis R. Fitz Irina L. Malkina Kurt Bumiller Claudia G. Sauer John T. Pisano Charles Bufalino Chen Song 《Atmospheric environment (Oxford, England : 1994)》2005,39(40):7768-7788
A new state-of-the-art indoor environmental chamber facility for the study of atmospheric processes leading to the formation of ozone and secondary organic aerosol (SOA) has been constructed and characterized. The chamber is designed for atmospheric chemical mechanism evaluation at low reactant concentrations under well-controlled environmental conditions. It consists of two collapsible 90 m3 FEP Teflon film reactors on pressure-controlled moveable frameworks inside a temperature-controlled enclosure flushed with purified air. Solar radiation is simulated with either a 200 kW Argon arc lamp or multiple blacklamps. Results of initial characterization experiments, all carried out at 300–305 K under dry conditions, concerning NOx and formaldehyde offgasing, radical sources, particle loss rates, and background PM formation are described. Results of initial single organic–NOx and simplified ambient surrogate–NOx experiments to demonstrate the utility of the facility for mechanism evaluation under low NOx conditions are summarized and compared with the predictions of the SAPRC-99 chemical mechanism. Overall, the results of the initial characterization and evaluation indicate that this new environmental chamber can provide high quality mechanism evaluation data for experiments with NOx levels as low as 2 ppb, though the results indicate some problems with the gas-phase mechanism that need further study. Initial evaluation experiments for SOA formation, also carried out under dry conditions, indicate that the chamber can provide high quality secondary aerosol formation data at relatively low hydrocarbon concentrations. 相似文献
43.
底泥对河流的二次污染浅析 总被引:39,自引:1,他引:39
根据底冲中污染物质累积和释放过程和底泥对河流二次污染的机理,运用适用的模式和苏州河的实测资料,可得到二次污染BOD和COD的年释放量,以及增加上覆河上的BOD和COD浓度。由此认为,对于底泥污染严重的河流,疏浚是必不可少的,其目的在于清除或隔绝黑富集层上覆河上的二次污染。 相似文献
44.
Diego Rubolini Maria Romano Roberta Martinelli Barbara Leoni Nicola Saino 《Behavioral ecology and sociobiology》2006,59(4):549-560
Mothers may profoundly affect offspring phenotype and performance by adjusting egg components, including steroid hormones.
We studied the effects of elevated prenatal testosterone (T) exposure in the ring-necked pheasant on the expression of a suite
of male and female traits, including perinatal response to stress, immune response, growth, and secondary sexual traits. Prenatal
T levels were increased by injecting the yolk of unincubated eggs with physiological doses of the hormone. Yolk T injection
resulted in a reduced length of male tarsal spurs, a trait which positively predicts male success in intra- and intersexual
selection and viability, whereas no direct effect on male wattle characteristics or plumage traits of either sex was observed.
Female spur length was also negatively affected by T, but to a lesser extent than in males. In addition, the covariation between
male secondary sexual traits, which are reliable quality indicators, differed between T and control males, suggesting that
the manipulation may have altered the assessment of overall male quality by other males and females. In conclusion, the negative
effects of elevated yolk T on spur length, a trait which positively predicts male fitness, coupled with the lack of effects
on growth or other traits in both sexes, provided limited evidence for mothers being subjected to a trade-off between positive
and negative consequences of yolk T deposition on offspring traits and suggest that directional selection for reduced yolk
T levels may occur in the ring-necked pheasant. 相似文献
45.
46.
Penghao Su Yuejiao Hao Zhe Qian Weiwei Zhang Jing Chen Fan Zhang Fang Yin Daolun Feng Yingjun Chen Yifan Li 《环境科学学报(英文版)》2020,32(5):262-270
Ship auxiliary engines contribute large amounts of air pollutants when at berth.Biodiesel,including that from waste cooking oil(WCO),can favor a reduction in the emission of primary pollutant when used with internal combustion engines.This study investigated the emissions of gaseous intermediate-volatile organic compounds(IVOCs) between WCO biodiesel and marine gas oil(MGO) to further understand the differences in secondary organic aerosol(SOA) production of exhausts.Results revealed that WCO exhaust exhibited similar IVOC composition and volatility distribution to MGO exhaust,despite the differences between fuel contents.While WCO biodiesel could reduce IVOC emissions by 50% as compared to MGO,and thus reduced the SOA production from IVOCs.The compositions and volatility distributions of exhaust IVOCs varied to those of their fuels,implying that fuel-component-based SOA predicting model should be used with more cautions when assessing SOA production of WCO and MGO exhausts.WCO biodiesel is a cleaner fuel comparing to conventional MGO on ship auxiliary engines with regard to the reductions in gaseous IVOC emissions and corresponding SOA productions.Although the tests were conducted on test bench,the results could be considered as representative due to the widely applications of the test engine and MGO fuel on real-world ships. 相似文献
47.
