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93.
炼油废水反硝化脱氮新工艺研究 总被引:1,自引:0,他引:1
何淦洁 《石油化工环境保护》2003,26(1):23-25
用水解酸化-好氧工艺模拟炼油废水生化处理系统,在二沉池中加入软性纤维填料后,不但使泥水分离效果更好,而且可起到反硝化脱氮的功能,改进了脱氮工艺的传统方式,弥补了由于原工艺中构筑物的原因造成废水无法回流脱氮的缺陷。二沉池中反硝化工艺研究表明,当供给适量C源、DO<1mg/L、温度在25℃-40℃时,NOx-N降解率可达75%-90%。出水COD、oiL等各污染指标均达到国家和DB44/56-92地方排放标准。 相似文献
94.
Charles J. Weschler Helen C. Shields 《Atmospheric environment (Oxford, England : 1994)》2003,37(39-40):5621
Reactions between ozone and terpenes have been shown to increase the concentrations of submicron particles in indoor settings. The present study was designed to examine the influence of air exchange rates on the concentrations of these secondary organic aerosols as well as on the evolution of their particle size distributions. The experiments were performed in a manipulated office setting containing a constant source of d-limonene and an ozone generator that was remotely turned “on” or “off” at 6 h intervals. The particle number concentrations were monitored using an optical particle counter with eight-channels ranging from 0.1–0.2 to>2.0 μm diameter. The air exchange rates during the experiments were either high (working hours) or low (non-working hours) and ranged from 1.6 to>12 h−1, with intermediate exchange rates. Given the emission rates of ozone and d-limonene used in these studies, at an air exchange rate of 1.6 h−1 particle number concentration in the 0.1–0.2 μm size-range peaked 1.2 h after the ozone generator was switched on. In the ensuing 4.8 h particle counts increased in successive size-ranges up to the 0.5–0.7 μm diameter range. At higher air exchange rates, the resulting concentrations of total particles and particle mass (calculated from particle counts) were smaller, and at exchange rates exceeding 12 h−1, no excess particle formation was detectable with the instrument used in this study. Particle size evolved through accretion and, in some cases, coagulation. There was evidence for coagulation among particles in the smallest size-range at low air exchange rates (high particle concentrations) but no evidence of coagulation was apparent at higher air exchange rates (lower particle concentrations). At higher air exchange rates the particle count or size distributions were shifted towards smaller particle diameters and less time was required to achieve the maximum concentration in each of the size-ranges where discernable particle growth occurred. These results illustrate still another way in which ventilation affects human exposures in indoor settings. However, the ultimate effects of these exposures on health and well being remain to be determined. 相似文献
95.
Introduction: Reducing the likelihood of freeway secondary crashes will provide significant safety, operational and environmental benefits. This paper presents a method for assessing the likelihood of freeway secondary crashes with Adaptive Signal Control Systems (ASCS) deployed on alternate routes that are typically used by diverted freeway traffic to avoid any delay or congestion due to a freeway primary crash. Method: The method includes four steps: (1) identification of secondary crashes, (2) verification of alternate routes, (3) assessment of the likelihood of secondary crashes for freeways with ASCS deployed on alternate routes and non-ASCS (i.e. pre-timed, semi- or fully-actuated) alternate routes, and (4) investigation of unobserved heterogeneity of the likelihood of freeway secondary crashes. Four freeway sections (i.e., two with ASCS deployed on alternate routes and two non-ASCS alternate routes) in South Carolina are considered. Results and Conclusions: Findings from the logistic regression modeling reveal significant reduction in the likelihood of secondary crashes for one freeway section (i.e., Charleston I-26 E) with ASCS deployed on alternate route. Other factors such as rear-end crash, dark or limited light, peak period, and annual average daily traffic contribute to the likelihood of freeway secondary crashes. Furthermore, random-parameter logistic regression model results for Charleston I-26 E reveal that unobserved heterogeneity of ASCS effect exists across the observations and ASCS are associated with the reduction of the likelihood of freeway secondary crashes for 84% of the observations (i.e., primary crashes). Location of the primary crash on the freeway is observed to affect the benefit of ASCS toward freeway secondary crash reduction as the primary crash’s location determines how many upstream freeway vehicles will be able to take the alternate route. Practical Applications: Based on the findings, it is recommended that the South Carolina Department of Transportation (SCDOT) considers deploying ASCS on alternate routes parallel to freeway sections where high percentages of secondary crashes are found. 相似文献
96.
