拟除虫菊酯气相色谱手性拆分方法及其影响因素分析

拟除虫菊酯具有较强的手性特征,包含多种异构体,不同异构体具有不同的生物活性,因此,其异构体的手性拆分具有重要的意义。气相色谱分析法因其分辨率高,峰容量大,灵敏度高、分析时间短,选择性强等特点,已被广泛应用于拟除虫菊酯的手性拆分中。文章通过阐述基于氢键作用、配位作用、包结络合作用的3种手性固定相的拆分机制,综述了气相色谱用于拟除虫菊酯手性分离的研究状况。此外,文章还分析了有机溶剂、水、温度等对拟除虫菊酯在拆分过程中差向异构现象的影响。     

Hg~(2+)对剩余污泥厌氧消化过程中物质释放的影响

以某采用A/O生物除磷工艺的污水处理厂排出的富磷剩余污泥为研究对象,设计两组厌氧消化比较试验,考察了Hg2+的毒性对剩余污泥厌氧消化过程中SCOD、VSS、SOP等相关指标的影响,藉此讨论相关物质的释放机制。结果发现,Hg2+的投加可以促进剩余污泥的水解,造成了短期内VSS的快速下降以及SOP的快速释放。当HgCl2投加量为0.25 g/L时,这个短期的时间尺度持续4 d左右;4 d以后,由于HgCl2对产甲烷菌、产酸菌以及聚磷菌均会产生不利影响,HgCl2开始抑制消化过程的进行,导致SCOD积累,VSS、SOP等释放速度减缓。这表明HgCl2可以促进水解释磷,抑制生物释磷。总体而言,投加HgCl2对剩余污泥中磷的释放是不利的。     

Transport risk modeling for hazardous chemical transport Companies—A case study in China

Traffic accidents of hazardous chemical transport vehicles strongly correlate with the operation and management level of road transport companies. An accurate risk assessment of these transport companies will play a critical role in improving their management and supervision and in turn the overall safety of roadways, property, and most importantly people's lives. Therefore, this study constructs a logistic regression scorecard model to evaluate transport risk of hazardous chemical transport companies and evaluates it using a case study in China. This study first selected 16 indicators from the dimensions of driver behaviors, driving performance, dangerous goods and company business operation to construct company user portraits. Next, a K-means++ algorithm was used to cluster the data samples of the companies on a monthly basis. On this basis, a scorecard was constructed based on a logistic regression scorecard model to realize and visualize the monthly risk portrait of companies. The constructed scorecard predicted transport risk of companies accurately. The results show that the more complex the types of dangerous goods transported, the higher the risk value of the company in the dangerous goods index. Moreover, for transport companies, the driver behaviors and driving performance on their trips are closely related to their business risk. In a practical application, the proposed scorecard can realize the dynamic risk monitoring of transport companies and enable managers and supervision departments to clarify where the risk is from. The transport companies can also carry out safety training and rectification for drivers and operations to reduce the occurrence of hazardous materials-related traffic accidents.     

Dust particle sedimentation in the 20 L standard vessel for dust explosion tests

According to the current international standards, to perform the correct evaluation of the explosion and flammability parameters, a uniform distribution of the dust particles should be achieved inside the 20 L and/or 1 m³ standard vessels.CFD simulations have shown that in both standard test vessels (20 L and 1 m³), the dust particles are not uniformly dispersed, being mostly concentrated at the edge of the macro-vortices generated by the injection of the fluid and particle through the nozzle. In addition, only a partial fed of the particles is obtained, and dust particles sedimentation phenomena can occur.As a result, the dust participating to the reactive process may be much lower than the expected nominal concentration in the vessel due to sedimentation and incomplete feeding. Consequently, misleading values of the flammability/explosion parameters could be measured.Particle sedimentation and incomplete feeding depends both on the Stokes number and on the Reynolds number, whereas the concentration distribution depends on the turbulence level, the fluid flow maps, and the number of particles which enter into the vessel through the nozzle.The aim of this work is to evaluate the key parameters (particle size, particle density, and fluid velocity) affecting sedimentation and incomplete feeding in 20 L vessel. To this end, CFD simulations of dust dispersion are performed at varying the particle density and size. Operating maps, in terms of the key parameters and/or their dimensionless combinations, are developed and a correlation for correction of the data is proposed.     

