TBT and TPhT persistence in a sludged soil

The persistence of tributyltin (TBT) and triphenyltin (TPhT) in soils was studied, taking into consideration the quantity of sewage sludge, TBT and TPhT concentrations in soil as well as the soil pH. The organotin compounds (OTC) were introduced into the soil via a spiked urban sludge, simulating agricultural practise. OTC speciation was achieved after acidic extraction of soil samples followed by gas chromatography–pulsed flame photometric analysis (GC–PFPD). Leaching tests conducted on a spiked sludge showed that more than 98% of TBT are sorbed on the sludge. TBT persistence in soil appeared to depend on its initial concentration in sludge. Thus, it was more important when concentration is over 1000 μg(Sn) kg⁻¹ of sludge. More than 50% of the initial TBT added into the soil were still present after 2 months, whatever the experimental conditions. The main degradation product appeared to be dibutyltin. About 90% of TPhT were initially sorbed on sludge, whatever the spiking concentration in sludge was. However, TPhT seemed to be quantitatively exchangeable at the solid/liquid interface, according to the leaching tests. It was also significantly degraded in sludged soil as only about 20% of TPhT remain present after 2 months, the monophenyltin being the main degradation product. pH had a significant positive effect on TBT and particularly TPhT persistence, according to the initial amounts introduced into the soil. Thus, at pH over 7 and triorganotin concentration over 100 μg(Sn) kg⁻¹, less than 10% of TBT but about 60% of TPhT were degraded. When the sludge was moderately contaminated by triorganotins (typically 50 μg(Sn) kg⁻¹ in our conditions) the pH had no effect on TBT and TPhT persistence.     

絮凝剂在河湖污泥脱水中的应用研究

河湖水质在一定程度上受河湖底泥的影响,要彻底改善水质就要对沉积的污泥进行处理。研究发现,有机高分子絮凝剂的种类及投加比例对河湖污泥脱水效果有着很大的影响。通过对特定湖泊污泥中投加不同型号、不同比例、不同用量的絮凝剂,比较其脱水效果,可以筛选出针对该种污泥的最佳絮凝剂投加使用方式,从而为污泥的大规模脱水减量化、资源化处置工程提供依据,并可大幅提高河湖污泥处置的经济效益,最终为河湖水质的改善提供了基础条件。     

灾害信息的采集及其成果积累

首先叙述信息、灾害信息及其相互关系,提出关于灾害信息的个人观点．在此基础上,按照作者长期灾害信息的研究实践,用大量事例阐明灾害信息的采集、及成果积累的有关技术问题,最后归纳出几点认识。     

UASB处理酒精废液颗粒污泥形成过程与运行效果的研究

本试验采中中温ＵＡＳＢ反应器处理酒精废液，通过启动、运行、颗粒污泥不同时期形成过程的探索，成功地培养出了颗粒污泥，取得了有机负荷高达１３－２２ｇＣＯＤ／ｌ．ｄ，ＨＲＴ１５．６－２２．３ｈｒ，ＣＯＤｃｒ去除率达８３．９－９２．２％，沼气产气率５．１－８．７１／ｌ．ｄ，ＣＨ４含量５５－７２％的良好效果。     

PESTICIDE ACCUMULATION IN A NEW IMPOUNDMENT IN IOWA1

ABSTRACT: Estimates were made of the amounts of selected pesticides entering and leaving Saylorville Reservoir, a new partly filled impoundment on the Des Moines River. Samples were collected at 1– or 2-week intervals at stations above, in, and below the reservoir. Atrazine, alachlor, and cyanazine were found only in the dissolved state, and dieldrin and p, p′ -DDE in both the, dissolved and suspended state. Heptachlor epoxide, p,p-DDT. p, p′ -DDD, 2,4-D, 2,4,5-TP, endrin, lindane, methoxychlor, propachlor, and toxaphene were not detected or were at very low concentrations. Estimated deposition in the reservoir from September 1977 to October 1978 was 281 kg atrazine, 251 kg alachlor, 26 kg cyanazine, 16 kg dieldrin, and 20 kg p, p′ -DDE.     

USE OF TIME-LAPSE PHOTOGRAPHY TO ASSESS POTENTIAL INTERCEPTION IN ARIZONA PONDEROSA PINE1

ABSTRACT: The behavior of intercepted snow on a stand of uneven-aged ponderosa pine in east-central Arizona was evaluated with the use of a super 8-mm time lapse movie camera to determine the relative significance of snowfall interception in the water yield of this type forest. A snow load index was developed to estimate interception storage for two trees in the field of view for discrete time periods. The snow load index. photographs, and climatic data were combined to describe accumulation and to identify and rank according to relative magnitudes the basic processes of canopy snow removal. The rate of snow accumulation was nonlinear with initial storage being rapid. then slowing with time. Most of the intercepted snow eventually reached the snowpack on the ground by snowslide and wind erosion or by snowmelt and subsequent stemflow and drippmg of meltwater, and was therefore not considered a significant loss to the water budget on site. Some water apparently was disposed of by the evaporation of meltwater and sublimation of canopy snow, but these losses appeared to be comparatively minor.     

