Three common metal contaminants of urban runoff (Zn, Cu & Pb) accumulate in freshwater biofilm and modify embedded bacterial communities

We investigated the absorption rates of zinc, copper and lead in freshwater biofilm and assessed whether biofilm bacterial populations are affected by exposure to environmentally relevant concentrations of these metals in flow chamber microcosms. Metals were rapidly accumulated by the biofilm and then retained for at least 14 days after transfer to uncontaminated water. Changes in bacterial populations were assessed by Automated Ribosomal Intergenic Spacer Analysis (ARISA) and 16S rRNA gene clone libraries. Significant differences in bacterial community structure occurred within only three days of exposure to metals and remained detectable at least 14 days after transfer to uncontaminated water. The rapid uptake of stormwater-associated metals and their retention in the biofilm highlight the potential role of biofilms in the transfer of metals to organisms at higher trophic levels. The sensitivity of stream biofilm bacterial populations to metal exposure supports their use as an indicator of stream ecological health.     

Technologies for pollutant removal and resource recovery from blackwater: a review

● Blackwater is the main source of organics and nutrients in domestic wastewater. ● Various treatment methods can be applied for resource recovery from blackwater. ● Blackwater treatment systems of high integration and efficiency are the future trend. ● More research is needed for the practical use of blackwater treatment systems. Blackwater (BW), consisting of feces, urine, flushing water and toilet paper, makes up an important portion of domestic wastewater. The improper disposal of BW may lead to environmental pollution and disease transmission, threatening the sustainable development of the world. Rich in nutrients and organic matter, BW could be treated for resource recovery and reuse through various approaches. Aimed at providing guidance for the future development of BW treatment and resource recovery, this paper presented a literature review of BWs produced in different countries and types of toilets, including their physiochemical characteristics, and current treatment and resource recovery strategies. The degradation and utilization of carbon (C), nitrogen (N) and phosphorus (P) within BW are underlined. The performance of different systems was classified and summarized. Among all the treating systems, biological and ecological systems have been long and widely applied for BW treatment, showing their universality and operability in nutrients and energy recovery, but they are either slow or ineffective in removal of some refractory pollutants. Novel processes, especially advanced oxidation processes (AOPs), are becoming increasingly extensively studied in BW treatment because of their high efficiency, especially for the removal of micropollutants and pathogens. This review could serve as an instructive guidance for the design and optimization of BW treatment technologies, aiming to help in the fulfilment of sustainable human excreta management.     

Regulating oil and gas facility stormwater discharge: An assessment of surface impoundments,spills, and permit compliance

Contaminated stormwater runoff from oil and gas (O&G) operations can pose a significant threat to surface waters. The purpose of this study is to examine the extent of this threat and identify more specific permitting requirements to protect surface waters. To better understand the extent of the threat, this paper identified and characterized the use of waste surface impoundments at O&G facilities as well as the threat level from O&G spills in California. To assess the efficacy of the current federal and California state-permitting regime, the paper evaluated stormwater permit compliance in two California counties. It also reviewed selected spill cases and associated Spill Prevention, Control and Countermeasure Plans and Stormwater Pollution Prevention Plans to identify the adequacy of current industry practices.The analysis showed that contaminated stormwater from O&G facilities can be better regulated. The U.S. Environmental Protection Agency does not require O&G facilities to file for an Industrial Stormwater General Permit even though many O&G industry practices have the potential to contaminate stormwater runoff from the site. When O&G facilities discharge a Reportable Quantity of a hazardous chemical or violate a water quality standard, they are required to enroll in the National Pollutant Discharge Elimination System permit program. Spills, although not a direct indication of stormwater runoff, can highlight polluted runoff discharges that should have been regulated. Medium and large spills that reached waterways were such a risk for which operators did not file for a permit. In California new filing requirements for the oil and gas industry require all facilities that discharge stormwater that has come into contact with any overburden, raw material, or intermediate products located on the site, to file for an Industrial Stormwater General Permit. As this study showed, there has been an increase in enrollment since the enactment of the new requirements. Having all facilities enroll in the general permit program, as done in California, would require minimum monitoring and maintenance that could help prevent spills. A further step to ensure better protocol is to require specific pollution control practices in addition to the current general permit requirements. Such permitting regimes not only can be implemented on the US federal level but also internationally.     

