全文获取类型
收费全文 | 586篇 |
免费 | 15篇 |
国内免费 | 80篇 |
专业分类
安全科学 | 14篇 |
废物处理 | 7篇 |
环保管理 | 74篇 |
综合类 | 181篇 |
基础理论 | 95篇 |
污染及防治 | 200篇 |
评价与监测 | 78篇 |
社会与环境 | 25篇 |
灾害及防治 | 7篇 |
出版年
2023年 | 3篇 |
2022年 | 14篇 |
2021年 | 3篇 |
2020年 | 10篇 |
2019年 | 9篇 |
2018年 | 9篇 |
2017年 | 16篇 |
2016年 | 25篇 |
2015年 | 13篇 |
2014年 | 19篇 |
2013年 | 65篇 |
2012年 | 34篇 |
2011年 | 78篇 |
2010年 | 35篇 |
2009年 | 57篇 |
2008年 | 56篇 |
2007年 | 36篇 |
2006年 | 31篇 |
2005年 | 14篇 |
2004年 | 19篇 |
2003年 | 19篇 |
2002年 | 18篇 |
2001年 | 17篇 |
2000年 | 14篇 |
1999年 | 7篇 |
1998年 | 16篇 |
1997年 | 13篇 |
1996年 | 2篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 3篇 |
1992年 | 3篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1973年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有681条查询结果,搜索用时 15 毫秒
511.
Guoqing Liu Gan Zhang Zhangdong Jin Jun Li 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):2994-3000
Sediment cores taken from Taihu Lake, East China were analyzed for polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs) and polybrominated biphenyl ethers (PBDEs). The results showed a general sharp increase of HCH, DDT, PAH and PBDE concentrations in the surface layers, corresponding to a sedimentation time of 1980 and 1990 onward in the Meiliang Bay and Xukou Bay, respectively. The source of PAHs has largely transferred from petrogenic to pyrogenic origin, and good relationships were observed between sediment PAH concentrations and the regional gross domestic product. The sharp increase of DDTs in recent years may be related to the mobilization and migration of these chemicals from surface soil to lake sediment, as a result of enhanced soil run-off due to large scale land transform, as well as the contribution of current usage of dicofol and DDT-containing anti-fouling paints. 相似文献
512.
Rico-Rico A Temara A Hermens JL 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):575-581
The study of the effect of the sorption of linear alkylbenzene sulfonates (LAS) on the bioavailability to marine benthic organisms is essential to refine the environmental risk assessment of these compounds. According to the equilibrium partitioning theory (EqP), the effect concentration in water-only exposure will be similar to the effect concentration in the sediment pore water. In this work, sorption and desorption experiments with two marine sediments were carried out using the compound C12-2-LAS. The effect of the sediment sorption on the toxicity of benthic organisms was studied in water-only and in sediment bioassays with the marine mud shrimp Corophium volutator. In addition, three common spiking methods were tested for its application in the toxicity tests, as well as the stability of the surfactant during the water-only and sediment-water test duration. LC50 values obtained from water-only exposure showed a good correspondence with the pore water concentrations calculated from the sorption and desorption isotherms in the spiked sediments. 相似文献
513.
Li Shen Sarah B. Gewurtz Eric J. Reiner Terry M. Kolic Paul A. Helm Debbie A. Burniston Chris H. Marvin 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1210-1218
Concentrations and congener profile patterns of 2378-substituted PCDD/Fs and DLPCBs in offshore, nearshore and tributary sediments of Lakes Superior and Huron are reported, and spatial trends and source contributions assessed. PCDD/F concentrations ranged from 5 to 18 000 pg/g dw (Lake Superior) and 3 to 6100 pg/g dw (Lake Huron); DLPCBs ranged from 9 to 11 000 pg/g dw (Lake Superior) and 9 to 27 000 pg/g dw (Lake Huron). Our analysis indicated atmospheric deposition is a primary source to depositional areas of both lakes; however, greater PCDD/F and DLPCB concentrations were observed at several nearshore and tributary sites, and were attributed to corresponding land use in the watershed. Statistical analysis and pattern comparison suggested that industrial inputs mainly associated with wood treatment plants, pulp and paper mills, mining operations, and chlorine-based chemical manufacturing also contributed to contamination by PCDD/Fs and DLPCBs in certain nearshore and offshore areas of Lakes Superior and Huron. 相似文献
514.
M. Babut C. Miege A. Abarnou P. Marchand 《Environmental pollution (Barking, Essex : 1987)》2009,157(12):3451-3456
Among the numerous PCB congeners, most of the dioxin-like PCBs (DL-PCBs) need to be characterized by hyphenated techniques. It has been shown in several instances that these congeners are well related to the total PCB content in fish. We examined datasets collected mainly in France, on freshwater and marine fish and sediments. A statistical model linking DL- and indicator PCBs was developed for a dataset composed of freshwater fishes, and proved to predict well DL-PCBs from indicator PCBs in all other fish sets, including marine ones. Type II error rates remained low in almost all fish sets. A similar correlation was observed in sediments. Non-dioxin-like PCBs elicit various adverse effects and represent 95% of the total PCBs. A European guideline for them is needed; the correlation between DL- and indicator PCBs could help develop this standard in the future. 相似文献
515.
