新型静电布袋除尘技术研究

提出了一种新的静电布袋混合式除尘器 ,并通过试验和理论分析 ,进行了原理性研究。研究结果表明 ,这种带高压静电的布袋除尘器组合了静电除尘和滤袋除尘 2种技术 ,在布袋与极板间形成了很强的静电场 ,,使荷电粉尘无法靠近滤袋而向极板沉积 ,过滤速度大为提高 ,阻力系数是各种过滤方式中最小的。新的静电布袋除尘器的经济性将优于现在的电除尘器、布袋除尘器和组合式除尘器。     

PCDDs, PCDFs emission control by dry scrubbing system

Presently, in Japan there are no limitations on the emission of PCDDs or PCDFs, but in order to study the feasibility of dry type air pollution control, a pilot plant was constructed in 1988 and the removal efficiencies for PCDDs, acid gas and heavy metals were measured.At the same time PCDDs concentration was compared with that of a previously installed electrostatic precipitator (ESP) plus wet scrubber line.In this paper, the following two items are reported.

1. (1) The difference in the amounts of PCDDs and PCDFs produced due to differences in gas temperature and retention time in ESP and fabric filter (FF).

2. (2) Removal efficiencies of PCDDs and PCDFs of fabric filter.

PCDDs concentration, generally 100–200 ng/Nm³ at the boiler outlet (ESP inlet and/or Quench Reactor (QR) inlet), increased several times at the ESP outlet, but it showed almost no increase at the QR outlet due to a sudden temperature drop. The temperature was 280–310°C, and the gas retention time was 12 sec. during passage through ESP so that it is thought that PCDD was formed under these conditions.On the other hand, a removal efficiency of approx. 90% was obtained with the fabric filter, and the PCDD at the bag outlet was at a sufficiently low level.     

应用于Anammox-MBR的尼龙织布亲水改性研究

采用聚乙烯醇（PVA）对尼龙织布表面涂覆改性,对改性前后织布进行表征并进行纯水通量测试,随后以牛血清蛋白（BSA）模拟污染物测试尼龙织布改性前后的抗污染性能,并对改性后的织布进行溶解性有机碳（DOC）浸出实验.改性过程中,优选3%涂覆浓度和250μm涂层厚度,改性后织布的纯水通量值约提高85.0%,对BSA的截留率由6.0%±0.5%上升至7.2%±0.7%,通量恢复率由90.0%提高到96.1%,可逆污染比重上升,不可逆污染比重下降,污染形式主要表现为可逆污染.为避免改性尼龙织布应用于厌氧氨氧化-膜生物反应器（Anammox-MBR）时对厌氧氨氧化反应产生不可逆危害,提出应对制备完成的改性尼龙织布进行为期3d及以上的静态清水浸泡或动态浸出处理.     

Fabrication of PVDF nanofibrous hydrophobic composite membranes reinforced with fabric substrates via electrospinning for membrane distillation desalination

To improve the mechanical properties of the electrospun nanofibrous membrane, the nonwoven fabrics and spacer fabrics were employed as support substrates to fabricate polyvinylidene fluoride(PVDF) nanofibrous composite membranes. The influences of the substrate on membrane morphology, hydrophobicity, pore size and pore size distribution,porosity, mechanical strength and permeability were comprehensive evaluated. The electrospun composite membranes had a three dimension bead-fiber interconnected open structure and a rough membrane surface. The membrane surface presented a multilevel re-entrant structure and all the water contact angles were above 140°. In contrast with the pure PVDF nanofibrous membrane, the stress at break and the elastic modulus of the composite membranes increased by 4.5–16 times and 17.5–37 times, respectively. Since the spacer fabrics had less resistance to mass transfer, the membranes composited with spacer fabrics exhibited greater permeate fluxes compared with the composite membranes with the nonwoven fabrics as substrates.During the membrane distillation test, the highest permeate flux was up to 49.3 kg/m~2/hr at the feed temperature of 80°C. The long-time and repeat operation of membrane distillation desalination indicated the fabricated membrane with a good resistance to scaling and wetting.The results suggested the potential of the electrospun composite membrane for membrane distillation application.     

