吹扫捕集-气相色谱法测定水中四氢呋喃

建立了吹扫捕集-气相色谱测定水中四氢呋喃的方法,不用有机溶剂萃取和浓缩,减少了损失和对环境的污染,具有灵敏度高、检出限低、定量准确、操作简便等特点。当进样量为5 mL时,检出限可达到0.18μg/L级,相对标准偏差为0.9%-4.0%,加标回收率在77.2%-100.8%之间。     

Contamination of butyltin compounds in Malaysian marine environments

Concentration of butyltin compounds (BTs), including tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT) and total tin (SigmaSn) were determined in green mussel (Perna viridis), 10 species of muscle fish and sediment from coastal waters of Malaysia. BTs were detected in all these samples ranging from 3.6 to 900 ng/g wet wt., 3.6 to 210 ng/g wet wt., and 18 to 1400 ng/g dry wt. for mussels, fish and sediments, respectively. The concentrations of BTs in several locations of this study were comparable with the reported values from some developed countries and highest among Asian developing nations. Considerable concentration of BTs in several locations might have ecotoxicological consequences and may cause concern to human health. The parent compound TBT was found to be highest than those of its degradation compounds, DBT and MBT, suggesting recent input of TBT to the Malaysian marine environment. Significant positive correlation (Spearman rank correlation: r2=0.82, P<0.0001) was found between BTs and SigmaSn, implying considerable anthropogenic input of butyltin compounds to total tin contamination levels. Enormous boating activities may be a major source of BTs in this country, although aquaculture activities may not be ignored.     

Nitrogen dynamics in the sediments of a wetland coastal ecosystem of southern India

The study area, Kuttanad Waters is a part of the Cochin estuarine system on the west coast of India. Kuttanad is well known for its agricultural activity and so the major contribution to the inorganic ions of nitrogen will be from fertilisers applied in agriculture. Based on observed salinity the stations have been divided into three zones. The fresh water zones had higher quantities of silt and clay whereas the estuarine zone was more sandy. The chemical speciation scheme applied here distinguishes three forms of ammoniacal nitrogen species: exchangeable, fixed, and organic ammoniacal nitrogen. No significant trends were observed in the seasonal distribution of total, exchangeable, fixed and organic nitrogen. A significant concentration of exchangeable ammonia was observed in the sediment due to their predominantly reducing environment, which restricts nitrification. High NH₄-N concentrations in the pore waters, along with the sedimentary composition leads to a significantly high quantity of fixed NH₄-N. The low values for N org is due to high mineralisation or deamination of organic nitrogen     

贫困的“物以类聚”：中国的农村空间贫困陷阱及其识别

理解贫困陷阱及其成因是理解减贫机制,进而理解贫困治理的基础。早期的实证研究注重从收入的角度研究农村贫困,较新的研究开始关注“空间外部性”对农村贫困的影响。然而,要正确识别农村的“贫困陷阱”,就需要对上述两个维度同时进行解释。鉴于此,运用中国县级层面的面板数据,从聚集与持久两个维度对中国的农村贫困陷阱进行了识别。研究结果表明：2006—2016年,中国农村的贫困空间格局几乎没有变化,并且贫困的空间分布与经济增长也并非是同步的,贫困县的分布主要与地形（坡度、海拔）因素有关;进一步研究还发现,中国的农村贫困具有持久性,贫困县收入存在低水平的均衡,贫困县与非贫困县之间存在收入的“俱乐部收敛”。本文揭示了空间外部性与农村贫困之间的关系,为正确评估经济发展与扶贫开发,合理制定区域反贫困瞄准机制提供了支持。     

燃用生物柴油对采用CRPT技术的柴油机微粒粒子数浓度和PAHs排放的影响

微粒和PAHs是柴油机排放污染物的重要组成部分,为揭示燃用生物柴油（biodiesel,下称BD）与采用CRPT（连续再生微粒捕集系统,continuous regeneration particulate traps system）技术后对柴油机排放中微粒粒子数浓度和PAHs组分质量的影响规律,利用内燃机综合测试台架对3台排量不同的柴油机进行微粒以及PAHs测试,研究不同微粒粒径对应的粒子数浓度变化规律以及PAHs各组分的质量变化规律.结果表明:①燃用BD对柴油机微粒排放中的聚集态粒子数浓度和总质量影响较大,对核态粒子数浓度影响不大,其中,聚集态粒子总质量降幅最大可达97.04%,粒子数浓度最大降幅从109 m-3降至106 m-3,而核态粒子数浓度变化不大,但粒子数比例有明显的上升,最大升幅为51.50%.②燃用BD对微粒排放中不同粒径粒子数浓度的影响导致CRPT技术条件下微粒质量捕集效率下降,最大降幅达21.10%.③PAHs总质量排放有明显下降,3台柴油机最大降幅分别为92.95%、91.78%和92.70%.但各组分呈现变化不一致现象,类似于二苯并蒽等部分组分质量下降幅度均达到100%,而和苯并蒽的质量均不降反升,其中的质量占燃用BD30后的多环芳香烃质量的50%左右.研究显示,采用"BD+CRPT"技术,柴油机微粒排放控制焦点应集中在核态微粒,PAHs排放的控制还应侧重于考虑和苯并蒽.      