上海市一次性塑料饭盒的管理现状分析及建议

梳理了上海市在一次性塑料饭盒管理工作中回收处置系统难以正常运转的主要问题，提出了建立全国一盘棋的格局，将其他塑料废弃物纳入回收处置的管理范畴，并建立对废塑料回收处置的奖励或补贴政策，从而继续控制视觉污染，促进生活垃圾减量化和资源化。     

固戍污水处理厂再生回用水工程论证研究

宝安区域污水处理厂出水水质基本是执行城镇污水处理厂污染物排放标准(GB 18918-2002)中一级B标准,需进行深度处理才能再生回用.以固戍污水处理厂为例,分析了实施固戍污水处理厂再生回用水工程的必要性,论证了再生回用水水质、规模和工艺方案,介绍了工程实施后的实际效果.论证的结果表明,采用二级处理加混凝、沉淀、过滤、消毒工艺,来改造宝安区域内的污水处理厂尾水成为再生回用水切实可行.     

“城市矿产”示范基地——我国再生资源产业化的发展方向

以前三批29个国家＂城市矿产＂示范基地为研究对象,对示范基地的回收利用规模、重点项目覆盖范围、示范基地类型做了概括性梳理,总结了示范基地建设的成功经验,分析了妨碍示范基地健康发展的问题,并提出一些预测性意见,供行业同仁参考。     

RMBR、SMBR、HMBR在中水回用中的应用研究

近年来,随着人们对废水处理和中水回用技术逐渐重视,一种将传统生物处理技术与膜分离技术结合起来的MBR工艺受到青睐。本文通过对RMBR、SMBR、HMBR应用原理及优缺点的分析。为实际应用提供参考。     

混凝-水解酸化-接触氧化-脱色工艺处理印染废水及回用

印染废水具有水量大、色度高、有机物含量高、可生化性较差等特点,采用混凝-水解酸化-接触氧化-脱色工艺处理某印染公司污水,经过实践证明,处理后出水水质稳定,操作管理方便等,出水直接回用到印染车间,提高了公司回用水的比率,具有较大的经济效益和社会效益,所以这处理工艺在印染废水处理及回用方面具有巨大的应用价值。     

Characterization and prediction of highway runoff constituent event mean concentration

Highway stormwater runoff quality data were collected from throughout California during 2000-2003. Samples were analyzed for conventional pollutants (pH, conductivity, hardness, and temperature); aggregates (TSS, TDS, TOC, DOC); total and dissolved metals (As, Cd, Cr, Cu, Ni, Pb, and Zn); and nutrients (NO(3)-N, TKN, total P, and ortho-P). Storm event and site characteristics for each sampling site were recorded. A statistical summary for chemical characteristics of highway runoff is provided based on statewide urban and non-urban highways. Constituent event mean concentrations (EMCs) were generally higher in urban highways than in non-urban highways. The chemical characteristics of highway runoff in California were compared with national highway runoff chemical characterization data. The results obtained in California were generally similar to those found in other states. The median EMC for Pb measured in studies conducted in previous decades was much higher than the current median Pb EMC in California. The lower Pb EMC in California compared to previous highway runoff monitoring is believed to be due to the elimination of leaded gasoline. An attempt was also made to identify surrogate constituents within a general family of water quality categories using Spearman correlations and selected pairs with Spearman coefficients greater than 0.8. The strongest correlations were observed among parameters associated with dissolved minerals (EC, TDS, and chloride); organic carbon (TOC and DOC); petroleum hydrocarbons (TPH and O & G); and particulate matter (TSS and turbidity). Within the metals category, total iron concentration was highly correlated with most total metal concentrations. The correlations between total and dissolved concentrations were all less than 0.8, even between total and dissolved concentrations of the same metals. Multiple linear regression (MLR) analyses were performed to evaluate the impact of various site and storm event variables on highway runoff constituent EMCs. Parameters found to have significant impacts on highway runoff constituent EMCs include: total event rainfall (TER); cumulative seasonal rainfall (CSR); antecedent dry period (ADP); contributing drainage area (DA); and annual average daily traffic (AADT). Surrounding land use and geographic regions were also determined to have a significant impact on runoff quality. The MLR model was also used to predict constituent EMCs. Model performance determined by comparing predicted and measured values showed good agreement for most constituents.     

Characterization of polycyclic aromatic hydrocarbons in urban stormwater runoff flowing into the tidal Anacostia River, Washington, DC, USA

To investigate the sources, fate, and transport dynamics of PAHs (polycyclic aromatic hydrocarbons) in stormwater runoff that is a leading source of pollution in urban watersheds, storm and base flow samples were collected in six branches along the lower Anacostia River. PAHs in storm flow (1510-12,500 ng/L) were significantly enriched in the particle phase, which accounted for 68-97% of the total PAHs. It suggests that reducing particles in stormwater using post-treatment system would decrease PAHs considerably. The solid-water distribution coefficients (KD) of PAHs in the storm flow samples were up to 340 times higher than predicted values. A greater portion of high molecular weight PAHs and their distribution patterns indicate higher contribution of automobile originated pyrogenic PAHs. Total suspended solids in storm flow had a positive relationship with flow rates and exceeded benchmark level for the protection of aquatic biota in some samples.