GIS在巨灾保险风险管理中的应用研究

近年来 ,巨灾的不断发生 ,使得许多保险和再保险公司遭受巨大赔偿 ,乃至可能造成破产。究其原因 ,除了人们对巨灾自身难以抗拒这一客观原因外 ,保险企业对巨灾保险的风险管理方法、技术和手段的不适也是一个很重要的因素。为此 ,笔者分析了利用GIS辅助巨灾保险风险管理的优越性 ,并就GIS在巨灾保险的信息管理、风险累积预测和风险管理专家系统中所起的作用和发挥的功能分别进行了探讨。利用GIS辅助巨灾保险风险管理 ,不仅可以了解巨灾的发生和变化规律 ,进行危险性区域和费率区域的划分 ,而且可以优化保险和再保险方案 ,并通过专家系统设计出符合实用灾情的风险管理及保险管理的对策 ,对保险公司的巨灾保险风险管理起到了重要的指导作用。     

Ecotoxicological implications of aquatic disposal of coal combustion residues in the United States: a review

We provide an overview of research related to environmental effects of disposal of coal combustion residues (CCR) in sites in the United States. Our focus is on aspects of CCR that have the potential to negatively influence aquatic organisms and thehealth of aquatic ecosystems. We identify major issues of concern, as well as areas in need of further investigation.Intentional or accidental release of CCR into aquatic systemshas generally been associated with deleterious environmental effects. A large number of metals and trace elements are presentin CCR, some of which are rapidly accumulated to high concentrations by aquatic organisms. Moreover, a variety of biological responses have been observed in organisms following exposure to and accumulation of CCR-related contaminants. In some vertebrates and invertebrates, CCR exposure has led to numerous histopathological, behavioral, and physiological (reproductive, energetic, and endocrinological) effects. Fish kills and extirpation of some fish species have been associatedwith CCR release, as have indirect effects on survival and growth of aquatic animals mediated by changes in resource abundance or quality. Recovery of CCR-impacted sites can be extremely slow due to continued cycling of contaminants withinthe system, even in sites that only received CCR effluents forshort periods of time. The literature synthesis reveals important considerations for future investigations of CCR-impacted sites. Many studies have examined biological responses to CCR with respect to Se concentrations and accumulation because of teratogenic andreproductively toxic effects known to be associated with thiselement. However, the complex mixture of metals and traceelements characteristic of CCR suggests that biologicalassessments of many CCR-contaminated habitats should examine avariety of inorganic compounds in sediments, water, and tissuesbefore causation can be linked to individual CCR components. Most evaluations of effects of CCR in aquatic environments havefocused on lentic systems and the populations of animalsoccupying them. Much less is known about CCR effects in loticsystems, in which the contaminants may be transported downstream,diluted or concentrated in downstream areas, and accumulated bymore transient species. Although some research has examinedaccumulation and effects of contaminants on terrestrial and avianspecies that visit CCR-impacted aquatic sites, more extensiveresearch is also needed in this area. Effects in terrestrial orsemiaquatic species range from accumulation and maternal transferof elements to complete recruitment failure, suggesting that CCReffects need to be examined both within and outside of theaquatic habitats into which CCR is released. Requiring specialattention are waterfowl and amphibians that use CCR-contaminatedsites during specific seasons or life stages and are highlydependent on aquatic habitat quality during those periods.Whether accidentally discharged into natural aquatic systems or present in impoundments that attract wildlife, CCR appears topresent significant risks to aquatic and semiaquatic organisms. Effects may be as subtle as changes in physiology or as drasticas extirpation of entire populations. When examined as a whole,research on responses of aquatic organisms to CCR suggests thatreducing the use of disposal methods that include an aquaticslurry phase may alleviate some environmental risks associatedwith the waste products.     

The accumulation and effects of environmental contaminants on snakes: a review

In any ecological risk assessment, afull complement of the relevant members of theecosystems being studied should be considered. Reptiles in general, and snakes in particular, areimportant although often neglected components ofterrestrial and aquatic ecosystems and should beincluded in any study on environmental contamination. By neglecting reptiles, the risks posed by aparticular contaminant cannot be fully assessed. Since all snakes are secondary, tertiary, and toppredators, they are susceptible to the bioaccumulationof environmental contaminants. Their unique lifehistories make their roles in food webs diverse andimportant, and they are crucial to the properfunctioning of many ecological processes. We reviewand summarize organic and inorganic contaminant andradionuclide/radiation residue and lethal andsublethal effects data for snakes to stress theimportance of snakes and encourage their inclusion inecological risk assessments, to demonstrate thepaucity of available contaminant data on snakes andreveal the main information gaps, to encourage furtherecotoxicological studies on snakes, and to facilitatethe use of existing snake contaminant data inecological risk assessments. This review is the mostcomprehensive review currently available on theeffects on and accumulation of environmentalcontaminants in snakes.     

Metal concentrations in deciduous tree leaves from urban areas in Poland

Accumulation of metals in deciduous tree foliage fromurban areas in western-south Poland was monitored duringthe vegetation season of 2000 year. Concentrations of Al,Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, Ti and Znwere measured in birch, willow, linden and maple leavesusing the ICP-AES method. Seasonal variations of metalconcentrations and their relations with sampling sitewere investigated. The most dynamic accumulation of Al,Cd, Cr, Ni and Pb was observed for examined species. Thehighest differences in element concentrations forinvestigated sites were found for Ba, Cd, Mn and Ni.Interelement correlations were investigated. In allfoliar samples synergistic relationships between Al–Crand Ca-Sr were found. Statistically significant negativecorrelations were observed only for Cd and Ti in birch leaves.