Determination of chlorothalonil residues in coffee

Coffee beans were treated with the fungicide chlorothalonil (2,4,5,6‐tetrachloro‐1,3‐benzene‐dicarbonitrile) and the residues were determined by high‐performance liquid Chromatograph (HPLC). Several techniques including Soxhlet extraction (SE), microwave‐assisted extraction (MAE) and accelerated solvent extraction (ASE) were compared for the extraction of residues. A column clean‐up procedure was developed to remove the co‐extractives in the extract before HPLC analysis. The overall mean recoveries from extracts obtained by SE, MAE and ASE were 89.2 ±3.9, 88.4 ±1.9 and 82.8 ±0.3, respectively. The results show that MAE followed by HPLC is a viable alternative to the commonly used SE and gas Chromatographic analysis for the determination of chlorothalonil in coffee.     

Environmental and economic viability of Alkali Activated Material (AAM) comprising slag,fly ash and spent coffee ground

ABSTRACT

This paper presents a concept of reusing spent coffee ground (CG) as a construction material. Through creating a CG-filled Alkali Activated Material (AAM) with industrial wastes such as fly ash (FA) and slag (S), a strong recycled material was synthesised and found suitable to be used as a road subgrade fill material. Potential groundwater contamination tests were done in accordance to the Australian Standard Leaching Procedure (ASLP). The environmental analysis done on this green material shows that albeit being composed of various industrial wastes and chemicals, CG-filled AAMs in the ground will not cause adverse environmental impacts to surrounding soils and groundwater. Heavy metals and cyanide leached from the AAMs were well below hazardous thresholds. Comparing the carbon footprint of CG, it is found that recycling CG into a construction material would reduce the nett global carbon emission by reducing dependency on quarried material. Cost analyses done on CG-filled AAMs show that these AAMs are expensive to produce relative to traditional construction materials. However, as recycling technology is progressively advancing, in the future the economic value of CG-filled AAM may increase to match those of contemporary construction materials.     

Chemical oxygen demand reduction in coffee wastewater through chemical flocculation and advanced oxidation processes

The removal of the natural organic matter present in coffee processing wastewater through chemical coagulation-flocculation and advanced oxidation processes （AOP） had been studied. The effectiveness of the removal of natural organic matter using commercial flocculants and UV/H202, UV/O3 and UV/H2O2/O3 processes was determined under acidic conditions. For each of these processes, different operational conditions were explored to optimize the treatment efficiency of the coffee wastewater. Coffee wastewater is characterized by a high chemical oxygen demand （COD） and low total suspended solids. The outcomes of coffee wastewater treatment using coagulation-flocculation and photodegradation processes were assessed in terms of reduction of COD, color, and turbidity. It was found that a reduction in COD of 67% could be realized when the coffee wastewater was treated by chemical coagulation-flocculation with lime and coagulant T-1. When coffee wastewater was treated by coagulation-flocculation in combination with UV/H2O2, a COD reduction of 86% was achieved, although only after prolonged UV irradiation. Of the three advanced oxidation processes considered, UV/H2O2, UV/O3 and UV/H2O2/O3, we found that the treatment with UV/H2O2/O3 was the most effective, with an efficiency of color, turbidity and further COD removal of 87%, when applied to the flocculated coffee wastewater.