Temporal and spatial distribution of Cs in Eastern Mediterranean Sea. Horizontal and vertical dispersion in two regions

Caesium-137 activity concentration in the water columns of the Gulf of Patras (Central Greece) and the North-Eastern Aegean Sea (easterward to Lemnos Island) was investigated in selected sampling stations during the period September 2004–June 2006. The methodology followed was based on the sorption of caesium (Cs) on cotton wound cartridge filters impregnated by Cu₂[Fe(CN)₆] via in-situ pumping. In terms of the horizontal and vertical records, the activity concentrations of ¹³⁷Cs in the Gulf of Patras ranged between 1.2 and 6.7 Bq m⁻³, depending on the sampling period and the prevailing physicochemical regime at the sampling station. The general pattern of the decreased activity concentrations of ¹³⁷Cs with increasing depth was reversed in the Gulf of Patras during the cold period attributed to the prevailing advective processes of the area. The activity concentrations of ¹³⁷Cs in the North-Eastern Aegean Sea ranged from 2.6 to 12.8 Bq m⁻³, whereas significant stratified curves were observed during the warm period and also, in one station during the cold period. In terms of temporal variation, the discharges in the Gulf of Patras resulted in enhanced levels of ¹³⁷Cs, whereas in the North Aegean Sea the incoming water masses form the Black Sea had an apparent influence throughout the year by increasing the ¹³⁷Cs levels, hence presenting a weak seasonal variation. Comparing the two studied areas, one could say that the North Aegean Sea, as an open sea environment, presented higher concentrations due to the influence of the Black Sea water masses. The estimated inventories of ¹³⁷Cs in the Gulf of Patras ranged 0.25 ± 0.03–0.79 ± 0.03 kBq m⁻², whereas in the North-Eastern Aegean Sea they ranged 0.33 ± 0.02–0.92 ± 0.03 kBq m⁻².     

重庆近48年来高温天气气候特征及其环流形势

利用重庆23个气象观测站1960~2007年逐日最高气温观测资料,NCEP/NCAR再分析数据集中的高度场格点资料,运用EOF、REOF等方法,探讨重庆高温日数的空间分布特征,并对多高温天气的2006年和少高温天气年7~8月的环流特征进行了分析。结果表明：重庆高温天气主要出现在7~8月份,高温日数具有显著的年代际和区域性差异,20世纪70年代最多,80年代最少,沿长江、乌江为高温多发带。一致性异常分布是重庆高温日数的最主要空间模态;高温日数的异常空间分布可分为以下3个关键区：重庆中西部、重庆东南部、重庆东北部。乌拉尔山至鄂霍次克海地区阻塞高压偏弱,东亚大槽偏浅;100 hPa 高空南亚高压偏东,500 hPa 高空副高偏北偏西,形成一种上高下高的叠加形势是重庆7~8月出现多高温天气的主要原因。     

Distribution of polybrominated diphenyl ethers in breast milk from North China: Implication of exposure pathways

The breast milk concentrations of polybrominated diphenyl ethers (PBDEs; sum of eight congeners: BDE-28, 47, 99, 100, 153, 154, 183 and 209) were determined (by high resolution gas chromatographic high resolution mass spectrometry) in samples from primiparous women collected in 2006 in Tianjin, China. Dietary and lifestyle habits of the participants were obtained by questionnaires. The median total PBDE concentration (including BDE-28, 47, 99, 100, 153, 154, 183) was 2500 pg g⁻¹ lipid weight, ranging from 1700 to 4500 pg g⁻¹ lipid weight. These levels were in the same range as those from Europe and Japan but much lower than those from North America. The congener profile in China was also different from other countries. The contribution of BDE-28 was around 15%, much higher than any other country, implying that a different Penta-BDE formulation might be used in the Chinese market. The lower ratio of the sum of BDE-47, 99, and 100 to the sum of BDE-153 and 154 suggested that Octa-products were in more demand in China. A significant correlation was found between a woman’s PBDE concentration and the time she used electronic appliances (h/d). This implies that electronics are a potential source of PBDEs to people. Inhalation or ingestion of particulate matter (such as dust) may also be an important exposure pathway. There was no significant correlation between the PBDE concentration and the consumption of meat, fish, and milk. Further research is needed to determine the specific contribution of each exposure route and their health effects.     

