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排序方式: 共有536条查询结果,搜索用时 125 毫秒
531.
针对地表水水质状况的科学评价问题,从计算原理出发,深入分析多级模糊数学综合评价方法无法科学合理评价劣Ⅴ类地表水的根本原因,并在此基础上探索性提出模糊数学评价应用修正方案。以武汉市的4个典型湖泊为评价分析对象,对修正方案的评估结果进行比较。实例研究证实模糊数学评价修正法能科学识别和合理描述劣V类水体的水质污染状况。以所有地表水污染状况为基础,整合所有待评水体污染指标超标最大值体系(溶解氧浓度的最小值)作为劣V类水质统一标准限值,能有效提高该评价法的科学合理性及全面通用性,有助于模糊数学综合评价法在地表水水质评价领域应用的完善与推广。 相似文献
532.
533.
Wang X Wu J Hao Y Zhu B Shi W Hu G Han X Giesy JP Yu H 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2720-2725
Reproductive toxicity of organic extracts of the surface water from the Tai section of the Yangtze River was assessed by in vitro cytotoxity assays and selected persistent organic pollutants including PCBs, OCPs and PAHs were quantified by instrumental analysis. Eleven of the US EPA priority PAHs were detected. Individual PAHs were found to range from 0.7 to 20 ng/L. Concentrations of BaP did not exceed the national drinking water source quality standard of China. However, a 286-fold concentrated organic extract induced significant reproductive toxicity in adult male rats. The morphology of cells, MTT assay and LDH release assay were all affected by exposure to the organic extracts of water. The results of the reproductive toxicity indicated that PAHs posed the greatest risk of the chemicals studied. The compounds present in the water could be bioconcentrated and result in adverse effects. 相似文献
534.
Distribution of perfluorinated compounds in surface water from Hanjiang River in Wuhan,China 总被引:2,自引:0,他引:2
Beibei Wang Menghua Cao Hudi Zhu Jing Chen Linling Wang Guanghong Liu Xiaoman Gu Xiaohua Lu 《Chemosphere》2013
This study provided the first spatial distribution of perfluorinated compounds (PFCs) in Hanjiang River in Wuhan, China (HR). Surface water samples, collected from 23 sites in HR were analyzed for eight PFCs. The total concentrations of PFCs ranged from 8.90 to 568 ng L−1, while perfluoropentanoic acid (PFOA, <LOQ − 256 ng L−1) and perfluorooctane sulfonate (PFOS, <LOQ − 88.9 ng L−1) dominated. All data were found to be normally distributed in the river. Similar spatial distribution tendencies were found among perfluorocarboxylates (PFCAs) and significant correlations were observed among PFCAs, while no significant correlations were found between PFOS and PFCAs. The distributions of PFCs were highly influenced by the industrial discharge and urban activities. The flux of PFCs from HR to the Yangtze River was estimated in the range of 16.9–127 kg yr−1. More than a half of the samples studied could not meet the drinking water standards and avian wildlife values, suggesting further studies of characterizing PFCs and their potential risk to human were needed. 相似文献
535.
中国地表饮用水水源地有机类内分泌干扰物污染现况分析 总被引:2,自引:0,他引:2
有机类内分泌干扰物(EDCs)是一类对人类和生物内分泌系统产生干扰,并可造成其紊乱的特殊外来物质,对人类和生物健康有极大的危害.以与人类生活密切相关的地表饮用水水源地中的有机类EDCs为研究重点,对中国目前地表饮用水水源地EDCs污染状况、污染物种类及其来源及可能的污染途径进行了评述.目前,中国各地区地表饮用水水源地均有有机类EDCs检出.其中以有机氯农药六六六及其异构体、DDT及其代谢产物和多氯联苯检出率最高,且某些地区检测浓度相当高,主要来源是农药使用和污水排放.国内外对地表饮用水水源地EDCs突发污染事件的研究均较少,应引起高度重视. 相似文献
536.
Coprecipitation mechanisms of Zn by birnessite formation and its mineralogy under neutral pH conditions
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Birnessite (δ-Mn(IV)O2) is a great manganese (Mn) adsorbent for dissolved divalent metals. In this study, we investigated the coprecipitation mechanism of δ-MnO2 in the presence of Zn(II) and an oxidizing agent (sodium hypochlorite) under two neutral pH values (6.0 and 7.5). The mineralogical characteristics and Zn–Mn mixed products were compared with simple surface complexation by adsorption modeling and structural analysis. Batch coprecipitation experiments at different Zn/Mn molar ratios showed a Langmuir-type isotherm at pH 6.0, which was similar to the result of adsorption experiments at pH 6.0 and 7.5. X-ray diffraction and X-ray absorption fine structure analysis revealed triple-corner-sharing inner-sphere complexation on the vacant sites was the dominant Zn sorption mechanism on δ-MnO2 under these experimental conditions. A coprecipitation experiment at pH 6.0 produced some hetaerolite (ZnMn(III)2O4) and manganite (γ-Mn(III)OOH), but only at low Zn/Mn molar ratios (< 1). These secondary precipitates disappeared because of crystal dissolution at higher Zn/Mn molar ratios because they were thermodynamically unstable. Woodruffite (ZnMn(IV)3O7•2H2O) was produced in the coprecipitation experiment at pH 7.5 with a high Zn/Mn molar ratio of 5. This resulted in a Brunauer–Emmett–Teller (BET)-type sorption isotherm, in which formation was explained by transformation of the crystalline structure of δ-MnO2 to a tunnel structure. Our experiments demonstrate that abiotic coprecipitation reactions can induce Zn–Mn compound formation on the δ-MnO2 surface, and that the pH is an important controlling factor for the crystalline structures and thermodynamic stabilities. 相似文献