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101.
A new method (NMM, using acetic acid fiber filter and 90% ethanol) was established to determine chlorophyll in freshwater
algae, and it was compared with US standard method (USM, using glass fiber filter and 90% acetone) and the method recommend
by EPA of China (CHM, using acetic acid fiber filter and 90% acetone). The precision and repeatability of NMM is equivalent
to that of USM, but NMM is safer to laboratory workers than USM and CHM because ethanol was used as solvent in NMM instead
of acetone used in USM and CHM, and time and money were also greatly saved by the new method. The precision and repeatability
of CHM was much less than USM and NMM, and the advice improving the method was proposed that the extraction time must be prolonged. 相似文献
102.
Kumar KS Suvardhan K Rekha D Kiran K Rao GC Jayaraj B Janardhanam K Chiranjeevi P 《Environmental monitoring and assessment》2007,129(1-3):271-276
Facile, selective and sensitive spectrophotometric method has been developed for the determination of carbosulfan in insecticidal
formulations, fortified water, food grains, agriculture wastewater and soil samples with newly synthesized reagents. The method
was based on acid and alkaline hydrolysis of the carbosulfan pesticide, and the resultant hydrolysis product of carbosulfan
was coupled with 2,6-dibromo-4-methylaniline to give a yellow color product with λ
max of 464 nm or interaction with 2,6-dibromo-4-nitroaniline to produce yellow colored product with λ
max of 408 nm or coupling with 2,4,6-tribromoaniline to form red colored product has a λ
max of 471 nm. Under optimal conditions, Beer’s law range for 2,6-dibromo-4-methylaniline (DBMA) was found to be 0.2–12.0 μg
ml−1, 0.6–16.0 μg ml−1 for 2,6-dibromo-4-nitroaniline (DBNA) and 0.4–15.0 μg ml−1 for 2,4,6-tribromoaniline (TBA). The molar absorptivity of the color systems were found to be 3.112 × 104 l mol−1 cm−1 for DBMA, 3.214 × 104 l mol−1 cm−1 for DBNA and 3.881 × 104 l mol−1 cm−1 for TBA. Sandell’s of the color reactions are 0.013 μg cm−2 (DBMA), 0.012 μg cm−2 (DBNA) and 0.011 μg cm−2 (TBA) respectively. The effect of the non-target species on the determination of carbosulfan was studied to enhance the selectivity
of the proposed methods. The formation of colored derivatives with the coupling agents is instantaneous and stable for 28,
30, and 26 h. Performance of the proposed methods were compared statistically in terms Student’s F and t-tests with the reported methods.
An erratum to this article can be found at 相似文献
103.
M. K. J. Siddiqui F. Anjum M. Mahboob Syed S. H. Quadri 《Journal of environmental science and health. Part. B》2013,48(2):115-124
Abstract Effect of acute doses of technical grade of dichloro diphenyl trichloro ethane (DDT) and piperonyl butoxide (PB) on hepatic micro‐somal cytochrome P450 (Cyt. P450) and cytosolic glutathione‐S‐transferase (GST) activity in pigeon were studied after 24 hours of treatment. A completely reverse trend of changes in Cyt. P450 and GST activity were found as increase in Cyt. ?450 paralleled with decrease in GST activity following exposure to DDT. However, intensity of changes in Cyt. P450 was greater than that of GST. A dose dependent decrease in Cyt. ?450 and GST activity was observed after PB treatment. The study may, therefore, throw some light on metabolic alterations in wild birds resulting from environmental pollution by DDT and allied chemicals. 相似文献
104.
研究了在溴化十六烷基吡啶存在下,邻硝基苯基荧光酮与铝显色反应的条件,结果表明,在pH5.0的乙酸-乙酸钠缓冲溶液中,A1(Ⅲ)与邻硝基苯基荧光酮生成一种玫瑰红色给合物,其最大吸收波长在559nm,摩尔吸光系数为7.82×104,比耳定律范围0~10μg/25ml,拟定了测定饮茶、饮水中微量铝的方法,结果令人满意。 相似文献
105.
在pH=4.0的缓冲溶液中,磷酸和棉红在100℃下反应生成天蓝色物质(λmax=675nm),该物质在微量铬VI的催化下被溴酸钾氧化褪色,建立了测定痕量铬VI的催化动力学新方法,方法的检出限是0.76ng/ml,线性范围0~0.06μg/ml,用于测定电镀废水中铬VI,结果满意。 相似文献
106.
分光光度法测定余氯的线性范围探讨 总被引:3,自引:0,他引:3
用分光光度法测定水样中的余氯,按照国际GB11898-89中的要求,整个浓度范围内(余氯0-5.00mg/L)所制得的标准曲线的相关系数在0.99-0.999之间。经对其标准曲线的线性范围进行探讨发现,当余氯的浓度范围为0-1.00mg/L时,标准曲线的线性较好,相关系数>0.999;当余氯的浓度>1.00mg/L,所绘制的标准曲线呈负偏离现象,相关系数<0.999。 相似文献
107.
新银盐光度法测定废水中的砷 总被引:2,自引:0,他引:2
通过改变测定吸收波长和降低试剂空白值,提高了样品测定的准确度和精密度. 相似文献
108.
本文从摩尔吸光系数ε出发,推算出分子吸收分光光度法中校准曲线的斜率b0,并确定出斜率值的允许范围。通过对我站历次所做校准曲线进行研究,发现它们的斜率范围与本文所确定的范围符合得较好。 相似文献
109.
挥发酚测定过程中应注意问题及方法改进 总被引:1,自引:0,他引:1
指出用4-氨基安替比林法测量水中挥发酚应该注意的问题,并对测量发法提出了一些改进。 相似文献
110.
孔雀绿萃取光度法测量微量铅的研究 总被引:1,自引:0,他引:1
研究了铅(Ⅱ)—碘化钾—孔雀绿(MG)缔合显色体系。发现在pH=4.7的HAc—NaAc缓冲溶液中,MG与PbI形成稳定的缔合物,可用苯萃取,其最大吸收峰位于625nm处,摩尔吸光系数为1.2×10 ̄5L/(mol·cm),Pb(Ⅱ)浓度在0~25μg/10ml范围内符合比耳定律,缔合物的组成比为Pb(Ⅱ):I:MG=1:4:2。应用此法测定了煤飞灰标样、茶叶、自来水中的铅含量,结果令人满意。 相似文献