Combined and synergistic effects of climate change and urbanization on water quality in the Wolf Bay watershed, southern Alabama

This study investigated potential changes in flow, total suspended solid(TSS) and nutrient(nitrogen and phosphorous) loadings under future climate change, land use/cover(LULC)change and combined change scenarios in the Wolf Bay watershed, southern Alabama,USA. Four Global Circulation Models(GCMs) under three Special Report Emission Scenarios(SRES) of greenhouse gas were used to assess the future climate change(2016–2040). Three projected LULC maps(2030) were employed to reflect different extents of urbanization in future. The individual, combined and synergistic impacts of LULC and climate change on water quantity/quality were analyzed by the Soil and Water Assessment Tool(SWAT).Under the "climate change only" scenario, monthly distribution and projected variation of TSS are expected to follow a pattern similar to streamflow. Nutrients are influenced both by flow and management practices. The variation of Total Nitrogen(TN) and Total Phosphorous(TP) generally follow the flow trend as well. No evident difference in the N:P ratio was projected. Under the "LULC change only" scenario, TN was projected to decrease,mainly due to the shrinkage of croplands. TP will increase in fall and winter. The N:P ratio shows a strong decreasing potential. Under the "combined change" scenario, LULC and climate change effect were considered simultaneously. Results indicate that if future loadings are expected to increase/decrease under any individual scenario, then the combined change will intensify that trend. Conversely, if their effects are in opposite directions, an offsetting effect occurs. Science-based management practices are needed to reduce nutrient loadings to the Bay.     

The effects of temperature and resource availability on denitrification and relative N2O production in boreal lake sediments

Anthropogenic environmental stressors(like atmospheric deposition,land use change,and climate warming) are predicted to increase inorganic nitrogen and organic carbon loading to northern boreal lakes,with potential consequences for denitrification in lakes.However,our ability to predict effects of these changes is currently limited as northern boreal lakes have been largely neglected in denitrification studies.The aim of this study was therefore to assess how maximum potential denitrification and N_2O production rates,and the relationship between the two(relative N_2O production),is controlled by availability of nitrate(NO_3~-),carbon(C),phosphorus(P),and temperature.Experiments were performed using the acetylene inhibition technique on sediments from a small,nutrient poor boreal lake in northern Sweden in 2014.Maximum potential denitrification and N_2O production rates at 4°C were reached already at NO_3~-additions of 106–120 μg NO_3~-–N/L,and remained unchanged with higher NO_3 amendments.Higher incubation temperatures increased maximum potential denitrification and N_2O production rates,and Q10 was somewhat higher for N_2O production(1.77) than for denitrification(1.69).The relative N_2O production ranged between 13% and 64%,and was not related to NO_3~-concentration,but the ratio increased when incubations were amended with C and P(from a median of 16% to 27%).Combined,our results suggests that unproductive northern boreal lakes currently have low potential for denitrification but are susceptible to small changes in NO_3 loading especially if these are accompanied by enhanced C and P availability,likely promoting higher N_2O production relative to N_2.     

ELECTRONIC DATA PROCESSING SYSTEM FOR STREAMFLOW1

Daily, monthly, and yearly summaries of streamflow and sediment transport are computed from continuous gage height records and discrete measurements of sediment concentration and discharge rate. The system includes computer computation of discharge measurement notes and an accuracy check of gage height and time input data. Maximum volumes of runoff for selected time intervals up to eight days and flow duration data can also be compiled. Electronic data processing equipment including a chart reader, card punch, computers, and card sorter are used. The system software includes 12 Fortran programs.     

土著微生物修复黑臭水体的生物技术研究

在分析底泥污染现状的基础上,综述了近年来国内外底泥的污染现状,介绍了土著微生物修复技术的概念,相关原理及底泥的污染类型与现状;讨论了刺激或抑制土著微生物菌群代谢活性的生物技术途径,利用底泥中土著微生物修复黑臭水体是恢复河涌健康的有效方法之一,今后将有良好的发展前景。     

吹脱捕集气相色谱法分析水中挥发性卤代烃

建立了吹脱捕集气相色谱法测定水中7种挥发性卤代烃的分析方法。对色谱条件、吹脱时间、实验用水等进行了探讨,同时对分析参数如线性相关性、相对标准偏差、最低检出限及加标回收率进行了评价。结果表明,采用吹脱捕集气相色谱法,在1.0μg/L～20.0μg/L范围内,7种卤代烃的质量浓度和峰面积呈良好的线性关系;10.0μg/L的7种挥发性卤代烃标准溶液经重复7次测定,其相对标准偏差为1.30%～8.71%;水样的加标回收率在86.3%～110%之间;最低检出限在0.17μg/L～0.96μg/L之间,该方法已成功地应用于饮用水和地表水中挥发性卤代烃的定性定量测定,结果令人满意。