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491.
492.
悬浮液进样石墨炉原子吸收法直接测定土壤、底泥中的铅、镓、钴、镍 总被引:1,自引:0,他引:1
介绍一种悬浮液进样直接测定土壤、底泥中多种微量金属元素的快速分析方法。基体改进剂的使用,适宜的原子化温度的选择,使用水相标准溶液作校准曲线成为可能.对标准作品的测定证明了此方法的精密度和准确度较好,适合于常规环境样品分析. 相似文献
493.
K. Nakamiya T. Furuichi K. Ishii 《Journal of Material Cycles and Waste Management》2003,5(1):0063-0068
The optimal soil-washing conditions for dioxins were estimated on a soil sample from the circumference of an incinerator
in Nose City, Osaka, Japan. The solvents ethanol, methanol, and acetone, together with a surfactant (100% of each) could extract
40% of the dioxins from contaminated soil at room temperature. From among these solvents, ethanol was chosen for a study on
how to optimize the extraction conditions because of its low toxicity and its economic advantages. The time-course of the
agitation showed that the extraction rate increased for 1 min, and thereafter the rate decreased. Therefore, the agitation
time was fixed at 1 min. To estimate the effect of temperature on the extraction rate, the extraction temperature was changed.
The amount of dioxins extracted was largest at the boiling point of ethanol (78.3°C), giving about 76% extraction. Furthermore,
at this temperature, almost 100% of the dioxins in the contaminated soil were extracted when the ratio of water to ethanol
was 20%.
Received: March 6, 2002 / Accepted: September 9, 2002 相似文献
494.
达县百节"水保生态园区"水土流失治理与生态环境保护 总被引:2,自引:1,他引:1
本文反映了严重的水土流失是导致达县百节河小流域生态环境恶化的主要原因。阐述了通过实施水土流失治理三大措施:工程措施、生物措施、农耕措施,有效地控制了水土流失等生态问题,极大地改善了当地生态环境,取得了显著的三大效益:经济效益、生态效益和社会效益。同时陈述了百节河小流域生态园区的建设特色:组织协调部门资金捆绑使用,集中投入:业主参与,责、权、利统一,投资渠道多元化,为水土保持和生态环境建设注入了生机与活力。 相似文献
495.
微波辐射在二氧化锰诱导下对六氯苯污染土壤的修复研究 总被引:4,自引:0,他引:4
以二氧化锰为微波吸附剂,在密封体系中研究了微波辐射技术对六氯苯污染土壤的修复效果。分别以不同浓度的酸碱水溶液添加到土壤中,在模拟含水率为20%情况下,硫酸(50%)介质下六氯苯处理效果最好,10min的微波辐射即可使50mg/kg的六氯苯达到完全去除;但是在纯水和10mol/L氢氧化钠介质下,六氯苯基本上没有去除;随着硫酸浓度的降低,六氯苯的去除率显著降低。气相色谱/质谱联用(GC/MS)分析没有检测到新物质。六氯苯去除机理推测为,直接矿化或者HCB及其分解的中间产物同土壤发生化学结合而被固定起来,以致难以萃取出来。 相似文献
496.
497.
498.
Agnew LJ Lyon S Gérard-Marchant P Collins VB Lembo AJ Steenhuis TS Walter MT 《Journal of environmental management》2006,78(1):63-76
Researchers have noted that current water quality protection strategies, like nutrient management plans, lack a sound hydrological underpinning for pollutant transport processes. This is especially true for areas like the northeastern U.S. where copious research has shown that variable source area hydrology largely governs runoff generation. The goal of this study was to develop a scientifically justified method to identify the locations that generate overland flow. Furthermore, this methodology must be computationally simple enough that it can be utilized or incorporated into nutrient management plans and other established water quality tools. We specifically tested the reliability of the 'distance from a stream,'D(s), and the 'topographic index,'lambda, to predict areas with a high propensity for generating overland flow, i.e. hydrologically sensitive areas (HSA). HSAs were defined by their probability of generating runoff, P(sat), based on 30 year simulations using a physically based hydrological model. Using GIS, each location's P(sat) was correlated with D(s) and lambda. We used three Delaware Co., NY watersheds in the New York City watershed system with areas varying in size from 1.6 to 37 km2 and with forested and agricultural land uses. The topographic index gave stronger, more regionally consistent correlations with P(sat) than did D(s). Equations correlating lambda and P(sat) for each month are presented and can be used to estimate hydrological sensitivity in the region surrounding our study watersheds, i.e. in Delaware Co. This work is currently being incorporated into an Internet Mapping System to facilitate user-friendly, on-line identification of HSAs. 相似文献
499.
In the investigation of soil cover design options for final decommissioning of reactive mine waste, it is often necessary to analyze or predict the anticipated cover performance as a function of the cost of implementation, which is governed by the type, number and thickness of the layers in the cover system. An example of such investigation is presented in this study where one-dimensional evaporation from hypothetical moisture-retaining cover systems is simulated to assess the influence of several cover properties and hydrogeologic parameters on performance. The commercially available transient flow model, SoilCover, was used to compute suction and water content profiles for different cover design scenarios. The predicted water content profile and porosity of layers were then used to estimate the oxygen diffusion coefficients of the various layers. The oxygen diffusion coefficients were used to estimate oxygen flux through the cover systems. The oxygen flux was, in turn, related to the maximum acid flux. The studied cover and hydrogeologic parameters included soil type, thickness of barriers, and water table elevation. Two types of infiltration and oxygen barrier and two types of capillary layer with different thicknesses were studied. The water table was either kept constant at the base of the waste (tailings) or dropped by 0.5, 1, 2, and 3m over 120 days. The results showed that the relationship between water table depression and the thickness of capillary layers, on one hand, and desaturation of the infiltration and oxygen barrier, on the other, is not linear. Relationships between oxygen flux and barrier thickness and between cost increase and performance improvement of the studied cover systems are presented. Finally, a method that outlines steps for site-specific and economically feasible design of multi-layer cover systems is introduced. 相似文献
500.
Socioeconomic Factors Affecting Farmers’ Perceptions of Land Degradation and Stonewall Terraces in Central Palestine 总被引:1,自引:0,他引:1
Land degradation by soil erosion is a socioeconomic and environmental problem facing many developing countries. Application
of stonewall terraces for soil moisture conservation is vital to reducing the environmental impacts of this phenomenon. To
this end, a field plot experiment was conducted in the study area along with the use of a closed-ended questionnaire. The
object of the experiment was to study the socioeconomic impacts of soil erosion on local farmers and their adoption of the
stonewall terrace technique. The study showed a higher net profit in areas that had implemented terrace conservation practices
than in areas that had not (i.e., 3.5 to 6 times higher net profit). Correlation analysis indicated that the farmers’ perceptions,
land ownership, and geomorphology were significantly related to the farmers’ incentives and willingness to adopt terraces
as soil conservation measures (P < 0.05), although the correlations were negative. Smallholder farmers (52% of the interviewed farmers) were involved in the
sale of the agricultural land for urban uses, largely because of the high price and immediate returns offered. However, the
associated land use changes warrant greater involvement of both the private and public sectors. This cooperation may be accomplished
through the introduction of a long-term agricultural loan system and the development of proper legislation accompanied by
a comprehensive and durable infrastructure and service system with the goal of reducing the negative impact of land use changes
and encouraging sustainable use of resources. 相似文献