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91.
Polycyclic aromatic hydrocarbons in the bulk precipitation and surface waters of Northern Greece 总被引:15,自引:0,他引:15
Bulk (wet and dry) precipitation and surface water sampling was undertaken in the main plain of central Macedonia in Northern Greece. Fourteen polycyclic aromatic hydrocarbons (PAHs) included in the US EPA's priority pollutant list were analysed. The concentrations determined in bulk precipitation were in general within the range of values worldwide reported. Concentrations were highest in the cold months. Deposition fluxes of PAHs were of the same order of magnitude as reported data. The greatest values were found when high concentrations of PAHs in precipitation coincided with large precipitation amounts. The concentrations of PAHs in surface waters (main rivers, tributaries, ditches, etc) were in general lower than those in bulk precipitation, and among the lowest reported for European rivers, excepting Np and Ph. Bulk deposition and domestic effluents are suggested as being the main PAH sources into surface waters. 相似文献
92.
Adsorption of Pb(II) on variable charge soils amended with rice-straw derived biochar 总被引:11,自引:0,他引:11
Two Ultisols and one Oxisol from tropical regions of southern China were incubated with rice straw biochar to investigate the effect of biochar on their surface charge and Pb(II) adsorption using batch methods. The incorporation of biochar induced a remarkable increase in soil cation exchange capacity after 30 d of incubation. The incorporation of biochar significantly increased the adsorption of Pb(II) by these variable charge soils; the enhancement of adsorption of Pb(II) by these soils increased with the addition level of biochar. Adsorption of Pb(II) involved both electrostatic and non-electrostatic mechanisms; however, biochar mainly increased Pb(II) adsorption through the non-electrostatic mechanism via the formation of surface complexes between Pb2+ and functional groups on biochar. There was greater enhancement of biochar on the non-electrostatic adsorption of Pb(II) by the variable charge soils at relatively low pH. Therefore, the incorporation of biochar decreased the activity and availability of Pb(II) to plants through increased non-electrostatic adsorption of Pb(II) by acidic variable charge soils. 相似文献
93.
Coal companies are reluctant to include wetland development in reclamation plans partly due to a lack of information on the
resulting characteristics of such sites. It is easier for coal companies to recreate terrestrial habitats than to attempt
experimental methods and possibly face significant regulatory disapproval. Therefore, we studied a young (10 years) wetland
on a reclaimed surface coal mine in southern Illinois so as to ascertain soil and water characteristics such that the site
might serve as a model for wetland development on surface mines. Water pH was not measured because of equipment problems,
but evidence (plant life, fish, herpetofauna) suggests suitable pH levels. Other water parameters (conductivity, salinity,
alkalinity, chloride, copper, total hardness, iron, manganese, nitrate, nitrite, phosphate, and sulfate) were measured, and
only copper was seen in potentially high concentrations (but with no obvious toxic effects). Soil variables measured included
pH, nitrate, nitrite, ammonia, potassium, calcium, magnesium, manganese, aluminum, iron, sulfate, chloride, and percent organic
matter. Soils were slightly alkaline and most parameters fell within levels reported for other studies on both natural and
manmade wetlands. Aluminum was high, but this might be indicative more of large amounts complexed with soils and therefore
unavailable, than amounts actually accessible to plants. Organic matter was moderate, somewhat surprising given the age of
the system. 相似文献
94.
浙江仇山膨润土经不同酸度活化,蒙脱石在酸度为17.5~20%时其颗粒大小、厚度趋于一致;酸度分别为12.5%,20%时集合体由絮状,团块状向厚片状,片状变化;酸度为12.5~17.5%时其颗粒边缘变为光滑,而酸度为25%时则变为锯齿状;酸度20%时,表面更加光滑,平整。蒙脱石形态直接反映它的表面积的变化,决定了活性白土脱色性能的优劣。本文讨论了蒙脱石表面积与活性白土脱色力的变化关系。 相似文献
95.
本文根据前文所提联合上限法和主应力法确定模具表面压力分布的基础原理,计算了圆柱坯料正挤压和十字头锻件镦挤时模具表面的压力分布,所得结果与测定值很吻合,进一步证明了UBM/SM法实际应用的可靠性. 相似文献
96.
上海市郊4种地表径流深度的测算 总被引:7,自引:0,他引:7
根据有关试验资料和美国土壤保持局推荐的方法,提出了上海市郊4种地表径流深度的计算公式。计算结果表明,当年降雨量为1053mm时,上海市郊4种地表径流的总量为13.6亿m^3,平均径流深度为300mm,径流系数为28.49%,4种径流量占郊区总量的77.82%,产流面积为郊区总面积的75.10%。 相似文献
97.
本文主要介绍流域径流污染的系统分析方法,并提出采用卡尔曼滤波理论进行仿真,从而实现污染的预报。 相似文献
98.
99.
The aim of this study was to compare degradation rates of aniline in laboratory shake flask simulation tests with field rates in the river Rhine. The combined events of a low flow situation in the Rhine and residual aniline concentrations in the effluent from the BASF treatment plant in Ludwigshafen temporarily higher than normal, made it possible to monitor aniline at trace concentrations in the river water downstream the wastewater outlet by means of a sensitive GC headspace analytical method. Aniline was analyzed along a downstream gradient and the dilution along the gradient was calculated from measurements of conductivity, sulfate and a non-readily biodegradable substance, 1,4-dioxane. Compensating dilution, field first-order degradation rate constants downstream the discharge of BASF were estimated at 1.8 day−1 for two different dates with water temperatures of 21.9 and 14.7 °C, respectively. This field rate estimate was compared with results from 38 laboratory shake flask batch tests with Rhine water which averaged 1.5 day−1 at 15 °C and 2.0 day−1 at 20 °C. These results indicate that laboratory shake flask batch tests with low concentrations of test substance can be good predictors of degradation rates in natural water bodies––at least as ascertained here for short duration tests with readily degradable compounds among which aniline is a commonly used reference. 相似文献
100.
In this study, a three-dimensional model was used to numerically study the buoyant flow, along with its mixing characteristics, of heated water discharged from the surface and submerged side outfalls in shallow and deep water with a cross flow. Hydraulic experimental data were used to evaluate the applicability of the model. The simulation results agree well with the experimental results, particularly, the jet trajectories, the dimensions of the recirculating zone, and the distribution of the dimensionless excess temperature. The level of accuracy of the simulation results of the present study is nearly identical to that of the results conducted by McGuirk and Rodi (1978). If the heated water is discharged into shallow water where the momentum flux ratio and the discharge densimetric Froude number are high, the submerged discharge method is better than the surface discharge method in terms of the scale of the recirculating zone and the minimum dilution. In deep water, where the momentum flux ratio and discharge densimetric Froude number are low, however, the submerged discharge method had few advantages. In shallow water, the discharge jet is deflected by the ambient cross flow, while forcing the ambient flow to bend towards the far bank for the full depth. For a submerged discharge in shallow water, the recirculating zone is the largest in the lowest layer but becomes smaller in the upper layer. As the water depth increases, the ambient flow goes over the jet and diminishes the blocking effect, thereby decreasing the bending of the jet. 相似文献