Primary and secondary components of PM2.5 in Milan (Italy) 总被引:1,自引:0,他引:1
In sampling campaigns--carried out by means of a high-volume gravimetric sampler--performed between August 2002 and December 2003, 24-h PM2.5 samples have been collected at an urban background site in downtown Milan and analyzed for elemental and organic carbon, ionic species (i.e., chloride, nitrates, sulfates and ammonium) and some elemental species. Chemical speciation data are evaluated also in terms of primary and secondary components of fine particulate matter: in particular, the contribution of secondary organic aerosols (SOA) and of the primary contribution from traffic to observed PM2.5 concentration levels are evaluated by means of the EC tracer method. 相似文献
97.
Chuanqi Li Qianqian Li Dongge Tong Qingliang Wang Mingge Wu Bohua Sun Guijin Su Li Tan 《环境科学学报(英文版)》2020,32(7):1-12
Volatile organic compounds (VOCs) are major contributors to air pollution. Based on the emission characteristics of 99 VOCs that daily measured at 10 am in winter from 15 December 2015 to 17 January 2016 and in summer from 21 July to 25 August 2016 in Beijing, the environmental impact and health risk of VOC were assessed. In the winter polluted days, the secondary organic aerosol formation potential (SOAP) of VOC (199.70 ± 15.05 μg/m3) was significantly higher than that on other days. And aromatics were the primary contributor (98.03%) to the SOAP during the observation period. Additionally, the result of the ozone formation potential (OFP) showed that ethylene contributed the most to OFP in winter (26.00% and 27.64% on the normal and polluted days). In summer, however, acetaldehyde was the primary contributor to OFP (22.00% and 21.61% on the normal and polluted days). Simultaneously, study showed that hazard ratios and lifetime cancer risk values of acrolein, chloroform, benzene, 1,2-dichloroethane, acetaldehyde and 1,3-butadiene exceeded the thresholds established by USEPA, thereby presenting a health risk to the residents. Besides, the ratio of toluene-to-benzene indicated that vehicle exhausts were the main source of VOC pollution in Beijing. The ratio of m-/p-xylene-to-ethylbenzene demonstrated that there were more prominent atmospheric photochemical reactions in summer than that in winter. Finally, according to the potential source contribution function (PSCF) results, compared with local pollution sources, the spread of pollution from long-distance VOCs had a greater impact on Beijing. 相似文献
98.
Jiaxin Wang Xiaohui Ma Yuemeng Ji Yongpeng Ji Yanpeng Gao Yuqi Xiao Guiying Li Taicheng An 《环境科学学报(英文版)》2023,35(4):103-112
Organosulfate (OSA) nanoparticles,as secondary organic aerosol (SOA) compositions,are ubiquitous in urban and rural environments.Hence,we systemically investigated the mechanisms and kinetics of aqueous-phase reactions of 1-butanol/1-decanol (BOL/DOL) and their roles in the formation of OSA nanoparticles by using quantum chemical and kinetic calculations.The mechanism results show that the aqueous-phase reactions of BOL/DOL start from initial protonation at alcoholic OH-groups to form carbenium ... 相似文献
99.
在开封市2005年交通噪声实地监测数据的基础上,运用二级模糊综合评价法,对市区交通噪声环境质量进行现状评价,评价结果为开封市交通噪声环境质量总体上昼间属于轻污染,夜间属于重度污染,夜间交通噪声环境质量明显劣于昼间。其结论符合开封市的实际情况,不仅能较好地描述开封市交通噪声环境污染的连续、渐变、模糊的特点,而且还弥补了一级模糊综合评价难以反映出小范围路段对整体环境质量贡献的不足。 相似文献
100.
基于能量转移理论、多米诺效应理论等相关理论对地铁火灾二次事故概念进行界定,并分析地铁火灾二次事故的演化机理,确定地铁火灾条件下易发的二次事故类型;建立了地铁火灾二次事故安全评价指标体系,通过BP神经网络的安全评价方法对地铁火灾二次事故进行量化分析。 相似文献