Investigation of PCDD/Fs and dl-PCBs in fish from the southern Baltic Sea during the 2002–2006 period

Concentrations of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (dl-PCBs) in the southern Baltic herring (Clupea harengus), sprat (Sprattus sprattus), and salmon (Salmo salar) are reported.The significant interspecies and season-specific differences in PCDD/Fs and dl-PCBs concentrations were observed. The contribution of dl-PCBs to the total toxicity equivalents (TEQs) ranged between 50% and 70%, dependently on fish species. In all samples, concentrations of PCDF were higher in comparison with that of PCDD.The permissible limits of the content of PCDD/Fs and dl-PCBs (8 pg g⁻¹ fresh weight for the sum of PCDD/Fs and dl-PCBs, and 4 pg g⁻¹ fresh weight for the PCDD/Fs) were exceeded mainly in salmon samples (in 80% of salmon samples studied). The elevated levels of PCDD/F and dl-PCB were observed only in two of seventy two herring samples, and in ten of 62 sprat samples.The multiple regression analysis revealed that fish lipid content, and concentration of PCB 153, used simultaneously, might be useful in the prediction of TEQ values of fish samples. These two variables explained more than 80% of total variance. For all fish species studied, the correlation coefficients obtained with the multiple regression analysis were higher than that obtained with the regression analysis involving total TEQ values, and only one independent variable: fish lipid content.     

Small-scale mining in China: Assessing recent advances in the policy and regulatory framework

This paper explores the background of a proposed revision to the Mineral Resources Law of China, why and how the law was amended in the past, its salient features and objectives. Of equal importance is an analysis of how this national law, with its attendant regulations and policies, formed the basis for the growth and continued development of China's small-scale mining industry. The Xiaoqingling Gold Mountain case study is shown to justify the necessity and feasibility for formalizing and consolidating small-scale mines in China, and to some extent, the success of the nation-wide ASM resource consolidation policy at a local level.     

中国雨日变化趋势的分形研究

利用1951-2002年中国752个台站的雨日资料,运用分形理论和R/S分析法,研究并预测了中国五大降水区年雨日的气候变化趋势.研究表明:中国五大降水区未来的年雨日变化趋势与过去50a的变化有着很好的自相似性.为了更深入研究雨日的未来的变化,设计了两项Hurst指数试验,用两项试验结果与年雨日年际变化趋势的对应关系来推断未来的变化趋势及其转折与突变.结果表明:中国五大降水区年雨日有着一致的减少趋势,但其变化呈现显著的地域分异特征.依照五大降水区的气候倾向率,西北区、西南区、青藏高原区、东部北方区、东部南方区未来平均每10a雨日减少分别为4.1d,11.4d,3.7d,6.8d和5.9d,其中西南区年雨日减少最多.期间,中国五大降水区虽有气候变化的转折,但不存在雨日气候变化的突变点.     

Influence of macroalgal diversity on accumulation of radionuclides and heavy metals in Bulgarian Black Sea ecosystems

Radionuclides and heavy metals were studied in green, brown and red Black Sea macroalgae by low-level gamma spectrometry and atomic absorption spectrometry. The samples were collected along the whole Bulgarian coast from 1996 to 2004. The levels have been depending on algae species, locations and year of sampling. The highest ¹³⁷Cs levels were found in red Ceramium rubrum species from all studied locations, while ²²⁶Ra and ²¹⁰Pb were up to three orders of magnitude higher in Bryopsis plumosa. The data showed that the red algae species (Rhodophyta) accumulate more heavy metals than the other phyla (except for Fe whose values were higher in green algae). The data confirmed that algae are valuable indicators of the environmental contamination. The observed elevated levels were mainly due to Danube, Dnieper and Dnester inputs in the NW corner of the Black Sea.     