The catalytic ozonation treatment of secondary biochemical effluent for papermaking wastewater by Ag-doped nickel ferrite was investigated. Ag-doped catalysts prepared by sol-gel method were characterized, illustrating that Ag entirely entered the crystalline of NiFe2O4 and changed the surface properties. The addition of catalyst enhanced the removal efficiency of chemical oxygen demand and total organic carbon. The results of gas chromatography-mass spectrometer, ultraviolet light absorbance at 254 nm and three-dimensional fluorescence excitation-emission matrix suggested that aromatic compounds were efficiently degraded and toxic substances, such as dibutyl phthalate. In addition, the radical scavenging experiments confirmed the hydroxyl radicals acted as the main reactive oxygen species and the surface properties of catalysts played an important role in the reaction. Overall, this work validated potential applications of Ag-doped NiFe2O4 catalyzed ozonation process of biologically recalcitrant wastewater. 相似文献
48.
Secondary organic aerosol (SOA) formation potential for six kinds of short aliphatic ethers has been studied. The size distribution, mass concentration, and yield of SOA formed by ethers photooxidation were determined under different conditions. The results showed that all six ethers can generate SOA via reaction with OH radicals even under no seed and NOx-free condition. The mass concentration for six seedless experiments was less than 10 µg/m3 and the SOA yields were all below 1%. The strong increase in the SOA formation was observed when the system contained ammonium sulfate seed particles, while SOA yield decreased under the high-NOx condition. SOA composition was analyzed using offline methods. Infrared spectra indicated that there are complex components in the particle-phase including carbonyls acid and aldehydes species. Moreover, the aqueous filter extracts were analyzed using ultraviolet-visible spectrometer and fluorescence spectrophotometer. For the fresh methyl n-butyl ether SOA, the largest absorption peak occurs at 280 nm and there exists slightly absorption in the 300–400 nm. Excitation-emission matrices display the distinct peak at excitation/emission = 470 nm/480 nm according to the fluorescence spectrum. These findings are important considerations of formation for ether SOA that can eventually be included in atmospheric models. 相似文献
49.
To perform a systematic survey on the occurrence and removal of micropollutants during municipal wastewater treatment, 943 semi-volatile organic chemicals in 32 wastewater samples including influents of secondary treatments, secondary effluents and final effluents(effluents of advanced treatments), which were collected from seven full-scale municipal wastewater treatment plants(MWTPs) in China, were examined by gas chromatography-mass spectrometry(GC-MS) coupled with an automated identification and quantification system with a database(AIQS-DB). In total, 196 and 145 chemicals were detected in secondary and final effluents, respectively. The majority of the total concentrations(average removal efficiency, 87.0%±5.9%) of the micropollutants were removed during secondary treatments. However, advanced treatments achieved different micropollutant removal extents from secondary effluents depending on the different treatment processes employed. Highly variable removal efficiencies of total concentrations(32.7%–99.3%) were observed among the different advanced processes. Among them,ozonation-based processes could remove 70.0%–80.9% of the total concentrations of studied micropollutants. The potentially harmful micropollutants, based on their detection frequency and concentration in secondary and final effluents, were polycyclic aromatic hydrocarbons(PAHs)(2-methylnaphthalene, fluoranthene, pyrene, naphthalene and phenanthrene), phosphorus flame retardants(tributyl phosphate(TBP), tris(2-chloroethyl)phosphate(TCEP) and tris(1,3-dichloro-2-propyl) phosphate(TDCP)), phthalates(bis(2-ethylhexyl)phthalate(DEHP)), benzothiazoles(benzothiazole,2-(methylthio)-benzothiazol, and 2(3H)-benzothiazolone) and phenol. This study indicated that the presence of considerable amounts of micropollutants in secondary effluent creates the need for suitable advanced treatment before their reuse. 相似文献
50.