多孔吸声材料流阻测试实践介绍

本文简单介绍多孔吸声材料流阻测试的初步实践,以促进同行交流。     

高海拔环境下离心风机性能数值模拟研究*

为研究高海拔环境下离心风机的运行性能规律,采用计算流体力学（CFD）方法对海拔高度分别为0,1 000,2 000,3 000,4 000和5 000 m条件下的离心风机流场及性能进行三维数值模拟。研究结果表明:相同工况风量条件下,风机内部流场形态不受海拔高度影响,但随着海拔的升高,内流场各处压力绝对值均减小,风机叶片载荷减小,风机蜗壳出口压力及轴功率均大致呈线性趋势降低,海拔每升高1 000 m,风机输出全压及静压分别降低9.3%及9.1%左右,轴功率降低9.0%左右。离心风机效率受海拔高度影响较小,模拟结果表明,各工况条件下,海拔每升高1 000 m,风机全压及静压效率分别平均降低0.21%和0.29%左右。研究为保证高海拔地区离心风机的高效运转及风机选型提供理论参考。     

Global assessment of the biodiversity safeguards of development banks that finance infrastructure

Infrastructure development is a major driver of biodiversity loss globally. With upward of US$2.5 trillion in annual investments in infrastructure, the financial sector indirectly drives this biodiversity loss. At the same time, biodiversity safeguards (project-level biodiversity impact mitigation requirements) of infrastructure financiers can help limit this damage. The coverage and harmonization of biodiversity safeguards are important factors in their effectiveness and therefore warrant scrutiny. It is equally important to examine the extent to which these safeguards align with best-practice principles for biodiversity impact mitigation outlined in international policies, such as that of the International Union for Conservation of Nature. We assessed the biodiversity safeguards of public development banks and development finance institutions for coverage, harmonization, and alignment with best practice. We used Institute of New Structural Economics and Agence Française de Développement's global database to identify development banks that invest in high-biodiversity-footprint infrastructure and have over US$500 million in assets. Of the 155 banks, 42% (n = 65) had biodiversity safeguards. Of the existing safeguards, 86% (56 of 65) were harmonized with International Finance Corporation (IFC) Performance Standard 6 (PS6). The IFC PS6 (and by extension the 56 safeguard policies harmonized with it) had high alignment with international best practice in biodiversity impact mitigation, whereas the remaining 8 exhibited partial alignment, incorporating few principles that clarify the conditions for effective biodiversity offsetting. Given their dual role in setting benchmarks and leveraging private finance, infrastructure financiers in development finance need to adopt best-practice biodiversity safeguards if the tide of global biodiversity loss is to be stemmed. The IFC PS6, if strengthened, can act as a useful template for other financier safeguards. The high degree of harmonization among safeguards is promising, pointing to a potential for diffusion of practices.     

深孔爆破孔底充填缓冲吸能材料减震试验研究

通过对影响爆破震波各种主要因素的分析,针对深孔爆破采用孔底装填吸能缓冲材料,来削减炸药爆炸在孔底的冲击压力和吸收部分能量,从而达到降低爆破震动对周边建(构)物影响的目的。并进行现场爆破试验,对爆破震动波进行测试,同时对减震爆破装药和非减震的常规爆破装药进行比较,获得的测试数据证明,采用孔底装填吸能缓冲材料其减震率达到3.23%～35.19%。     

抗静电纺织品的测试标准浅析与探讨

本文阐述了目前抗静电纺织品的发展现状和主流开发技术路线,结合常用的纺织品抗静电性能测试方法和技术,浅析了目前我国的抗静电纺织品检测标准和方法,探讨了一些技术细节和常见问题。     

环境标准物质探讨及含有干扰组分的COD标准物质的研制

很多标准物质与环境实际样品在基体组成上存在着很大差异．因此在环境监测中仅仅使用基体纯净的标准物质不能完全有效地进行质量控制,根据上述问题,本文介绍了含有干扰组分的COD标准物质的研制与应用。