不同织物构造PPS滤料对PM2.5的过滤特性影响分析

针对纤维细度、纤维横截面形状、面层后处理工艺对PM2.5的过滤效率及阻力的影响问题,分别选用1#面层含100％ 2.22 dtex PPS纤维经PTFE浸渍、2#面层含50％ PPS细纤维不经PTFE浸渍、3#面层含50％ PPS细纤维经PTFE浸渍、4#面层含50％ PPS三叶形纤维不经PTFE浸渍、5#面层含50％ PPS三叶形纤维经PTFE浸渍、6#面层PTFE覆膜、7#面层含50％ PPS细纤维和50％ PTFE超细纤维的7种PPS滤料进行过滤性能试验.在环境气溶胶中,采用清洁滤料进行过滤试验研究.结果表明,1 m/min风速下对PM2.5的过滤效率从大到小为6#(81％)、7#(80％)、3#(76％)、5#(72％)、1#(63％)、2#(47％)、4#(41％),各因素中PTFE乳液浸渍后处理工艺的影响最为显著,面层纤维采用细纤维截面设计和三叶形截面设计都能有效增加滤料对PM2.5的过滤效率.过滤阻力方面,6#覆膜滤料随过滤风速增大阻力迅速上升;其他6种滤料的阻力较接近,上升缓慢.过滤品质因数Q值方面,相对于常规滤料,面层中混入细纤维或三叶形纤维滤料的Q增大;提高面层中细纤维比例,也能使Q增大;覆膜滤料效率虽高,但阻力较大,Q最小.     

应用于Anammox-MBR的尼龙织布亲水改性研究

采用聚乙烯醇（PVA）对尼龙织布表面涂覆改性，对改性前后织布进行表征并进行纯水通量测试，随后以牛血清蛋白（BSA）模拟污染物测试尼龙织布改性前后的抗污染性能，并对改性后的织布进行溶解性有机碳（DOC）浸出实验.改性过程中，优选3%涂覆浓度和250μm涂层厚度，改性后织布的纯水通量值约提高85.0%，对BSA的截留率由6.0%±0.5%上升至7.2%±0.7%，通量恢复率由90.0%提高到96.1%，可逆污染比重上升，不可逆污染比重下降，污染形式主要表现为可逆污染.为避免改性尼龙织布应用于厌氧氨氧化-膜生物反应器（Anammox-MBR）时对厌氧氨氧化反应产生不可逆危害，提出应对制备完成的改性尼龙织布进行为期3d及以上的静态清水浸泡或动态浸出处理.     

服装面料选取时难降解成分鉴定分析研究

当前面料中难降解成分对环境造成很大程度污染,在服装面料选取时,为避免难降解面料的使用,提出基于近红外光谱的面料难降解成分鉴定分析方法.通过分析服装面料中难降解成分对环境的影响,提取面料中难降解成分,得出三种成分类型,通过对不同成分造成环境污染程度进行鉴定分析,完成服装面料选取时难降解成分的鉴定.实验结果表明,该方法误差控制在-0.2~0.2范围内,能够准确鉴定出服装面料中难降解成分,为降低环境污染提供了有效帮助.     

防弹衣舒适性能改善设计

本文通过对防弹衣的改进研究,探讨了利用经编间隔织物对防弹装备舒适性提高的可行性。用经编间隔织物代替传统防弹衣里料（平纹机织布）,并制成成衣。通过红外热成像仪分别测试以经编间隔织物为里料的防弹衣的热湿传导性、透气散热性来探讨经编间隔织物对防弹衣的舒适性能的影响。实验结果表明：在相同测试条件下,以经编间隔织物为里料的防弹衣的热湿传导性能良好,透气散热性优于传统防弹衣1℃左右。因此经编间隔织物对提高防弹衣的舒适性能具有推动作用。本课题的研究意义在于为警用防弹衣的舒适性能提供理论参考,为警察或军队的作战能力提高做出更大的贡献。     

无纺布填料处理污水试验及机理

采用无纺布作为一种新型悬浮填料,探索无纺布填料处理污水的适用条件、运行参数及降解机理.研究认为不同容积负荷应采取不同的填料投配率:当CODCr容积负荷低于1.2kg/(m³·d)时,取填料投配率为20%;当CODCr容积负荷在1.2～2.0kg/(m³·d)之间时,取填料投配率为38%;当CODCr容积负荷达2.0 kg/(m³·d)以上时,取填料投配率为29%模型结果表明,附着微生物降解有机物的规律可用Monod方程的形式描述.