Rapid detection of multiple class pharmaceuticals in both municipal wastewater and sludge with ultra high performance liquid chromatography tandem mass spectrometry

This work described the development, optimization and validation of an analytical method for rapid detection of multiple-class pharmaceuticals in both municipal wastewater and sludge samples based on ultrasonic solvent extraction, solid-phase extraction, and ultra high performance liquid chromatography-tandem mass spectrometry quantification. The results indicated that the developed method could effectively extract all the target pharmaceuticals （25） in a single process and analyze them within 24 min. The recoveries of the target pharmaceuticals were in the range of 69%-131% for wastewater and 54%-130% for sludge at different spiked concentration levels. The method quantification limits in wastewater and sludge ranged from 0.02 to 0.73 ng/L and from 0.02 to 1.00μg/kg, respectively. Subsequently, this method was validated and applied for residual pharma- ceutical analysis in a wastewater treatment plant located in Beijing, China. All the target pharmaceuticals were detected in the influent samples with concentrations varying from 0.09 ng/L （tiamulin） to 15.24 μg/L （caffeine）; meanwhile, up to 23 pharmaceuticals were detected in sludge samples with concentrations varying from 60 ng/kg （sulfamethizole） to 8.55 mg/kg （ofloxacin）. The developed method demonstrated its selectivity, sensitivity, and reliability for detecting multiple-class pharmaceuticals in complex matrices such as municipal wastewater and sludge.     

城镇生活污水的低温厌氧生物处理技术研究与应用进展

归纳了厌氧过程处理低温生活污水的运行机制和影响因素总结了污水中典型污染物的去除特征评述了国内外厌氧反应器对低温生活污水的处理效能以及如何通过改进反应器自身结构及运行参数来应对低温、低浓度对厌氧反应器运行的不利影响最后介绍了厌氧反应器在资源化利用和能源回收方面的应用以及实际工程案例,并指出了存在的问题与今后研究的方向。     

溧阳市1985~2011年环境空气质量变化规律的模糊综合评价

选用模糊综合评价法,对溧阳市1985~2011年环境空气质量进行了综合评价,选用SO2、NO2、TSP/PM10作为评价因素,通过计算各评价因素权重分配系数和隶属度,分析了长期空气环境质量变化趋势。结果表明:TSP/PM 10为1985年以来溧阳市首要环境空气质量制约因素,20世纪80年代中期全市空气质量主要隶属于一级标准,20世纪80年代后期主要隶属于二级标准,20世纪90年代初期主要隶属于三级标准,20世纪90年代中后期至今主要隶属于二级标准,近几年受TSP/PM1 0因素影响,在三级标准的隶属度有上升趋势;自20世纪90年代中期始,NO 2超越SO2成为继PM 10之后制约空气质量的第2大因素;经济发展对环境空气质量的规模效应较为显著,技术减排效应逐步显现。     

乌海市炭素企业沥青烟气的监测分析与治理研究

本文通过对乌海市三家炭素企业排放烟气的监测（重点监测、苯并[a]芘）并进行数据分析。结合炭素生产工艺流程进行研究。提出了对沥青烟气治理所采取的相应措施。为做好乌海市炭素企业沥青烟气监测及改善沥青烟气污染状况提供了一定的参考依据。     

化学镀镍废水中磷处理的研究

化学镀镍技术,以其独特的优越性正被广泛应用。但是化学镀镍溶液因其自身的还原反应性质导致镀液不稳定、使用寿命短。产生的废液中含有大量的镍离子、亚磷酸盐、硫酸钠及一些有机物等。镍是一种致癌的重金属物质,也是一种短缺昂贵的金属资源,磷则是引起水体富营养化现象的主要污染因素之一。因此,如何有效地处理化学镀镍废液中的磷,减少对环境的污染及生态平衡的破坏,有着非常重要的现实意义。本文通过大量的试验对影响磷处理效果的氯化钙投加量、反应温度、反应时间、反应pH值等因素进行了优化。在试验的基础上,可根据实际操作所得出的温度与pH值对镀镍废水磷处理的影响的结论,设计出一套化学镀镍废液综合治理的工艺流程。因此,具有非常重要的现实意义。     

北京市水资源领域适应气候变化对策及保障措施探讨

气候变化问题日益凸显。应对和适应气候变化刻不容缓。然而,短期内无法有效减缓气候变化产生的不利影响。因此,有必要针对不同领域制定相应的适应措施来提高人们对气候变化的适应能力。北京作为人口众多的大城市及我国的缺水城市之一,气候变化无疑将加剧水资源的供需矛盾。本文针对北京市水资源现状及气候变化对北京市水资源领域已经形成的影响,从自然、工程、政策制度三个角度探讨了北京市水资源领域适应气候变化可采取的对策及保障措施。     

我国赤泥环境管理现状分析

针对中国氧化铝行业日益严重的赤泥排放及堆存污染防治问题,本文简要介绍了国内赤泥产生、综合利用和堆存的环境管理现状,总结分析了目前赤泥环境管理存在的主要问题,进而提出了相应的对策建议。     

水体中阿特拉津去除技术研究进展

在阐述了阿特拉津的污染现状和危害基础上,探讨了国内外常规生物处理技术及深度处理:膜处理、高级氧化、催化还原、吸附等技术对阿特拉津的去除研究进展,并总结对比了各种处理技术的优缺点。     

LED 外延片芯片制造业工业废水的治理分析

本文介绍了LED外延片芯片制造业工业废水的治理方法,同时,也对废水处理后的回用方法进行了分析。     

Novel cationic polyamidine: Synthesis, characterization, and sludge dewatering performance

In this study, a new and facile route was employed for synthesis of polyamidine with abundant cations and attractive five-membered ringlike structural unit. N-vinylformamide and acrylonitrile copolymerized firstly to form intermediates, and the intermediates were processed with hydrochloric acid to produce polyamidine. A series of polymerization conditions (e.g. polymerization time, temperature and dosage of initiator) were optimized through productivity, viscosity and cationic degree as evaluation. SEM analysis illustrated that the amidinization process could reduce the size of spaces between molecular and created compact structure, which would contribute to good flocculation performance and high viscosity. FT-IR, XPS and NMR spectra presented a rather clear structure of polyamidine. 34.3% of sludge was sedimentated through the flocculation of polyamidine in the early stages. In contrast, only 6.8% of sludge was sedimentated by polyacrylamide. The moisture content in dehydrated floc could be reduced to 77.7% when 60 mg/L polyamidine was added. These results demonstrated that the polyamidine showed a great potential in the practical application of sludge dewatering.