Urbanization in China Based on International Comparison： A Discussion with Two Prevalent Views

Two prevalent views are reviewed on China＇s urbanization firstly. Then, this article highlights the characteristics and pattern of urbanization in the world based on the quadrants map, using data of 118 countries or areas. The results indicate that the process of urbanization in the world excluding the data of China has slowed down gradually. A further exploration examines China＇s urbanization process and economic development over time, which reveals that both urbanization level and the level of economic development belong to the low-grade coordination pattern. The low level of urbanization is closely connected with the low level of economic development. Actually, China＇s urbanization gap appeared during 1985-1995, but it has been eliminating this urbanization gap since 1995 as a result of rapid urbanization growing. The complicated realities revealed in this analysis challenge the existing two prevalent views.     

China＇s Land Carrying Capacity Based on Man-grain Relationships

With population growth and increasing pressure on land resources, land carrying capacity （LCC） and food safety have been attracting great attention worldwide. From the point of man-grain relationship and by establishing LCC and land carrying capacity index （LCCI） models, this article firstly analyzes the spatial-temporal dynamics of LCC of China from 1949 to 2005 at county, provincial and national levels. Choosing 2005 as a representative year, this article then evaluates the LCC of 264 pastoral regions （semipastoral regions）, 663 urban regions and 592 poverty stricken regions of the country. The results show that： （1） from 1949 to 2005, with the increase of grain production, the LCC of China has been improved conspicuously, but due to the rapid population growth, the production can only maintain a low level grain consumption; （2） over the past 25 years （1980-2005）, the number of population overloading provinces decreased from 23 to 15 and the mangrain relationship has been improved gradually, but there were more overloading provinces than surplus provinces in China; （3） at county level, there were 1572 overloading counties in 1980 accounting for 68.26% of the total counties of the country and where were 649 million people lived, while in 1990, 2000 and 2005, the number of overloading counties were 1066, 1133 and 1087 respectively, which shows that the man-grain relationship has been improved obviously during the past 25 years; as for spatial distribution, the surplus counties were mainly concentrated in agriculture developed regions, such as Northeast Plain, North China Plain, middle and lower Reaches of the Yangtze River Plain, and overloading counties were mainly located in regions with poor natural environment and low grain production capacity, such as Northwest China, Tibetan Plateau and Loess Plateau and economically developed urban regions, such as Beijing, Tianjin and Shanghai; （4） animal husbandry improved greatly the LCC of pastoral and semi-pastoral regions, while urban regions were overloading for increasing population pressure and more than half of poverty stricken regions were overloading due to critical natural environment and poor economic conditions.     

Levels and congener profiles of PCDD/Fs, PCBs and PBDEs in seafood from China

A nationwide investigation into polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) in market seafood was conducted for the first time in this study. Total PCDD/F concentrations in fatty fish ranged from 0.13 to 8.64 pg g⁻¹ wet weight (mean 2.05 pg g⁻¹ wet weight), total PCB concentrations ranged from 38.9 to 3514 pg g⁻¹ wet weight (mean 1133 pg g⁻¹ wet weight), and total PBDE concentrations ranged from 42.8 to 913 pg g⁻¹ wet weight (mean 322 pg g⁻¹ wet weight). Corresponding mean toxicity equivalent (TEQ) values for total PCDD/F and dioxin-like PCB were 0.25 pg g⁻¹ wet weight (WHO 98-TEQ) and 0.32 pg g⁻¹ wet weight (WHO 98-TEQ), respectively. OCDD, PCB-138 and PBDE-47 were the dominant compounds according to their respective congeners. WHO 98-TEQ _{PCDD/PCDF/PCB} for fatty fish and shell fish were 0.60 and 0.070 pg g⁻¹ wet weight, respectively, lower than the standard set by the European Commission. The contamination levels and profiles were compared with those documented in previous publications.