Sediment Quality Assessment in the Gulf of Gdańsk (Baltic Sea) Using Complementary Lines of Evidence
Roberta Bettinetti Silvana Galassi Jerzy Falandysz Marina Camusso Davide A. L. Vignati 《Environmental management》2009,43(6):1313-1320
Sediments from Polish coastal environments were classified by a quality assessment approach that took into account trace metal
and organic micropollutant concentrations, grain-size distribution, and organic carbon content. Generally, no benthic organisms
were found at sites where sediments were classified as heavily polluted. However, areas characterized by a moderate contamination
showed a variable composition of the benthic community and changing bioaccumulation patterns; therefore, no single species
found in the Gulf of Gdańsk could be considered representative of the whole benthic environment. Although sediment monitoring
must be considered a suitable tool to detect hot-spot pollution areas in coastal and inland waters, it should be complemented
by bioaccumulation measurements to evaluate the actual risk posed by contaminants to benthic organisms. This “biological information”
allows a better appreciation of the real benthic infaunal community exposure to chemicals and can usefully complement the
existing sediment quality guidelines. 相似文献
516.
Sunderland EM Cohen MD Selin NE Chmura GL 《Environmental pollution (Barking, Essex : 1987)》2008,156(2):526-535
Changes in atmospheric mercury deposition are used to evaluate the effectiveness of regulations controlling emissions. This analysis can be complicated by seemingly incongruent data from different model runs, model types, and field measurements. Here we present a case study example that describes how to identify trends in regional scale mercury deposition using best-available information from multiple data sources. To do this, we use data from three atmospheric chemistry models (CMAQ, GEOS-Chem, HYSPLIT) and multiple sediment archives (ombrotrophic bog, headwater lake, coastal salt marsh) from the Bay of Fundy region in Canada. Combined sediment and modeling data indicate that deposition attributable to US and Canadian emissions has declined in recent years, thereby increasing the relative significance of global sources. We estimate that anthropogenic emissions in the US and Canada account for 28-33% of contemporary atmospheric deposition in this region, with the rest from natural (14-32%) and global sources (41-53%). 相似文献
517.
We determined the kinetics of phenanthrene desorption from three activated carbons to water using Tenax beads as an infinite sink for organic compounds in water. Desorption kinetic data very well fitted a biphasic kinetic model based on the presence of two different adsorption sites, viz. low-energy sites and high-energy sites. Rate constants for desorption to water from these two types of sites in the three activated carbons did not reveal a relation with activated carbon grain size. These rate constants were comparable to those for desorption of various organic compounds from hard carbon in various sediments. 相似文献
518.
Polycyclic aromatic hydrocarbons and their hydroxylated metabolites in fish bile and sediments from coastal waters of Colombia 总被引:3,自引:0,他引:3
Johnson-Restrepo B Olivero-Verbel J Lu S Guette-Fernández J Baldiris-Avila R O'Byrne-Hoyos I Aldous KM Addink R Kannan K 《Environmental pollution (Barking, Essex : 1987)》2008,151(3):452-459
Sediments and fish bile collected from the Atlantic coastal waters of Colombia were analyzed for 16 parent polycyclic aromatic hydrocarbons (PAHs), and 23 hydroxylated PAHs (OH-PAHs), respectively. Sediments contained overall mean SigmaPAH concentrations of 2090, 234 and 170 ng/g, dry wt, for Cartagena Bay, Caimanera Marsh, and Totumo Marsh, respectively. The mean concentration of the summed OH-PAHs in fish bile was 1250, 180 and 64.1 ng/g bile wt for Cartagena Bay, Caimanera Marsh, and Totumo Marsh, respectively. The results suggest that Cartagena Bay is heavily polluted by PAHs, and that exposure to high concentrations of PAHs together with other factors could contribute to the decreased health of fish living in this ecosystem. This is one of the first studies to describe the analysis of 23 individual OH-PAHs in fish bile, using authentic standards. 相似文献
519.
Artificially prepared sediments were used to assess the effects of sediment composition on inorganic Hg partitioning, speciation and bioavailability. Organic coating in sediment greatly increased the Hg partitioning and the amount of bioavailable Hg bound with the clay and the Fe and Mn oxides, but had little effect on that bound with the quartz and calcium carbonate as a result of weaker binding of humic acids and fulvic acids. The clay content increased the concentration of Hg in the sediments but inhibited the gut juice extraction due to the strong binding of Hg-organic matter (OM) complexes. Most Hg in the sediments was complexed by OM (mainly distributed in the organo-complexed phase and the strongly complexed phase), and the Hg-OM complexes (especially Hg in the strongly complexed phase) in sediments contributed much to gut juice extraction. Redistribution of Hg-OM complexes between sediments and gut juices may occur during gut juice extraction and modify Hg bioavailability and speciation in sediments. 相似文献
520.
This paper details the distribution of Cu, Pb and Zn in aquatic systems draining Mount Isa Ag-Cu-Pb-Zn Mine in arid northern Queensland, Australia. Sediment-metal concentrations in the <2mm grain-size fraction adjacent to and downstream of the mine significantly exceed background concentrations (Cu, 159; Pb, 36; Zn, 86 ppm) as well as Australian government sediment quality low trigger guidelines (Cu, 65; Pb, 50; Zn, 200 ppm). Overbank sediments are more contaminated than channel sediments with mean values of Cu, 480; Pb, 540; Zn, 750 ppm. Mean concentrations in cut riverbank samples from the <2mm fraction were Cu, 195; Pb, 724; Zn, 807 ppm. Corresponding <180 microm samples returned concentrations of Cu, 321; Pb, 995; Zn, 1110 ppm. Delivery of contaminants during wet seasons from Mount Isa Mine and historically contaminated riverbanks remains an ongoing issue. The ease of dust entrainment in arid zones means that sediments enriched in toxic concentrations of metals may be widely dispersed and ultimately ingested and absorbed by biota. 相似文献